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R. Meyer J. Köhler A. Homburg Explosives

R. Meyer J. Köhler A. Homburg Explosives

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181 Hygroscopicity<br />

melting point:<br />

stable modification: 70.7 °C = 159.3 °F<br />

unstable modification: 62.1 °C = 143.8 °F<br />

lead block test: 408 cm3 /10 g<br />

detonation velocity, confined:<br />

8690 m/s 28500ft/s at r = 1.60 g/cm3 decomposition temperature: 229 °C = 444 °F<br />

impact sensitivity: 0.75 kp m = 7.4 N m<br />

critical diameter of steel sleeve test: 6 mm<br />

Hydrazine nitrate is readily soluble in water.<br />

The high detonation velocity of the salt is interesting. Mixtures with<br />

W Octogen, pressed to high density, reach more than 9000 m/s.<br />

Hydrazine Perchlorate<br />

perchlorate d’hydrazine<br />

colorless crystals<br />

empirical formula: H5N2O4Cl<br />

molecular weight: 132.5<br />

energy of formation: –291 kcal/kg = –1216 kJ/kg<br />

enthalpy of formation: –318 kcal/kg = –1331 kJ/kg<br />

oxygen balance: +24.1%<br />

nitrogen content: 21.14%<br />

volume of explosion gases: 838 l/kg<br />

heat of explosion<br />

(H2O liq.): 882 kcal/kg = 3690 kJ/kg<br />

(H2O gas): 725 kcal/kg = 3033 kJ/kg<br />

density: 1.83 g/cm3 melting point: 144 °C = 291 °F<br />

lead block test: 362 cm3 /10 g<br />

deflagration point: 272 °C = 522 °F<br />

impact sensitivity: 0.2 kp m = 2 N m<br />

friction sensitivity: at 1 kp = 10 N pistil load no reaction<br />

critical diameter of steel sleeve test: 20 mm<br />

The product is thus very sensitive.<br />

Hygroscopicity<br />

Hygroskopizität; hygroscopicité<br />

Tendency of a substance to absorb moisture from its surroundings;<br />

specifically, absorption of water vapor from atmosphere.

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