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R. Meyer J. Köhler A. Homburg Explosives

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Nitro-Sugar<br />

Nitro-Sugar<br />

Nitrozucker, Zuckernitrat; nitrate de sucre<br />

Nitro-sugar in its pure form is too unstable to be utilized in practice;<br />

however, during the First World War, a liquid explosive named “Nitrohydren”<br />

was prepared by nitration of solutions of cane sugar in<br />

glycerol and was then further processed into explosives and gunpowders.<br />

However, these mixtures are much more difficult to stabilize than<br />

nitroglycerine alone and are no longer of interest, since glycerin is<br />

freely available.<br />

Nitrotoluene<br />

Nitrotoluol; nitrotoluène<br />

pale yellow liquid<br />

empirical formula: C7H7O2N<br />

molecular weight: 137.1<br />

oxygen balance: –180.9%<br />

nitrogen content: 10.22%<br />

Nitrotoluene is of importance as an intermediate or precursor for in the<br />

manufacture of TNT. There are three isomers, of which only the orthoand<br />

para-isomers can yield pure 2,4,6-trinitrotoluene. “Mononitration”<br />

of toluene yields mostly the orthocompound, as well as 4% of the<br />

meta-, and about 33% of the para-compound.<br />

It is often advantageous to separate the isomers from each other (by<br />

distillation or by freezing out) in the mononitro stage.<br />

3-Nitro-1,2,4-triazole-5-one<br />

Oxynitrotriazole,NTO,ONTA<br />

colorless crystals<br />

empirical formula: C2H2N4O3<br />

molecular weight: 130,1<br />

234

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