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R. Meyer J. Köhler A. Homburg Explosives

R. Meyer J. Köhler A. Homburg Explosives

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Large Hole Blasting<br />

Large Hole Blasting<br />

density: 0,8 g/cm 3<br />

oxygen balance: –1,6%<br />

gas volume: 981 l/kg<br />

specific energy: 1001 kJ/kg<br />

velocity of detonation: 3700 m/s<br />

(steel tube confinement 52/60/1500 mm)<br />

Großbohrloch-Sprengverfahren; sautage à grand trou<br />

In large-scale blasting processes in open pit mining and quarrying,<br />

rows of nearly vertical boreholes are drilled parallel to the quarry face;<br />

the diameter of each borehole is 3–8 in. (in Germany more often<br />

3– 4 in.), while the borehole length is over 12 m. The holes are filled<br />

with explosive and stemmed. W Free-flowing <strong>Explosives</strong> or pumped<br />

W Slurries can be applied.<br />

Lead Acetylsalicylate<br />

Bleiacetylsalicylat; acétylsalicylate de plomb<br />

colorless, fine crystals<br />

empirical formula: C18H14O8Pb·H2O<br />

molecular weight: 583.5<br />

energy of formation: –810 kcal/kg = –3391 kJ/kg<br />

enthalpy of formation: –823 kcal/kg = –3444 kJ/kg<br />

oxygen balance: –98.7%<br />

Lead acetylsalicylate is a combustion-modifying additive, especially so<br />

in W Double Base rocket propellants.<br />

Lead Azide<br />

Bleiazid; azoture de plomb<br />

Pb(N3)2<br />

colorless crystals; microcrystalline<br />

granules, if dextrinated<br />

molecular weight: 291.3<br />

194

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