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R. Meyer J. Köhler A. Homburg Explosives

R. Meyer J. Köhler A. Homburg Explosives

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Nitrocellulose<br />

such as nitroglycerine or TNT. The components are named by nitro:<br />

dinitrotoluene; by carbo: solid carbon carriers as fuel: by nitrate:<br />

ammonium nitrate.<br />

NCN as a classification for dangerous goods has been removed by the<br />

US Department of Transportation and replaced by “Blasting Agent” as<br />

a shipping name (W Blasting Agents).<br />

Nitrocellulose<br />

Nitrocellulose; nitrocellulose; NC<br />

white fibers<br />

empirical formula of the structural unit: C12H14N6O22<br />

nitrogen content referring to the unattainable*) nitration<br />

grade = 14.14%<br />

nitrogen content, practical maximum value: ca. 13.4%<br />

molecular weight of the structure unit:<br />

324.2 + % N/14.14270<br />

energy of formation and enthalpy of formation in relation<br />

to the nitrogen content:<br />

Energy of Formation Enthalpy of<br />

Formation<br />

% N kcal/kg kJ/kg kcal/kg kJ/kg<br />

13.3 –556.1 –2327 –577.4 –2416<br />

13.0 –574.6 –2404 –596.1 –2494<br />

12.5 –605.6 –2534 –627.2 –2624<br />

12.0 –636.5 –2663 –658.4 –2755<br />

11.5 –667.4 –2793 –689.6 –2885<br />

11.0 –698.4 –2922 –720.7 –3015<br />

220<br />

* Nitrogen content > 13.5 % may be reached in the laboratory by use of acid<br />

mixtures with anhydrous phosphoric acid as a component.

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