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R. Meyer J. Köhler A. Homburg Explosives

R. Meyer J. Köhler A. Homburg Explosives

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105 Dinitrosobenzene<br />

energy of formation: +81.2 kcal/kg = +339.6 kJ/kg<br />

enthalpy of formation: +60.3 kcal/kg = +252.1 kJ/kg<br />

oxygen balance: –88.8%<br />

nitrogen content: 28.28%<br />

According to the studies performed by the Bundesanstalt für Materialprüfung,<br />

Germany (BAM), this compound may explode when dry, but<br />

in the presence of 20% water there is no longer any danger of<br />

explosion. It is widely used in analytical organic chemistry for the<br />

preparation of dinitrophenylhydrazon and its derivates from ketones<br />

and aldehydes.<br />

Dinitrosobenzene<br />

Dinitrosobenzol; dinitrosobenzène<br />

empirical formula: C6H4N2O2<br />

molecular weight: 136.1<br />

oxygen balance: –141%<br />

nitrogen content: 20.58%<br />

melting point: decomposition<br />

lead block test: 138 cm3 /10 g<br />

deflagration point: 178–180 °C = 352–355°F<br />

impact sensitivity: 1.5 kp m = 15 N m<br />

friction sensitivity:<br />

up to 36 kp = 353 N pistil load no reaction<br />

critical diameter of steel sleeve test: 2 mm<br />

This substance is explosive despite its low oxygen content. It will<br />

explode in a 1-in steel pipe if actuated by a primer.

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