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R. Meyer J. Köhler A. Homburg Explosives

R. Meyer J. Köhler A. Homburg Explosives

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283 Silver Azide<br />

Shot Firer<br />

Sprengmeister; boutefeu<br />

That qualified person in charge of and responsible for the loading and<br />

firing of a blast (same as a W Blaster).<br />

Shunt<br />

A short-circuiting device provided on the free ends of the leg wires of<br />

electric blasting caps to protect them from accidental initiation by<br />

extraneous electricity.<br />

Silver Acetylide<br />

silver carbide; Silberkarbid; Acetylensilber; acétylure dargent<br />

C2Ag2<br />

molecular weight: 239.8<br />

oxygen balance:–26.7%<br />

deflagration point: 200 °C = 392 °F<br />

Silver carbide is very sensitive to impact. It is prepared by bubbling<br />

acetylene through a slightly acidic or neutral silver nitrate solution.<br />

Silver Azide<br />

Silberazid; azoture dargent<br />

AgN3<br />

molecular weight: 149.9<br />

nitrogen content: 28.03%<br />

volume of detonation gases: 224 l/kg<br />

density: 5.1 g/cm3 melting point: 251 °C = 484 °F<br />

lead block test: 115 cm3 /10 g<br />

deflagration point: 273 °C = 523 °F<br />

Silver azide is sensitive to light, insoluble in water, and soluble in<br />

ammonia, from which it can be recrystallized. It is prepared from<br />

sodium azide and solutions of silver salts (depending on the working<br />

conditions) as a cheesy, amorphous precipitate.<br />

It gives a very satisfactory initiating effect which is superior to that of<br />

lead azide. Nevertheless, its practical use is limited, because of its<br />

high sensitivity to friction, and because its particular texture makes the<br />

dosing difficult.

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