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R. Meyer J. Köhler A. Homburg Explosives

R. Meyer J. Köhler A. Homburg Explosives

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2,4,6-Trinitrophenylnitraminoethyl Nitrate<br />

enthalpy of formation: –208.4 kcal/kg = –871.9 kJ/kg<br />

oxygen balance: – 45.3%<br />

nitrogen content: 17.61%<br />

volume of explosion gases: 878 l/kg<br />

heat of explosion<br />

(H2O liq.): 935 kcal/kg = 3911 kJ/kg<br />

(H2O gas): 906 kcal/kg = 3792 kJ/kg<br />

specific energy: 115 mt/kg =1131 kJ/kg<br />

density: 1.68 g/cm 3<br />

melting point: 104.5 °C = 219.6 °F<br />

lead block test: 350 cm 3 /10 g<br />

detonation velocity, confined:<br />

7600 m/s = 25000ft/s at r = 1.65 g/cm 3<br />

deflagration point: >300 °C = >570 °F<br />

impact sensitivity: 0.8 kp m = 7.9 N m<br />

The compound is insoluble in water, but soluble in acetone and<br />

toluene. It is very stable and gelatinizes nitrocellulose on heating.<br />

It is prepared by nitration of the corresponding dinitro compound.<br />

2,4,6-Trinitrophenylnitraminoethyl Nitrate<br />

Trinitrophenylethanolnitraminnitrat; nitrate de<br />

trinitrophenylnitramineéthyl; Pentryl<br />

yellowish crystals<br />

empirical formula: C8H6N6O11<br />

molecular weight: 362.2<br />

oxygen balance: –35.4%<br />

nitrogen content: 23.19%<br />

density: 1.75 g/cm 3<br />

melting point: 128 °C = 262 °F<br />

lead block test: 450 cm 3 /10 g<br />

deflagration point: 235 °C = 455 °F<br />

impact sensitivity: 0.4 kp m = 4 N m<br />

354<br />

The compound is soluble in water, sparingly soluble in common organic<br />

solvents, but is soluble in nitroglycerine. Its stability is satisfactory,<br />

but one of the five NO2-groups in the molecule is a nitrate<br />

rather than a nitro group, so that the compound cannot be as stable as<br />

e.g., TNT.

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