R. Meyer J. Köhler A. Homburg Explosives

333 Thermodynamic Calculation of Decomposition Reactions
Table 38. Molar internal enthalpies of reaction products ¯cv (T-To); To = 25 °C ≈ 300 K.
CO CO2 H2O H2 O2 N2 NO
Tempera-
kJ
/mol
kcal
/mol
kJ
/mol
kcal
/mol
kJ
/mol
kcal
/mol
kJ
/mol
kcal
/mol
kJ
/mol
kcal
/mol
kJ
/mol
kcal
/mol
kJ
/mol
kcal
/mol
ture
K
700 4.99 20.89 7.68 32.16 5.98 25.04 4.75 19.89 5.22 21.85 4.93 20.64 5.11 21.39
900 6.60 27.63 10.33 43.25 8.00 33.49 6.21 26.00 6.91 28.93 6.52 27.29 6.75 28.30
1100 8.24 34.50 13.04 54.59 10.12 42.37 7.71 32.28 8.62 36.09 8.14 34.00 8.43 35.29
1200 9.08 38.01 14.43 60.41 11.22 46.98 8.47 35.46 9.49 39.73 8.97 37.55 9.28 38.86
1300 9.92 41.53 15.84 66.32 12.34 51.67 9.25 38.73 10.36 43.38 9.81 41.07 10.14 42.46
1400 10.78 45.14 17.25 72.23 13.48 56.44 10.04 42.03 11.25 47.10 10.65 44.59 11.01 46.10
1500 11.62 48.66 18.70 78.30 14.45 60.50 11.06 46.31 12.54 52.50 11.50 48.15 11.95 50.03
1600 12.47 52.21 20.07 84.03 15.56 65.15 11.77 49.28 13.30 55.69 12.33 51.63 12.79 53.55
1700 13.32 55.77 21.46 89.86 16.71 69.96 12.50 52.33 14.10 59.04 13.17 55.14 13.64 57.11
1800 14.16 59.29 22.85 95.67 17.87 74.82 13.26 55.52 14.91 62.43 14.00 58.62 14.49 60.67
1900 15.03 62.93 24.28 101.66 19.06 79.80 14.04 58.79 15.76 65.99 14.87 62.26 15.36 64.31
2000 15.81 66.20 25.73 107.73 20.29 84.91 14.84 62.14 16.63 69.63 15.73 65.86 16.23 67.96
2100 16.77 70.22 27.19 113.84 21.51 90.06 15.66 65.57 17.51 73.31 16.60 69.50 17.11 71.64
2200 17.65 73.90 28.66 120.00 22.79 95.42 16.49 69.04 18.41 77.08 17.47 73.15 17.99 75.32
2300 18.54 77.63 30.16 126.28 24.01 100.53 17.33 72.56 19.32 80.89 18.35 76.83 18.88 79.05
2400 19.42 81.31 31.62 132.39 25.28 105.85 18.19 76.16 20.24 84.74 19.23 80.52 19.78 82.82
2500 20.30 85.00 33.11 138.63 26.54 111.12 19.04 79.72 21.16 88.60 20.11 84.20 20.66 86.50
2600 21.19 88.72 34.61 144.91 27.83 116.52 19.91 83.36 22.11 92.60 20.99 87.90 21.56 90.27
2700 22.09 92.49 36.12 151.23 29.12 121.93 20.78 87.01 23.06 96.55 21.88 91.61 22.46 94.04
2800 22.98 96.22 37.63 157.56 30.42 127.37 21.67 90.73 24.01 100.53 22.77 96.34 23.36 97.81
2900 23.88 99.99 39.15 163.92 31.73 132.85 22.55 94.42 24.97 104.55 23.67 99.11 24.27 101.62
3000 24.78 103.75 40.68 170.33 33.04 138.34 23.48 98.31 25.94 108.61 24.56 102.83 25.17 105.39
3100 25.68 107.52 42.21 176.73 34.36 143.87 24.34 101.91 26.91 112.67 25.46 106.60 26.08 109.20