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R. Meyer J. Köhler A. Homburg Explosives

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Thermodynamic Calculation of Decomposition Reactions<br />

Table 33. (continued)<br />

Component Empirical Enthalpy Enthalpy Energy Energy Number of Atoms per kilogram Uses<br />

Formula of Forma- of Formationof Forma- of Formation<br />

tiontion<br />

kcal/kg kJ/kg kcal/kg kJ/kg C H O N<br />

sodium nitrate O3NNa –1315 – 5506 –1301 – 5447 – –35.29 11.76 Na.<br />

11.76 (5);<br />

(16)<br />

tetranitromethane CN4O8 + 46.9 + 196.4 + 65.0 + 272.1 5.10 – 40.81 20.40<br />

Tetryl C7H5O8N5 + 16.7 + 67.9 + 35.3 + 147.6 24.40 17.40 27.86 17.40 (2)<br />

TNT (trinitrotoluene) C7H5O6N3 – 70.6 – 295.3 – 52.4 – 219.0 30.82 22.01 26.40 13.20 (2)<br />

toluene<br />

C9H6O2N2 – 179.7 – 752 – 162.7 – 681 51.71 34.47 11.49 11.49 (12)<br />

diisocyanate (TDI)<br />

triaminoguanidine nitrate CH9N7O3 – 68.8 – 287.9 – 35.2 – 147.2 5.98 53.86 17.95 41.89 (4)<br />

triaminotrinitrobenzene C6H6N6O6 – 129.4 – 541.3 – 108.7 – 455.0 23.25 23.25 23.25 23.25 (2); (4)<br />

trimethylamine nitrate C3H10O3N2 – 673.1 – 2816 – 636.7 – 2664 24.57 81.90 24.57 16.38 (17)<br />

1,3,3-trinitroazetidine (TNAZ) C3H4N4O6 + 45.29 + 189.50 + 66.84 + 279.77 15.62 20.82 31.23 20.82 (2)<br />

trinitrobenzene C5H3O5N3 – 48.8 – 204 – 32.1 – 135 28.15 14.08 28.15 14.08 (2)<br />

trinitrochlorobenzene C6H2O6N3Cl + 25.9 + 108 + 40.4 + 169 24.24 8.08 24.24 12.12 Cl:<br />

4.04 (2)<br />

trinitropyridine C5H2O6N4 + 88,0 + 368.5 + 104.6 + 437.9 23.35 9.34 28.03 18.68 (2)<br />

trinitropyridine-1-oxide C5H2O7N4 + 102.5 + 428.9 + 119.2 + 499.1 21.73 8.69 30.42 17.38 (2)<br />

trinitroresorcinol C6H3O8N3 – 510.0 – 2134 – 493.1 – 2063 24.48 12.24 32.64 12.24 lead<br />

(styphnic acid) salt<br />

urea CH4ON2 –1326 – 5548 –1291 – 5403 16.65 66.60 16.65 33.30 (5); (17)<br />

urea nitrate CH5O4N3 –1093 – 4573 –1064 – 4452 8.12 40.62 32.49 24.37<br />

water H2O –3792 –15880 –3743 –15670 – 111.01 55.51 – (17)<br />

wood dust –1116 – 4672 –1090 – 4564 41.7 60.4 27.4 – (6)<br />

328

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