R. Meyer J. Köhler A. Homburg Explosives

331 Thermodynamic Calculation of Decomposition Reactions
Table 37. Molar internal energies of reaction products ¯cv (T-To); To = 25 °C ≈ 300 K.
CO CO2 H2O H2 O2 N2 NO C*)
kJ
/mol
kcal
/mol
kJ
/mol
kcal
/mol
kJ
/mol
kcal
/mol
kJ
/mol
kcal
/mol
kJ
/mol
kcal
/mol
kJ
/mol
kcal
/mol
kJ
/mol
kcal
/mol
kJ
/mol
kcal
/mol
Temperature
K
1000 3.65 15.28 6.34 26.55 4.64 19.43 3.41 14.28 4.33 18.13 3.59 15.03 3.77 15.78 3.31 13.86
1200 4.86 20.35 8.59 35.97 6.26 26.21 4.47 18.72 5.62 23.53 4.78 20.01 5.02 21.02 4.33 18.13
1400 6.11 25.35 10.91 45.68 7.99 33.45 5.58 23.36 6.93 29.02 6.01 25.16 6.30 26.38 5.32 22.27
1500 6.75 28.26 12.10 50.66 8.89 37.22 6.14 25.71 7.58 31.74 6.64 27.80 6.95 29.10 5.88 24.62
1600 7.39 30.94 13.31 55.73 9.81 41.07 6.72 28.14 8.22 34.42 7.28 30.48 7.61 31.86 6.38 28.71
1700 8.05 33.71 14.51 60.75 10.75 45.01 7.31 30.61 8.67 36.30 7.92 33.16 8.28 34.67 6.92 28.97
1800 8.69 36.39 15.77 66.03 11.52 48.23 8.13 34.04 9.61 40.24 8.57 35.88 9.02 37.77 7.48 31.32
1900 9.34 39.11 16.94 70.92 12.43 52.04 8.64 36.17 10.17 42.58 9.20 38.52 9.66 40.44 7.95 33.27
2000 19.99 41.83 18.13 75.91 13.38 56.02 9.17 38.39 10.77 45.09 9.84 41.20 10.31 43.16 8.46 35.42
2100 10.64 44.55 19.33 80.93 14.35 60.08 9.74 40.78 11.39 47.68 10.49 43.92 10.97 45.93 8.94 37.43
2200 11.31 47.35 20.56 86.08 15.34 64.22 10.32 43.20 12.04 50.41 11.15 46.68 11.64 48.73 9.53 39.90
2300 11.98 50.16 21.81 91.31 16.36 68.49 10.92 45.72 12.71 53.21 11.81 49.44 12.31 51.54 10.10 42.28
2400 12.65 52.97 23.07 96.59 17.39 72.81 11.54 48.31 13.39 56.06 12.48 52.25 12.99 54.38 10.68 44.71
2500 13.33 55.81 24.34 101.91 18.43 77.16 12.17 50.95 14.09 58.99 13.15 55.05 13.67 57.23 11.28 47.22
2600 14.02 58.70 25.61 107.22 19.49 81.60 12.81 53.63 14.80 61.96 13.83 57.90 14.36 60.12 11.88 49.74
2700 14.70 61.55 26.90 112.63 20.56 86.08 13.47 56.39 15.52 64.98 14.51 60.75 15.06 63.05 12.50 52.32
2800 15.39 64.44 28.20 118.07 21.63 90.56 14.13 49.16 16.25 68.03 15.20 63.64 15.75 65.94 13.12 54.93
2900 16.08 67.33 29.50 123.51 22.72 95.12 14.80 61.96 17.00 71.17 15.88 66.48 16.45 68.87 13.75 57.57
3000 16.78 70.26 30.81 129.00 23.81 99.69 15.47 64.77 17.75 74.31 16.57 69.37 17.15 71.80 14.30 59.87
3100 17.47 73.15 32.12 134.48 24.91 104.29 16.16 67.66 18.50 77.45 17.26 72.26 17.85 74.73 15.04 62.97
3200 18.17 76.08 33.44 140.01 26.02 108.94 16.84 70.50 19.26 80.64 17.96 75.19 18.56 77.71 15.69 65.69
3300 18.87 79.01 34.77 145.58 27.13 113.59 17.54 73.43 20.03 83.86 18.65 78.08 19.26 80.64 16.35 68.45
3400 19.57 81.94 36.10 151.15 28.25 118.28 18.23 76.32 20.80 87.08 19.35 81.01 19.97 83.61 17.01 71.22
3500 20.27 84.87 37.43 156.71 29.37 122.97 18.93 79.25 21.58 90.35 20.05 83.94 20.68 86.58 17.67 73.98
3600 20.97 87.86 38.76 162.28 30.50 127.70 19.64 82.23 22.37 93.66 20.74 86.83 21.39 89.55 18.34 76.78