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R. Meyer J. Köhler A. Homburg Explosives

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101 Dinitrodioxyethyloxamide Dinitrate<br />

Dinitrodimethyloxamide<br />

Dinitrodimethyloxamid; dinitrodiméthyloxamide<br />

colorless needles<br />

empirical formula: C4H6N4O6<br />

molecular weight: 206.1<br />

energy of formation: –331.2 kcal/kg = –1385.8 kJ/kg<br />

enthalpy of formation: –354.2 kcal/kg = –1482.0 kJ/kg<br />

oxygen balance: –38.8%<br />

nitrogen content: 27.19%<br />

density: 1.523 g/cm3 lead block test: 360 cm3 /10 g<br />

detonation velocity, confined: 7100 m/s = 23300 ft/s<br />

at r = 1.48 g/cm3 impact sensitivity: 0.6 kp m = 6 N m<br />

The compound is insoluble in water, sparingly soluble in ether and<br />

chloroform and soluble in acetone. It is chemically stable.<br />

It is prepared by nitration of dimethyloxamide with a sulfuric acidnitric<br />

acid mixture.<br />

Dinitrodioxyethyloxamide Dinitrate<br />

Dinitrodioxiethyloxamiddinitrat, Dinitrodiethanoloxamiddinitrat, Neno;<br />

dinitrate de dioxyéthyl-dinitroxamide; N, N'-dinitro-N, N' bis (2-hydroxyethyl)-oxamide<br />

dinitrate<br />

colorless flakes<br />

empirical formula: C6H8N6O12<br />

molecular weight: 356.2<br />

energy of formation: –355.5 kcal/kg = –1487.2 kJ/kg<br />

enthalpy of formation: –377.1 kcal/kg = –1577.7 kJ/kg<br />

oxygen balance: –18.0%<br />

nitrogen content: 23.60%<br />

melting point: 88 °C = 190°F<br />

This compound is readily soluble in acetone and in hot alcohol, and is<br />

insoluble in cold water. It is prepared by nitration of diethanoloxamide,<br />

the latter being prepared by condensation of monoethanolamine with<br />

oxalic acid.

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