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R. Meyer J. Köhler A. Homburg Explosives

R. Meyer J. Köhler A. Homburg Explosives

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253 Picratol<br />

Picramic Acid<br />

Dinitroaminophenol; acide picramique<br />

empirical formula: C6H5N3O5<br />

molecular weight: 199.1<br />

energy of formation: –279 kcal/kg = –1167 kJ/kg<br />

enthalpy of formation: –298 kcal/kg = –1248 kJ/kg<br />

oxygen balance: –76.3%<br />

nitrogen content: 21.11%<br />

volume of explosion gases: 847 l/kg<br />

heat of explosion<br />

(H2O liq.): 639 kcal/kg = 2674 kJ/kg<br />

specific energy: 68.2 mt/kg = 669 kJ/kg<br />

melting point: 169.9 °C = 337.8 °F<br />

lead block test: 166 cm3 /10 g<br />

deflagration point: 240 °C = 464 °F<br />

impact sensitivity: 3.5 pm m = 34 N m<br />

friction sensitivity: up to 36 kp = 353 N<br />

pistil load no reaction<br />

critical diameter of steel sleeve test: 2.5 mm<br />

Diazotization of picramic acid yields W Diazodinitrophenol (DDNP).<br />

Lead picramate and DDNP are W Initiating <strong>Explosives</strong>.<br />

Picratol<br />

A 52:48 mixture of ammonium picrate and TNT was used as a bomb<br />

filling in the Second World War.<br />

casting density: 1.62 g/cm3 detonation velocity,<br />

at casting density, confined: 22600ft/s

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