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R. Meyer J. Köhler A. Homburg Explosives

R. Meyer J. Köhler A. Homburg Explosives

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103 Dinitroorthocresol<br />

molecular weight: 218.2<br />

energy of formation:<br />

1,5–isomer: +49.7 kcal/kg = +208.1 kJ/kg<br />

1,8–isomer: +57.5 kcal/kg = +240.7 kJ/kg<br />

enthalpy of formation:<br />

1,5–isomer: +33.5 kcal/kg = +140.0 kJ/kg<br />

1,8–isomer: +41.25 kcal/kg = +172.6 kJ/kg<br />

oxygen balance: –139.4%<br />

nitrogen content: 12.84%<br />

volume of explosion gases: 488 l/kg<br />

heat of explosion (H2O liq.):<br />

1,5–isomer: 725 kcal/kg = 3031 kJ/kg<br />

1,8–isomer: 732 kcal/kg = 3064 kJ/kg<br />

specific energy: 58 mt/kg = 569 kJ/kg<br />

melting point: 1,5–isomer: 216 °C = 421°F<br />

1,8–isomer: 170 °C = 338°F<br />

deflagration point: 318 °C = 605°F<br />

This material is prepared by a two-step nitration of naphthalene with<br />

nitric acid. The commercial product, which is a mixture of isomers,<br />

melts above 140 °C = 276°F. It is readily soluble in benzene, xylene,<br />

and acetone and is sparingly soluble in alcohol and ether. It has been<br />

used in French explosive mixtures (schneiderites) as fuel mixed with<br />

ammonium nitrate.<br />

Dinitroorthocresol<br />

Dinitro-o-kresol; dinitroorthocrésol<br />

yellow crystals<br />

empirical formula: C7H6N2O5<br />

molecular weight: 198.1<br />

energy of formation: –221.8 kcal/kg = –928.1 kJ/kg<br />

enthalpy of formation: –241.3 kcal/kg = –1009.4 kJ/kg<br />

oxygen balance: –96.9%<br />

nitrogen content: 14.51%<br />

volume of explosion gases: 832 l/kg<br />

heat of explosion (H2O liq.): 724 kcal/kg = 3027 kJ/kg<br />

specific energy: 70.5 mt/kg = 691 kJ/kg<br />

melting point: 86 °C = 187°F<br />

impact sensitivity: up to 5 kp m = 50 N m no reaction

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