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Carbon Nanotube Reinforced Composites: Metal and Ceramic ...

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Figure 4.4 SEM micrographs showing tensile fracture surfaces of<br />

(a) 2024 Al/1 wt% MWNT <strong>and</strong> (b) 2024 Al/2 wt% MWNT<br />

nanocomposites. Reproduced with permission from [Chap. 2,<br />

Ref. 35]. Copyright Ó (2007) Elsevier.<br />

elongation of nanocomposites remains nearly unchanged by adding nanotubes up<br />

to 1 wt%; this is due to the superior flexibility of CNTs. As a result, CNTs can bridge<br />

advancing crack during tensile deformation, thereby improving the tensile ductility<br />

of nanocomposites having nanotube content 1 wt% (Figure 4.4(a)). On the other<br />

h<strong>and</strong>, pull-out of nanotubes can be readily seen in the fracture surface of 2024 Al/2 wt<br />

% MWNT nanocomposite, indicating poor interfacial nanotube–matrix bonding<br />

strength (Figure 4.4(b)).<br />

Nanocrystalline metals generally exhibit limited tensile plasticity due to a lack<br />

of work hardening capability. Therefore, cracks are readily initiated in nanocrystalline<br />

metals during the earlier stage of tensile deformation. Figure 4.5 shows typical tensile<br />

true stress–strain curve of nanocrystalline Al prepared by extruding ball-milled<br />

powders [18]. Apparently, nanocrystalline Al exhibits a high mechanical strength of<br />

Figure 4.5 Tensile true stress–strain curves of nanocrystalline<br />

(nc) Al <strong>and</strong> its composite reinforced with 0.7 vol% SWNT. These<br />

materials were prepared by hot extrusion of ball-milled powders.<br />

Reproduced with permission from [18]. Copyright Ó (2007)<br />

Elsevier.<br />

4.2 Tensile Deformation Behaviorj109

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