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Carbon Nanotube Reinforced Composites: Metal and Ceramic ...

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70j 2 <strong>Carbon</strong> <strong>Nanotube</strong>–<strong>Metal</strong> Nanocomposites<br />

Figure 2.23 (a) Appearances of spark plasma sintered copper,<br />

Cu/5 vol% MWNT <strong>and</strong> Cu/10 vol% MWNT nanocomposites;<br />

(b) SEM image of etched Cu/5 vol% MWNT nanocomposite<br />

showing homogeneous distribution of CNTs within copper matrix.<br />

Reproduced with permission from [87]. Copyright Ó (2007)<br />

Elsevier.<br />

the Cu/10 vol% MWNT composite powder even after reduction of CuO matrix<br />

in hydrogen.<br />

Xu et al. also fabricated Cu/MWNT spherical powders by mixing Cu ions<br />

with functionalized MWNTs at the molecular level [90]. They managed to produce<br />

Cu/MWNT composite powders having much finer sizes of 200–300 nm.<br />

The MWNTs were dispersed ultrasonically in a gelatin solution followed by adding<br />

Figure 2.24 Schematic diagrams showing (a) oxygen atoms in<br />

CuO matrix <strong>and</strong> functionalized MWNTs; (b) residual oxygen<br />

atoms at the nanotube-Cu interface after reduction process; (c)<br />

homogeneous dispersion of nanotubes in Cu matrix after<br />

consolidation. Reproduced with permission from [89]. Copyright<br />

Ó (2008) Wiley-VCH Verlag GmbH.

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