Carbon Nanotube Reinforced Composites: Metal and Ceramic ...

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5 Carbon Nanotube–Ceramic Nanocomposites 131 5.1 Overview 131 5.2 Importance of Ceramic-Matrix Nanocomposites 133 5.3 Preparation of Ceramic-CNT Nanocomposites 136 5.4 Oxide-Based Nanocomposites 138 5.4.1 Alumina Matrix 138 5.4.1.1 Hot Pressing/Extrusion 138 5.4.1.2 Spark Plasma Sintering 142 5.4.1.3 Plasma Spraying 147 5.4.1.4 Template Synthesis 149 5.4.2 Silica Matrix 150 5.4.3 Titania Matrix 155 5.4.4 Zirconia Matrix 156 5.5 Carbide-Based Nanocomposites 157 5.5.1 Silicon Carbide Matrix 157 5.6 Nitride-Based Nanocomposites 160 5.6.1 Silicon Nitride Matrix 160 References 161 6 Physical Properties of Carbon Nanotube–Ceramic Nanocomposites 169 6.1 Background 169 6.2 Electrical Behavior 171 6.3 Percolation Concentration 172 6.4 Electromagnetic Interference Shielding 177 6.5 Thermal Behavior 179 References 182 7 Mechanical Properties of Carbon Nanotube–Ceramic Nanocomposites 185 7.1 Fracture Toughness 185 7.2 Toughening and Strengthening Mechanisms 187 7.3 Oxide-Based Nanocomposites 189 7.3.1 Alumina Matrix 189 7.3.1.1 Deformation Behavior 189 7.3.2 Silica Matrix 200 7.4 Carbide-Based Nanocomposites 201 7.5 Nitride-Based Nanocomposites 205 7.6 Wear Behavior 207 References 212 8 Conclusions 215 8.1 Future Prospects 215 8.2 Potential Applications of CNT–Ceramic Nanocomposites 217 Contents VII
VIII Contents 8.2.1 Hydroxyapatite–CNT Nanocomposites 218 8.3 Potential Applications of CNT–Metal Nanocomposites 223 References 224 Index 227
Page 2 and 3: Sie Chin Tjong Carbon Nanotube Rein
Page 4 and 5: Sie Chin Tjong Carbon Nanotube Rein
Page 6 and 7: Contents Preface IX List of Abbrevi
Page 10: Preface Carbon nanotubes are nanost
Page 13 and 14: XII List of Abbreviations HIP hot i
Page 16 and 17: 1 Introduction 1.1 Background Compo
Page 18 and 19: Figure 1.2 Transmission electron mi
Page 20 and 21: 1.3 Synthesis of Carbon Nanotubes 1
Page 22 and 23: MWNTs can be as high as 70% of the
Page 24 and 25: Figure 1.7 In situ TEM images recor
Page 26 and 27: 1.3 Synthesis of Carbon Nanotubesj1
Page 28 and 29: show TEM images of MWNTs synthesize
Page 30 and 31: Since then, large efforts have been
Page 32 and 33: 1.3.4 Patent Processes Carbon nanot
Page 34 and 35: 1.4 Purification of Carbon Nanotube
Page 36 and 37: Table 1.3 Patent processes for the
Page 38 and 39: Figure 1.13 Schematic illustration
Page 40 and 41: 1.5 Mechanical Properties of Carbon
Page 42 and 43: Figure 1.14 Carbon nanotubes in hig
Page 44 and 45: Figure 1.15 In situ tensile deforma
Page 46 and 47: Table 1.7 Theoretical and experimen
Page 48 and 49: Nomenclature ~a 1 , ~a 2 Unit vecto
Page 50 and 51: carbon nanotubes. Physical Review L
Page 52 and 53: 70 Jang, I., Uh, H.S., Cho, H.J., L
Page 54 and 55: 108 Shelimov, K.B., Esenaliev, R.O.
Page 56 and 57: Bonnamy, S., Beguin, F., Burnham, N
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2 Carbon Nanotube-Metal Nanocomposi
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isostatic pressing. In certain case
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This implies the absence of effecti
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coating material, the plasma gun an
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Table 2.4 Changes in the size and v
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Figure 2.6 (a) Low and (b) high mag
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Figure 2.8 SEM micrographs showing
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Figure 2.11 Bright field TEM microg
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Figure 2.13 TEM image of bulk Al/5
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2.5 Magnesium-Based Nanocomposites
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limited improvement in ultimate ten
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Figure 2.18 SEM micrographs of the
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Figure 2.19 (a) Low and (b) high ma
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Figure 2.22 SEM micrographs of (a)
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Figure 2.25 (a) TEM micrograph show
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2.8 Transition Metal-Based Nanocomp
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Figure 2.27 TEM image of electrodep
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Figure 2.29 SEM micrographs of (a)
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Figure 2.31 Schematic representatio
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einforcement content SiCp/Al compos
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Materials Science Forum, 534-536 (P
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composite. Materials Science and En
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111 Cha, S.I., Kim, K.T., Arshad, S
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90j 3 Physical Properties of Carbon
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100j 3 Physical Properties of Carbo
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104j 4 Mechanical Characteristics o
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132j 5 Carbon Nanotube-Ceramic Nano
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186j 7 Mechanical Properties of Car
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Table 8.1 Patent processes for maki
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218j 8 Conclusions development of c
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220j 8 Conclusions Figure 8.2 TEM m
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222j 8 Conclusions increase in Vick
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224j 8 Conclusions References 1 Cha
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226j 8 Conclusions nano-matrix. Scr
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228j Index l laser ablation 7 load
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