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Intégration des paramètres spatio-temporels et des risques d ...

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tel-00783708, version 1 - 1 Feb 2013<br />

<strong>Intégration</strong> <strong>des</strong> <strong>paramètres</strong> <strong>spatio</strong>-<strong>temporels</strong> <strong>et</strong> <strong>des</strong> <strong>risques</strong> d'accident à l'Analyse du Cycle de Vie<br />

ENVIRONMENT-EXPOSURE<br />

DEGRADATION AND TRANSFORMATION<br />

Characterization of biodegradability Not biodegradable<br />

Readily biodegradable S<br />

Degradation calculation m<strong>et</strong>hod in STP First order, standard OECD/EU tests<br />

First order, standard<br />

OECD/EU tests D<br />

Rate constant for biodegradation in STP 0 24 [d-1] O<br />

Rate constant for biodegradation in surface water 0 0.0462 [d-1] (12[oC]) O<br />

Rate constant for biodegradation in bulk soil 6.93E-07 0.0231 [d-1] (12[oC]) O<br />

Rate constant for biodegradation in aerated sediment 6.93E-07 0.0231 [d-1] (12[oC]) O<br />

Rate constant for hydrolysis in surface water 6.93E-07 6.93E-07 [d-1] (12[oC]) O<br />

Rate constant for photolysis in surface water 6.93E-07 6.93E-07 [d-1] O<br />

ENVIRONMENT-EXPOSURE<br />

DISTRIBUTION<br />

LOCAL SCALE<br />

[1 "", IC=15/UC=55][PRODUCTION]<br />

Concentration in air during emission episode 0 1.39E-06 [mg.m-3] O<br />

Annual average concentration in air, 100 m from point source 0 3.81E-09 [mg.m-3] O<br />

Concentration in surface water during emission episode (dissolved) ?? ?? [mg.l-1] O<br />

Annual average concentration in surface water (dissolved) ?? ?? [mg.l-1] O<br />

Local PEC in surface water during emission episode (dissolved) ?? ?? [mg.l-1] O<br />

Annual average local PEC in surface water (dissolved) ?? ?? [mg.l-1] O<br />

Local PEC in fresh-water sediment during emission episode ?? ?? [mg.kgwwt-1] O<br />

Concentration in seawater during emission episode (dissolved) ?? ?? [mg.l-1] O<br />

Annual average concentration in seawater (dissolved) ?? ?? [mg.l-1] O<br />

Local PEC in seawater during emission episode (dissolved) ?? ?? [mg.l-1] O<br />

Annual average local PEC in seawater (dissolved) ?? ?? [mg.l-1] O<br />

Local PEC in marine sediment during emission episode ?? ?? [mg.kgwwt-1] O<br />

Local PEC in agric. soil (total) averaged over 30 days ?? ?? [mg.kgwwt-1] O<br />

Local PEC in agric. soil (total) averaged over 180 days ?? ?? [mg.kgwwt-1] O<br />

Local PEC in grassland (total) averaged over 180 days ?? ?? [mg.kgwwt-1] O<br />

Local PEC in groundwater under agricultural soil ?? ?? [mg.l-1] O<br />

ENVIRONMENT-EXPOSURE<br />

DISTRIBUTION<br />

REGIONAL AND CONTINENTAL SCALE<br />

REGIONAL<br />

Regional PEC in surface water (dissolved) ?? ?? [mg.l-1] O<br />

Regional PEC in seawater (dissolved) ?? ?? [mg.l-1] O<br />

Regional PEC in air (total) ?? 0 [mg.m-3] S<br />

Regional PEC in agricultural soil (total) ?? ?? [mg.kgwwt-1] O<br />

Regional PEC in pore water of agricultural soils ?? ?? [mg.l-1] O<br />

Regional PEC in natural soil (total) ?? ?? [mg.kgwwt-1] O<br />

Regional PEC in industrial soil (total) ?? ?? [mg.kgwwt-1] O<br />

Regional PEC in sediment (total) ?? ?? [mg.kgwwt-1] O<br />

Regional PEC in seawater sediment (total) ?? ?? [mg.kgwwt-1] O<br />

332

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