Material Safety Data Sheets Collection:Genium Publishing CorporationOne Genium Plaza Sheet No. 318Schenecmiy, NY 123044690 USA Xylene (Mired Isomers)6 P(518) 377-88S4Issued: 1 l/80 Revision: E. 9192ji.Section 1. Material Identifkation 39Xylene (Mixed Isomers) (C,$tJ Description: The commercial product is a bknd of the three isomer [onho-( mete-(m- R 1 NFPA). paw@-)] with the largest proportion being m- xylene. Xylene is obtained from coal tar, mluene by tmmalkylation, <strong>and</strong>pseutiumene. Used in the manufacture of dyes, resins, paints, varnishes, <strong>and</strong> other organics; as a general solvent <strong>for</strong>adhesivs, a cleaning agent in microscope technique; as a solvent <strong>for</strong> Canada balsam microscopy. as a fuel component; inaviation gasoline, protective coatings, sterilizing catgut hydrogen peroxide, perfumes, insect repellam& phatmaceuticals, <strong>and</strong>the leather industry; in the production of phthalic anhydride, isophthalic. <strong>and</strong> terephthalic acids <strong>and</strong> their dimethyl esterswhich am used in the manufacture of polyester Tibet <strong>and</strong> as an indirect food additive as a component of adhesives. Aroundthe home, xylene is found as vehicles in paints, paint removers. degreasing clearws. lacquers, glues <strong>and</strong> cements <strong>and</strong> assolvent/vehicles <strong>for</strong> pesticides.other Designations: CAS No. 1330-20-7 t95-474 108-38-3; 106-42-3 (6, m-. p-isomers)]. dimethylbenxene,methyltoluene. NCECSS232. Violet 3, xylol.Manufacturer: Contact your supplier or distributor. Consult latest Chemical Week BUJWS' Guide) <strong>for</strong> a suppliers listCautions: Xylene is an eye, skin. <strong>and</strong> mucous membrane irritant <strong>and</strong> may be narcotic in high concentmtions. It is a dangerous fire hazard. * Sec.;Section 2. Ingredients <strong>and</strong> Occupational Exposure LimitsPPE $t ckoaicEffects*Xylene (mixed isomers): the commercial product generally contains - 40% m-xylene; 20% each of o-xylene. p-xylene, <strong>and</strong> ethylbenzene; <strong>and</strong> smallquantities of toluene. Unptied xylene may contain pseudocumene.I991 OSHA PELS 1992-93 ACGIH TLVs 1985-86 Toxicity Data*8-hr TWA: 100 ppm (435 mglm3) TWA: 100 ppm (434 mg/m? HW inhalation, TC,: 200 ppm producedSmin STEL: 150 ppm (655 mg/m31 87~~: ISO ppm (651 mg/m ) olfaction effects, conjunctiva irritation+ <strong>and</strong> otherBE1 (Biological Exposure Index): Methylbippuric ChangeJ involving the lungs, thorax+ or respiration.1990 IDLH Leveltidsinurineatendofshiftz1Jg/gQeatinine hfau. inhalation, la&,: 10000 ppm/6 hr. toxic1000 wmeffects not yet reviewed.1990 DFG (Germany) MAKl990 NIOSH RELsTWA: 100 ppm (440 mg/m3)Human, oral, L&: SO mgkg; no toxic effect noted.TWA: 100 ppm (435 mg/m? cat&g$~ ~2s~bsmlces wllb systemic effects&zl..Dss: 4300 mg/kg; toxic effect not yet8TEL: 150 ppm (655 mg/m )Peai&mrc 200 ppm 30 min, average value.Rat inhaktiolb LC& 5000 ppml4 hr toxic effects4peakspershiimt yet reviewed.* *Wdbi b;f;yJ$; ;i;+(& :cj;-~-&&;J’F (138.8‘c);paw- 281.3 ‘F (1385 ‘C)Freezing Point/Melting Point: orfho: - 13 ‘F (-25 ‘C);----- =* = *=’ 47.4 ‘c); punx 55 to 57 -F(13 to 14 ‘C)5.72 mm Hg at 70 ‘F (21‘C)~~&I~&& Density (Air = 1.2 kglm’): 1.23 kg/m3, 0.077 lb&Appearance <strong>and</strong> Odor: Clear, sweet-smelling liquid.l Msterials with wider aad PatroWer boilillg raaga are commemislly svailsble.Section 4, Fire <strong>and</strong> ExDio!sion DataMolecular Weigbtz 106.16Speeifk Gravity: 0.864 at 20 l U4 ‘CWater Solnbility: Practically insolubleOther Sohsbiit.k~: Miscible with absolute alcohol, ether, <strong>and</strong>many other organic liquids.OetanoVW’ater Partition Coefficient: 1ogKow = 3.12-3.20Odor Tbresheldr 1 ppmViscosity: 42.6 SUSFlash Point: 63 to 77 ‘F (17 to 2; ‘C) CC \Autoignition Tempera- 982 ‘F (527 ‘C) (m-) ILEL: 1.1 (m-.p); 0.9 (e) IUEL: 7.0 (m-, p-); 6.7 (o-)Extinguishing Media: For small fires, use dry chemical. carbon dioxide (CO& water spray or regular foam. Por large fires, use water spray, fog orrem&r foam. Water may be ineffective. Use water spray to cool f-exposed containur. Unumal Fur or Explosion H-r&: Xylene vapors orlit& (which floats on water) may travel to an ignition source <strong>and</strong> flash back. The heat of fa may cause containers.to explode <strong>and</strong>/or producehritating or poisonous decomposition products. Xylene may present a vapor explosion hazard indoors, outdoom, or m sewers. Accumulated staticelectricity may occur from vapor or liquid flow sufficiento cause ignition. Qeclal Fireflgbthtg Procedures: Because fire may produce toxicthermal decomposition products. wear a self-contained breathing apparatus (SCBA) with a full faapiece operated in pressure-dem<strong>and</strong> or positivepressuremode. Structural fuefighter’s protective clothing will provide limited protection. If feasibk ad without risk, move containers from fue arcaOthenvke, cool he-exposed containers until well after fue is extinguished. Stay clear of tank ends. Use u nmanned hose holder or monitor nozzles <strong>for</strong>massive cargo fires. If impossible, withdmw from area <strong>and</strong> let fire bum. Withdraw immediately in case of any tank discoloration or rising sound fromventing safety device. Do not release runoff from fire control methods to sewers or waterways.Section 5. Reactivity DataStability/Polymerization: Xylene is stable at mom temperature in closed containets under normal storage <strong>and</strong> h<strong>and</strong>ling conditions. Hazardouspolymerization cannot occur. Xylem is easily chlorinated. sulfonated. or nihated. chemical Incempatibllities: Incompatibilities include strongacids <strong>and</strong> oxidizers <strong>and</strong> 1.3-dichloto-SJdimethyl-2.6imidarolidindione (dichlorohydrantoin). Xykne attack some <strong>for</strong>ms of plastics. mbber. ati dcoatings. Conditions to Avoid: Avoid heat <strong>and</strong> ignition sources <strong>and</strong> incompatibles. Hazardous Pruducta of Decomposition: Thermal ox&tit redecomposition of xylene can produce carbon dioxide. carbon monoxide. <strong>and</strong> various hyw products.Section 6. Health Hazard DataCarchogenicity: The IARC,“@) NTP!tss) <strong>and</strong> OSHA(‘@) do not list xylene as a carcinogen Summary of Risks: Xylene is an eye, mucousmembmne. <strong>and</strong> respimtory u-act irritant Irritation starts at 200 ppm; severe breathing difIiculties which may be delayed in onset can occur at highconcentrations. It is a central nervous system (CNS) depressant <strong>and</strong> at high concentrarions can cause coma. Xidney <strong>and</strong> liver damage can occur withxylem exposure. With prolonged or repeated cutaneous exposure, xylene produces a &fatting damatitis. Chronic toxicity is not well defined, but itis less toxic than benzene. Prior to the 1950s. benzene was often found as a contaminant of xylena <strong>and</strong> the effects attributed to xylene such as blooddyscrasias are questionable. Since the late 1950s. xylenes have been virtually benzene-fme <strong>and</strong> blood dyscrasias have not been associated withxylenes. Chronic exposure to high concentrations of xylene in animal studies have demonstrated milk reversible decrease in red <strong>and</strong> white cellcounts as well as increasesplatelet counts.conlinllc 0” nextpqCopyright 0 1992 Gcmum lbblishmg Curpanuon My -roll ut Q rrpoaPctlm vilhoul Um pubhhdr pllmdanispobibiled
No. 318 Xylene (Mixed Isomers) 9/92Section 6. Health Hazard Data, continuedimgulatity was reported in association with <strong>work</strong>place exposure to xylene perhaps due to effects on liver metabolism. Xyiene cmsses the humanplacenta, but does not appear to be terafogenic under conditions tested to date. Medical Conditions Aggravated by Long-Term Exposure: CNS.~,miratory, eye, skin, gastrointestinal (GI) , liver <strong>and</strong> kidney disonien. Target Organsz CNS, eyes, GI trac& liver. kidneys. <strong>and</strong> skin. Primary‘y Routes: Inhaladon, skin absorption (slight), eye contact, ingestion. Acute Effects: Inhalation of high xylene concentrations may causeiness: nausea vomiting. <strong>and</strong> abdominal pain; eye. nose, <strong>and</strong> throat irritation; respiratory tract initation leading to pulmonary edema (fluid in-de); drowsiness; <strong>and</strong> unconsciousness. Direct eye contact can result in conjunctivitis <strong>and</strong> corneal burns. Ingestion may cause a burning sensationin the orophatynx <strong>and</strong> stomach <strong>and</strong> mmsient CNS depression. Chronic Effectsz Repeated or prolonged skin contact may cause drying <strong>and</strong> defattingof the skin leading to dermatitis. Repeated eye exposure to high vapor concentrations may cause reversibl eye damage, peripheral <strong>and</strong> centralneuropathy. <strong>and</strong> liver damage. Other symptoms of chronic exposure include headache, fatigue, irritability, chronic bronchitis, <strong>and</strong> GI disn&+anc~such as nausea, loss of appetite, <strong>and</strong> gas.FIRST AID &urgency personnel shouldprvtecragainst exposure. Eyes: Do not allow victim to tub or keep eyes tightly shut Gently lib eyelidsaud flush immediately <strong>and</strong> continuously with flooding amounts of water until transported to an emergency medical facility. Consult a physicianimmediately. Skin: Quickly remove contaminated clothing. Rinse with flooding amounts of water <strong>for</strong> at least 15 min. Wash exposed ana with soap<strong>and</strong> water. For reddened or blistered skin, consult a physician. Carefully dispose of contaminated clothing as it may pose a fue hazard. Inhaletion:Remov exposed person to fresh air <strong>and</strong> support breathing as needed. Monitor exposed person <strong>for</strong> respiratory distress. Ingestion: Never giveanything by mouth to an unconscious or convulsing person. Contact a poison control canter <strong>and</strong> unless otherwise advised, do not induce vomiting! Ifspontaneous vomiting should occur. keep exposed person’s head below the hips to prevent aspiration (breathing liquid xylene into the lungs).Aspiration of a few millimeters of xyfene can cause chemical pneuwwnitis, puhnonary e&w <strong>and</strong> hemorrhage. Note to Physicipas: Hipptic acidor the ether glucumnide of orrho-toluic acid may be useful in diagnosis of me&, pum- <strong>and</strong> onho-xylene exposure. respectively. Consider gasticImage if a large quantity of xylene was ingested. Proceed gastric lavage with protection of the airway from aspiration; consider endotmcheaiintubation with inflated cuff.Section 7. SDill. Leak. <strong>and</strong> DismalProceduresSpill/Leak: Notify safety personnel, evacuate ail unnecessaty personnel, remove all heat <strong>and</strong> ignition sources, <strong>and</strong> ventilate spill atea. Cleanuppersonnel should protect against vapor inhalation <strong>and</strong> skin or eye contact If feasible <strong>and</strong> without undue risk, stop leak. Use appropriate foam toblanket release <strong>and</strong> suppress vapors. Water spray may reduce vapor, but does not prevent ignition in closed spaces. For small spills, absorb on paper<strong>and</strong> evaporate in appropriat exhaust hood or absorb with s<strong>and</strong> or some non-combustible absorbent <strong>and</strong> place in containers <strong>for</strong> later disposal. Forlarge spills dike far ahead of liquid to contain. Do not allow xylene to enter a confined space such as sewers or drains. On l<strong>and</strong>, dike to contain ordivert to impermeable holding area. Apply water spray to control flammable vapor <strong>and</strong> remove makrial with pumps or vacuum equipment. Onwater, contain material with natural barriers, booms, or weirs; apply universal gelling agent; <strong>and</strong> use suction hoses to remove spilled material.Report any release in excess of 1000 lb. Follow applicable OSHA regulations (29 CFR 1910.120). Environmental T~p~rt: Little biocuncen-@ation is expected. Biological oxygen dem<strong>and</strong> 5 (after 5 days at 20 ‘C): 0.64 (no stated isomer). Ecotoxicity v&es: LD, Go1df”h, 13 mg/l,f24 hr,conditions of bioassay not specified. no specific isomer. Environmental Degradation: In the atmosphere, xylenes degrxie by reacting withphotochemically produced hydroxyl radicals with a half-life ranging from 1-l .7 hr. in the summer to 10- 18 hr in winter or a typical loss of 67-86sper day. Xylenes are resistant to hydrolysis. Soil AbsorptiodMobilitp: Xylenea bave low to moderate adsorption to <strong>soil</strong> <strong>and</strong> when spilled on l<strong>and</strong>,will volatihze <strong>and</strong> leach into groundwater. Disposal: As a hy drocarbon, xylene is a good c<strong>and</strong>idate <strong>for</strong> amtrolled incinuation. Contact your supplieror a licansed conaactor <strong>for</strong> detailed recommendations. Follow applicable Fedeml. state, <strong>and</strong> local regulations.-A Designations OSHA DeJignationsIA Extremely Hazardous Substance (40 CFR 355): Not listedListedasanAirContaminant(29CFR1910.1CNJO.TableZ1-A)sd as a SARA Toxic Chemical (40 CFR 372.65)Listed as a RCRA Hazardous Waste (40 CFR 261.33): No. U239. FOO3 (spent solvent)Listed as a CERCLA Hazardous Substance* (40 CFR 302.4): Fti Repottable Quantity (RQ). 1000 lb (454 kg) [* per Clean Water Act.Sec. 31 l(b)(4); per RCRA, Sec. 30011Section 8. Special Protection DataGoggles: Wear protective eyeglasses or chemical safety goggles. per OSHA eye- <strong>and</strong> face-protection regulations (29 CFR 1910.133). Becausecontact lens use in industry is controversial. establish your own policy. Respirator: Seek professional advice prior to respirator selection <strong>and</strong> use.Follow OSHA respiratoregulations (29 CFR 1910.134)<strong>and</strong>, if necessary, wear a MSHA/NIOSH-approved respirator. For concentrations > 1000ppm. use any chemical cartridge respirator with organic vapor cartridges; any powered, air-purifying respirator with organic vapor cartridges: anysupplied-air respirator. or any self-contained breathing apparatus. For emergency or nonroutine operations (cleaning spills, reactor vessels, orstorage tanks), wear an SCBA. Warning! Air-purifying respirators do not pro&ct <strong>work</strong>ers in oxygen-dejicient atmospheres. If respirators are use&Other: Wear chemically protective gloves. boots, aprons, <strong>and</strong> gauntlets to prevent all skin contact. With breakthmugh times > 8 hr. considerpolyvinyl alcohol <strong>and</strong> fluorocarbon rubber (Won) as materials <strong>for</strong> PPE. Ventilation: Pnwide general <strong>and</strong> local exhaust ventilation systems tomaintain airborne concentrations below the OSHA PELs (Sec. 2). Local exhaust ventilation is prefemzd because it prevents contaminant dispersioninto the <strong>work</strong> area by controlling it at its source. (‘03) Safety Stations: Make available in the <strong>work</strong> area emergency eyewash stations. safetylquickdrenchshowers. <strong>and</strong> washing facilities. Contaminated Equipment: Separate contaminated <strong>work</strong> clothes from street clothes. Launder contaminated<strong>work</strong> clothing be<strong>for</strong>e wearing. Remove this material from your shoes <strong>and</strong> clean PPE. Commento: Never ea& drink or smoke in <strong>work</strong> areas.Practice good personal hygiene after using this material. especially be<strong>for</strong>e eating, drinking. smoking, using the toilet. or applying cosmetics.Section 9. Special Precautions <strong>and</strong> CommentsStorage Requirements: Store in clearly labelled. tightly closed, containersa cool. well-ventilated place, away from s@ong oxidizing materials<strong>and</strong> beat <strong>and</strong> ignition sources. During txansfening operations. electrically ground <strong>and</strong> bond metal containers. Engineering Controls: To reducepotential health hazards. use sufficient dilution or local exhaust ventilation to control airborne contaminants <strong>and</strong> to maintain c~n~entsati~~ at thelowest practical level. Use hermetically sealed equipment, transfer xylene in enclosed systems, avoid ptocesses associated with open evaporatingsurfaces. <strong>and</strong> provide sources of gas release with enclosures <strong>and</strong> local exhaust ventilation. Use Class I. Group D electrical equipment. AdministrativeControls: EsrdAish air <strong>and</strong> biological monitoring programs <strong>and</strong> evaluate regularly. Consider preplacement <strong>and</strong> periodic medical examinationsincluding a complete blood count. a routine urinalysis. <strong>and</strong> liver function tests. Consider bernatologic studies if there is any signifiunt contaminationof the solvent with benzene. Lf feasible. consider the replacement of xylene by less toxic solvent such as petrol (motor fuel) or white spirit. Be<strong>for</strong>ecarrying out maintenance <strong>and</strong> repair <strong>work</strong>. steam <strong>and</strong> flush all equipment to remove any xy-lene residues.Transportation Data (49 CF’R 172.101)DOT Shipping Name: Xylenes Packaging Authorizations Quantity Limitations Vessel Stowage R uirementsRO;oH~~3C;ass: 3 a) Exceptions: 173.150 a) Passenger. Aircraft. or Railcar 5L a) Vessel Stowage: “SI.b) Nonbulk Packaging : 173.202 b) Cargo A&raft Only: 6oL b)Oti-.-v lr facking_Group: . . I. II ,.- .> c) Bulk Packaging: 173.242-31 LawI: mamma me LtquiaSpecial Provisions (172.102): Tl148.149,153.159,163. 16A 167.171. 174.176.180.. . .
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