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i:.:::;:. ..-., \,’. .No. 68 Calcium Hypochlorite 11189~Section 6. Health Hazard Data.; ‘.Cardnogcnldty: Neither the NTP, IARC. nor OSHA lists calcium hypochlorite as a carcinogen.Summary of Risks: This strong oxidizing agent can irritarc <strong>and</strong> damage all the tissue it COIWCU. with the degree of injury depending on the dose,available chlorine level, <strong>and</strong> exposure time. The chlorine this compound gcncrates is tht pm toxic SgcnL Both the powder <strong>and</strong> solutionsptuducc chlorine levels corrosive to body tissues. InhaIing its vapor is exlremely itritafing <strong>and</strong> toxic. Possible injuries include: conjunctivitis, libIephariti.s (inflammation of the margins of the eyelids). comeal ulcerations, gingivitis, contact dermatitis, <strong>and</strong> tooth damage. Medical Condldo&Aggravated by Long-Term E&sure: Repeated contact can reverely~datnage tissue. Target Organs Skin, eyes, r&phory sysmstomach. Primary Entry: Inhalation, ingestion. Acute Effects Skin contact can produce initation <strong>and</strong> vcsicuhr qtions. Dust i&&&oniniratu the respiratory @act <strong>and</strong> may cause puhnonaty edema. Ingestion i&ares the mouth, thtuas <strong>and</strong> stoma& <strong>and</strong> gastric acid liberateshypochlorous acid. Fatalities can result from ievens compLcadons of local injury, shock toxemia, hemorrage, wall pufotation, <strong>and</strong> obstruction.~b&c~cc!s: Eczcmatoid dermatitis may result from rtpeared skin ~~llta~f Eye t%mtact CM cause severe eye damage.Eycsz Flush immediately. including under the eyelids, geutly but thoroughly with flooding amounts of ruuniag wpft~ <strong>for</strong> at least 15 min.Skin: Aftcrrinsiug affcaed area with tboding amounts of water, wash it with soap <strong>and</strong> water. Inhalation: Remov exposed person m &e& airad support brea&mg as needed. Ingestion: Never give anything by mouth to an -nscious or convulsing person. If ingested, piompdy rinsemouth of conscious person with water be<strong>for</strong>e giving large az~ounts of milk or water to drink followed by n&k of znagne&After flrst aid, get approprlatc In-<strong>plan</strong>t, paramcdlc, or commuuity medical attention <strong>and</strong> support.Section 7,. Spill, Leak, <strong>and</strong> ~sp~f.:P~&~~s: . I:: .:-..:.:;: :. I-. . . . “.::i.:.:..:.... . I.::,~::~~ :.:. ;: ::_;A;. .:..:::,:.I:~:.:.S~WL&C Notify safety personnel of spills. Remove combustibles <strong>and</strong> ignition sourcu. Those involved in cleanup need protection againstccmtxt with the solid <strong>and</strong> dust inhalation. Pmmt dust genemtion <strong>and</strong> prevent direct discharge into sewers or watcxwayshe this mata+& inlow concentrations, is toxic to aquatic life. Recover uncont&nated solid mate&l in clean, dty contains. Cover other spilled ma&al with weakt&acing agents (3M I-I$O, with bisulfltu or fenous salts), shiny it with water, <strong>and</strong> then flush it with water to a suitable holding ta& Wash spill<strong>site</strong> well with soap solution containing a weak reducing sgcuLD&sposal: Use reducing agents to destroy available chlorine. Adjust this reducal liquid’s pH to ncufral <strong>and</strong> decant Discharge neutraliquid,diluting with much water. Dispose of neutral shulge (lf any) in a l<strong>and</strong>fi’i Contact your supplier or a licensed contractor <strong>for</strong> detailed recommendations.Follow appliuble Federal, state, <strong>and</strong> local regulations.OSHA DaignadonaAir Contaminant (29 CFR 1910.1000. Subpart Z): Not listedEPA DesignationsRCRA Hazardous Was& (40 CFR 261.33): Not listedlisted as a CERCIA Hazardous Substance* (40 CFR 3024). Reportable Quantity (RQ): 10 lb (4.54 kg) [* per Clean Water AC& Sec. 31 l(b)(4)]SARA Examdy Hazardous Substance (40 CFR 355): Not listedSARA Toxic Chtmical(40 CFR 372.65: Not listed;&Con: 8:;. sp&& IttotectiO~:D’~~~~~~~~~~::~~~~~~~:~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~.: _.. ..._..l.?

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