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i -Material Safety -Data .-Sheet .--lfhm Gcnium’s Reftrtnce CokcrionGcnium ?ubiishing Corporation@p-zk~;~a19~i31145 Cacakn StrwS&-y, ST lk303-1836 USAoauuu maustu~a corn(5181377-8855crm7n.x t MATFRTAT. TnrhTTFTpdTTnN .~.‘.“.‘.-.:“:-i~.. .’“I” *v*. A. . ..saLYI.Y~Y .a--.. * Y --.a- a-. .,771 -ni%tcrial Same: ISOBUTYLE!!E41 0Descripdon (OrigiruTsa): Obuiuai fromrciiocy - by absorption ou 6% soili& acid (&SO3.u59’F (15-Q. Used prizrsily ro producz diisobucyicc, oimcn. bury1 nrbbc. aad orherpol~; alsoe9used m produc: a&oxidants for foods, plasrics, and pa&aging food s@eaazs.3FPAOther Designations: Iroburcne; t-Mcrhyipropenc; pm-Burylee; C+C(CH,),; Cti No. 0115-11-7.Manufacturu: Contact your supplier or disoibumr. Consult the latest cditiou of the CjlMII’Eohu l ekBuyers Guide (Guium ref. 73) for a Iist of supptinSECI’IOIY 2. INGREDIENTS AND HAZARDS .. .% EXPOSURE LIMITS . .Isobutyleoe, CAS No. 0115-U-57 Cal00 OSHA PELl MouitorNIOSX RTECS (UDO8!lOOOQ. for addifioox! durNone EstablishedACGXH TLV, X98&89None EstablishedXOSH RELNose EscahiishedTaxi&y Data*RaL Iukaiadort. Lc,: 620 ghd (4 Hn)Mouse, Idniadcm, LC,,z 415 ,yyd (2 I-b)SECTION 3. PHYSICAL DATA ....T..z._.: .:...:....-: . ....i.Bailiag Poiac -19.6-F (-63T) Moiecaiar Wig&c 56 GmnsiMoIcM&lag Poiac -2ZOT (-140X) Solabill~ ia Water (%): Iosoluble*Vapor Density (Air = 1): 19 ’ + Vohdh by Voiumc: 100Sptiflc Gntiq (YO = I): Ca 0.6Appearance aad Odor: A colorist. exuuneiy nnmnthie gas; odor not Med.l rsobccry1alc is very sokcbIa ia aicohoS ether. aid mlfuric acid.SECTION 4. mE AND E($BLOSI(-JN DATA- -“i;:.:;:‘;;.:.< ‘. : . .: i _.._:::,._.: ...’Rash Point’ 1 Autoignition Tmtararurr: 869-F (465-O 1 LEL 1.8% v/v I UEL 9.6% WV&daguishbg Wcdfr: Isoburylcoe gas is 1~ erntndy f!ammable gas that baa a &sun&i explosive air-gas range. For iso- fpsrberrurmmcrrdcdfuc-fi~~gtecfnriqueLu,~~fIowofgarinncrdol~~g~ef~LIthc[luntsrrrenin~mdtht’isobutyhe gas coorimes to esape m 1~4 a uphive air-gas cuixmre uu form quickly aad i@e dkout wming. A nsukiq explosioncouldcJutc~~ethrn~w~~tvooldkuusedby~wing~eBrcmt)tarr~ouLK~cfirrmosrbccxtingPishcda,9ovsafe wuss m shnmffvalveq ruummcndal atinguisbing agents it&de CO, and dry chcmiuI. Uausaal. Fire or Explosion Ryydr la~y~~eprrfarcdsuucgyis~rllowrhc~to~uembrm!~to~lthe~ondinyuri~u~spnytopmmt~of owrby combustibiu. Isobutylcnc gas is havia &a air md cry colkt in &w-lyiag. coafiicd sprccr Pouorially explosive air-gzsmixturu are cspecitiy likely to build up in sncb au m so eo~cr it with atrnnt aodou wkcfhc oruot it is prr~enrly involved in a firr.Possible sources of ignition must not be bmugkt into any area suspecti of coatlining mbstanirl concuaztions of koburylcne gu. Spcci?l.Fire-&hang Procedures: War a seif-coouioed brcuking apparatus (S-A) witk a lull factpiece opera&d io the pressuredemand orpositive-prasm mode.l Sax (Gcuium ref. 6) reports a flash point of -1OST (-WC) for isoburylmcSECTION 5. REACTMTY DATA : “iShbility/Po@acrindon: Isobucyleec is stable in closed, pressurized con&rxrs during ruurinc opmdonr at mom WpcnurrCHyydous @ywriio cannot occur. Chemical IncompatibiIities: koburyleuc cm rezct tigerously wilh ~mng oxidizing m-Coadldons to Avoid: l+eveot exposing isobuq-Ime LO auy souse of ignirioo suc.b as an opeo Ilao% sparks. ligh’sd tobacco pradlPc% Orrtcun lieu. Hazardous Produers of Decompositioa: ~bucyleoe f&s w pduce taxic gasesuck as arbon nonoxide (CO) or lowermoiccular-weighthydrnctions. Cornmerits: The af=sc flammability of isobucylme muos tkat xy rcztions inmiring tkis mtWi&including oookazudous onu. must be performed arefuiIy in order to prevent fii znndlor cxplosiort.jECTIOIY 6. HEALTH HAZARD I&FORMATIONlrcinogenicity fsobucylcne is oat tisrcd Y a cqiiqa by ckc KIP. IARC. or OSHAiummary of Risks: Isoburylcnc is a simple zsphyxi;mr .4s suck it wil1 not uuse signifiunc pkysiologiul .~~JOOSCS. but it can displx: tihcninimum fcq:*Jcd xmospkcric oxygen level. Signif!ctnr displacczxzt by isobutylc=e results in an oxygen-defic::~ atzosphex WiLb nod4u3tc warotig pmpcrdcs. Asphyxiation ftiiriu an occur apaiaily in confined. low-lying, poorly vcxA~tzd qaccs because isobuq-.
. .SECTION 6. HEXLTH HAZARD. IfiFORMATIOIV. cont. . . . . . . - -- . . . . ..- -..---,.Ias gas is almost Lwiec as dca~e as ;lit &if (see SOX, 3). ;Mcdicrl Conditions Aggravated by I~ng-Term &OSW~ None f~?ontd.“arget Organs: None rcponcd. Primary Entry: IahJtioa. .h~te EKects: Initial sympmas of Ihe effas of simple asphyxianrpa arc rapid respiration and air hunger. dimiuished mead akncss, aad &paired muscular coordiaxtioe CoUiauing lack of oxygencues faulty judgmczL depression of all sczsakons. rapid ftig?% aad c=otioaal iasubilicy. As rhe asphyxia coatiaues. aausca: vomitiaq;pmstioa; loss of consciousness; and. finally, coavulsiort; deep COEU; and dexth cxa occur. Chronic EKeco: None mpohd.FIRST AID: Inhalation. would-be mscuc~s aced (0 be coaczzd about rhcir owg sxf~y whca eatig conf%cd, porfy vc~&M,axygcadeficicar areas. Seif-caataiacd bretiag quipazeat I=*SL be rexdily available for rcscxax. StaJioa srandby wozkcs outside theimmc&iarc area so rhac rhcy cm summon additional help if it is ~czded. Remove the exposed ~CTSO~ LO ~IZA air. I#UJTC andlor supporthis or her breathing as needed. Have qualified atcdicxl pcsoa--. -4 adaiaisur oxygen as rquimd. Commcna: The uueze fldiliryof isobutyleac gas wva~u spccixl aucasioa evca during rcscz opcrarioas. RCSXC pcnoancl mu% UOL smoke AU czzeqcacy iz’“ls andhodligh~ thxt must be low& inro cac!oscd areas for rescue opcyiol~ azust be explosion proof. Obka this quipmnt before xayemerge-Xy OCM aad make iL accessible co cmcrgucy-rcsporw paxoannci. CcC med1a.i help (Ia plan& PanLttediC, communi~) for111 exposures. Seek pr0cqX malicxi assisuncc for funha Irc--,U -‘---L obscvtioa, aad support after fit aid.SECTION 7. SPILL. LEAK. AND DISPOSAL PROCEDURESSpiillkk Tnzax any iwhqluu gru leak a M enwpcy. If the leaking gas has aoc yet ignited, use water sprxy to direct fixmmxble gxsairmirrucs away from sourca of igaidoo. Extiaguisb all SOIEU of igaidoa as quickly as possible; homvcr. if the lakiag gxs is burning,do not a~~cmpr 10 cxbguis& rho flama uaril UC sauxcc of the iobutylcac gxs is loufed aad sealed. OthcrwiK, fhxaabie is0bucyicac gasairatixatres cfo explode without wxrniag and cause widesp& dmxge char might uoc have oamrcd if the original fat hxd baa aowedIO bum i&elf OUL 11 ir is aazssary ~3 extiaguish isobulyiuc Ilazzs ia order 10 gain access V) a shutoff valve, use dry Chtzi~a! or carb0afioxidc as extiguishiag ageart. WYU Disposal: Coatxct you supplier or a liceascd wamxor for dcticd recammadacioas. FollowFcda-d, scau, and local cegulaLious.OS&i DexigaadoasAirCoouminaar(29 CFR 1910.1000 Subparct): Not LisudEPA Desfgaarhas (40 CFR 5024): Not L&dSECTION 8. SPECIAL PROTECTIOti LiFOR.M.4TION : .. ...I’...- .,.Rapiraror. Follow OSHA rapiracar rcguladoas (29 CPR 1910.134). For emergency ar aoaroaLiae opcrxtiom (leaks or clexaiag rcxctarvessels and storage tanks). wear an !XBA. Waraingz Air-pur@iag respinton will n0l proreCr Workers in Oxyecn-detideat ~sphtrrt.which lack warning w to wack in them safely mquirs rlw a Sc8A be warn. Vcntfladoa: hall aad opaate gaicral ad locala cxplosioa-proof vcacilacion syslcrm powerful caough 10 mxiauia xizbome levels of this matah! b&w the lower explosive limirJcd in h 4. Locd cxhausc vcatilarioa is prcfd beuusc ir prevents dispersion of the conrrminmc into he gead work xca by4tlimia~ is at i0 saurce. Coasuk the Usr edition of Ccniua dcratce 103 for &tied n2ammadarioru Safefy Stations: M&e ancrgeacyeyewash St&a& ufety/quick-dIcaCh showm, aad wu.Siag facilities avxiIxble in urork xrws. Coatamiaati Equipment CaauCrleases pose a spaiai hazard; saft leasa mxy absarb irritants, aad ail leasa coaccarrxte tha Da IWI wear coatxct kasa ia say wark arex.Commcnb: Practice good pcrsaaxl hygiuc; always wash thoroughly after uxiag &is mxtcrial aad befare cuing. drinking, smoking. usingLb roiltr, or applying cosaluia. Keep it off yoor &hiag tad equipment Avoid ~aasfcrriag it from your hrndt TV .wur rrrouth while eadngd&king, ar samking. Da mt cak cfdak or smoke in say work area Da aoc inhale hobutyiaxe vapor.SECTION 9. SPECIAL PRECAUTIOfiS AND COMMENTS . .. ::-s. ,. . ,.‘.“S~dSegregatloo: Stam itobu~lcac ia closed, ptess&& conuinen ia a cool, dry, well-vcafilrrcd arca away iha sources of ignirioa,ombustibic azarrrials. aad moag oxidiza~ Prarccr eoaraiaa fmm physical damage. !Zagiaeering Coatr0k Make sarc all eagiactringsysum @uductiou tm7sspoKaKioa) ace of auxialum explosion-proof desigz EIecdulIy gmuad md bond an caataha% pipdim ctc,a& ia shippiag, uaasferriag, &g, pradacrion, aad sampiiig 0pu&ms to prcvatr static sparks. Comments: Isabutykae is aacxucmeiy explosive md nlmmnhlc gxs. It amst not be cx~osd ta my possible source of ignition ia work or age trcuTmasportltlon Data (49 CFR 172.101-t)DOT Shippbg Nama: Iiqucfkd Peoolcum GasDOT Hard CIassz Ramaable GasID so. UN1055DOT Label: Flammxblc GasDOT Packaging Rquiremena: 49 C!Zl1733W, 3 14,3 ISDOT Packaging Excepdons: 49 CX 173.306MO Shipping Same: IrobutyleaeCd0 Honrd CIus: 21510 Lab& Ramrzlblc Gasrferenccs: 1.6. Q4-94. 116.117. 120.111._
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NOHM RemediationServices Corp.WORK
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1.0 INTRODUCTIONThis Work Plan (WP)
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2.0 SITE BACKGROUNDMCB Camp Lejeune
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..;/II'. 1i4\..\1 '*.XCAVATION \.AR
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A I B I CE I PI 0 I H I IPARK I NGA
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OHM RemediationServices Corp. WORK
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5.0 SITE CONTROL PLANSOHM will impl
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L= THE DISTANCE SUCH THAT POINTA AN
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OHMRemediationServices Corp. WORK P
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7.0 SITE RESTORATION AND DEMOBILIZA
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9.0 PROJECT SCHEDULEThe project sch
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NOHM RemediationServices Corp.SAMPL
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TABLE OF CONTENTS - CONTINUED6.0 DA
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2.0 PROJECT MANAGEMENT2.1 Project B
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Program ManagerG. Krauter, P.E.Prog
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OHM RemediationServices Corp. SAMPL
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A I 8 I P I 0 I EFI I 6 IH1 IPARKIN
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4.0 DATA ACQUISITION4.1 Analytical
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OHMRemediationl QC samples are with
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lWorking order of instruments and e
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8.0 CORRECTIVE ACTIONCorrective act
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Table A-lSampling SummarySample Typ
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AppendixBSample LabelCustody SealCh
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3 CHAIN-OF-CUSTODY RECORDOI IM Corp
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IA== B OHM Renmhtionavices Corp\&FC
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BOHM RemediationServices Corp.SITE-
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TABLE OF CONTENTS - CONTINUED6.0 DE
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This Health and Safety Plan (HASP)
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_OHM RemediationServices Corp. HEAL
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OHM RemediationServices Corp. HEALT
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OHMRemediationconnection between th
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OHMRemediationTask No. 4: SoilSampl
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OHM RemediatioaServices Corp. HEALT
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5.0 PROTECTIVE EQUIPMENTThis sectio
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6.0 DECONTAMINATION PROCEDURESThis
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. . . --..7.0 AIR MONITORINGAir mon
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OHMRemediationServices Corp. HEALTH
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ci@- OHM RemediationServices Corp.
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9.0 TRAINING REQUIREMENTSAs a prere
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HEALTH-AND-SAFETYPLAN CERTlFICATION
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APPENDIX B - OHM HAZARD COMMUNICATI
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8. Know what you are expected to do
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. Methods and observations that may
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msPhysical propertiesAcute/Chronic
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GPI Material Safety Data Sheets Col
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Material Safety Data Sheets Collect
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Page 178 and 179: I, r.___Genium Publishing Corporati
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Page 182 and 183: .UrRPLS= ?UXiURE OF PARAFFIHTC, CTt
Page 184 and 185: APPxavg a5twfIc vAPUR'C!fE?!XCAL CA
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Page 188 and 189: WITCO MATERIAL SAFETY .O A T A SHEE
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Page 223 and 224: AJ 0. 14MSDS No. 324 Isopropyl Alco
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Page 236 and 237: .. . DFIRSTBRANIlSMaterial Safety D
Page 238 and 239: Tdeshone:Infomation: (619) 275liu~C
Page 240 and 241: APPENDIXDHEALTH AND SAFETY FORMSAcc
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Page 246 and 247: IBAR MONTHLY INSbBCTIONCHECRLIBTBAR
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Page 250 and 251: DIRECT READING INSTUMENT LOGNAME:PR
Page 252 and 253: j% - -5 mi -omcorpo~Date:DAILY SA.F
Page 254 and 255: . ‘ISCUA MONIIILY INSFECA'ION CIi
Page 256 and 257: SITE SAFETY OFFICERDAILY REPORTDATE
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Page 262 and 263: HAZARD ANALYSISEM 38s i1 Ott 92nLll
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