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Material Safe9 Datu Sheets Collection:Genium Publishing Corporation1145 catalyn saw Sheet No. 68Scfienccfady, NY 12303-1836 USA Calcium Hypochlorite(518) 3311-8854. .ICalcium hypochlori~*OSHA PELNone utablishaIACGIH TLV, l9sw9 NIOSH REL, l987 Toxkfty DataNoae utablished None arabUshaf Ras oral. mm: 850 aI@.fIcSpdaf Fhdlghtfng Procedures: Wear a self-coataiaed breath@ qpmfas (SCEA) with a full f&q&e opented ia rhe pressuredeand orpositive-pfessute mode. Full protective clothing is also aaessaxy. Fiit oussive fires using unmamzd hose holdas. If this is impossible, let tireburn and withdraw fram hazardous areas.I!Chcmlcal IacompatibUitla: Calcium hypochlorite is a powerful oxidiziag ageat that rwdiiy igaitcs combustibles. Violent reactioas or cxplosioascaa occur. for exaaqle. with amiaes, carboa tcfxachloride sad bear, c&on or chzcoal sad hcas ethyl akohoi, metal oxides, mcrcaptoas.&fur, tarpcatiac, strong reducing agents, orgaaic maita, combustible mat&&, aiaomerhaae, m &bride, N,Ndichfotamcthylamiaead heat, acetic acid aad potassium cyanide, cthsaol. isobutaaethiol, methaaol, I-pro-paaethiol, and rust Reaca with wafer or steam to producetoxic and corrosive ftmes or HCI aad (X (Sec. 6). Potentially explosive with sodium carbow, starch, md sodium hydrogen sulfate. Rcactioawith aifxogcaous bases or acc~lenc forms explosive product. Igaites on contact with glyccriae algacide sad hy+axy compounds (e.g.. glycerol,diethylenc glycol moaome~I1y1 echa, sad phenol). sod organic sulfur compouads. Material coaaining ova 60% available chloxiae ignites oacoatact with lubricating oil (additioa of about 20% or morr warerpmeats this). Oa coatact with acids it foray hypochloraus acid sad liberatesq gas. It forms tie highly explosive NCI, with urea.Hazardous Products of Decompositloa: Rapid exothamic (heatproducing) decoaqositioa above 347 “F(l75 ‘c) releases oxygen sad chlorine.When heated f~ decompositioa. calcium hypochlorite emits highly toxic hydrochloric acid (HQ furacs aad explodes.
i:.:::;:. ..-., \,’. .No. 68 Calcium Hypochlorite 11189~Section 6. Health Hazard Data.; ‘.Cardnogcnldty: Neither the NTP, IARC. nor OSHA lists calcium hypochlorite as a carcinogen.Summary of Risks: This strong oxidizing agent can irritarc and damage all the tissue it COIWCU. with the degree of injury depending on the dose,available chlorine level, and exposure time. The chlorine this compound gcncrates is tht pm toxic SgcnL Both the powder and solutionsptuducc chlorine levels corrosive to body tissues. InhaIing its vapor is exlremely itritafing and toxic. Possible injuries include: conjunctivitis, libIephariti.s (inflammation of the margins of the eyelids). comeal ulcerations, gingivitis, contact dermatitis, and tooth damage. Medical Condldo&Aggravated by Long-Term E&sure: Repeated contact can reverely~datnage tissue. Target Organs Skin, eyes, r&phory sysmstomach. Primary Entry: Inhalation, ingestion. Acute Effects Skin contact can produce initation and vcsicuhr qtions. Dust i&&&oniniratu the respiratory @act and may cause puhnonaty edema. Ingestion i&ares the mouth, thtuas and stoma& and gastric acid liberateshypochlorous acid. Fatalities can result from ievens compLcadons of local injury, shock toxemia, hemorrage, wall pufotation, and obstruction.~b&c~cc!s: Eczcmatoid dermatitis may result from rtpeared skin ~~llta~f Eye t%mtact CM cause severe eye damage.Eycsz Flush immediately. including under the eyelids, geutly but thoroughly with flooding amounts of ruuniag wpft~ for at least 15 min.Skin: Aftcrrinsiug affcaed area with tboding amounts of water, wash it with soap and water. Inhalation: Remov exposed person m &e& airad support brea&mg as needed. Ingestion: Never give anything by mouth to an -nscious or convulsing person. If ingested, piompdy rinsemouth of conscious person with water before giving large az~ounts of milk or water to drink followed by n&k of znagne&After flrst aid, get approprlatc In-plant, paramcdlc, or commuuity medical attention and support.Section 7,. Spill, Leak, and ~sp~f.:P~&~~s: . I:: .:-..:.:;: :. I-. . . . “.::i.:.:..:.... . I.::,~::~~ :.:. ;: ::_;A;. .:..:::,:.I:~:.:.S~WL&C Notify safety personnel of spills. Remove combustibles and ignition sourcu. Those involved in cleanup need protection againstccmtxt with the solid and dust inhalation. Pmmt dust genemtion and prevent direct discharge into sewers or watcxwayshe this mata+& inlow concentrations, is toxic to aquatic life. Recover uncont&nated solid mate&l in clean, dty contains. Cover other spilled ma&al with weakt&acing agents (3M I-I$O, with bisulfltu or fenous salts), shiny it with water, and then flush it with water to a suitable holding ta& Wash spillsite well with soap solution containing a weak reducing sgcuLD&sposal: Use reducing agents to destroy available chlorine. Adjust this reducal liquid’s pH to ncufral and decant Discharge neutraliquid,diluting with much water. Dispose of neutral shulge (lf any) in a landfi’i Contact your supplier or a licensed contractor for detailed recommendations.Follow appliuble Federal, state, and local regulations.OSHA DaignadonaAir Contaminant (29 CFR 1910.1000. Subpart Z): Not listedEPA DesignationsRCRA Hazardous Was& (40 CFR 261.33): Not listedlisted as a CERCIA Hazardous Substance* (40 CFR 3024). Reportable Quantity (RQ): 10 lb (4.54 kg) [* per Clean Water AC& Sec. 31 l(b)(4)]SARA Examdy Hazardous Substance (40 CFR 355): Not listedSARA Toxic Chtmical(40 CFR 372.65: Not listed;&Con: 8:;. sp&& IttotectiO~:D’~~~~~~~~~~::~~~~~~~:~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~.: _.. ..._..l.?
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NOHM RemediationServices Corp.WORK
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1.0 INTRODUCTIONThis Work Plan (WP)
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2.0 SITE BACKGROUNDMCB Camp Lejeune
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..;/II'. 1i4\..\1 '*.XCAVATION \.AR
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A I B I CE I PI 0 I H I IPARK I NGA
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OHM RemediationServices Corp. WORK
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5.0 SITE CONTROL PLANSOHM will impl
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L= THE DISTANCE SUCH THAT POINTA AN
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OHMRemediationServices Corp. WORK P
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7.0 SITE RESTORATION AND DEMOBILIZA
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9.0 PROJECT SCHEDULEThe project sch
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NOHM RemediationServices Corp.SAMPL
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TABLE OF CONTENTS - CONTINUED6.0 DA
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2.0 PROJECT MANAGEMENT2.1 Project B
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Program ManagerG. Krauter, P.E.Prog
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OHM RemediationServices Corp. SAMPL
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A I 8 I P I 0 I EFI I 6 IH1 IPARKIN
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4.0 DATA ACQUISITION4.1 Analytical
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OHMRemediationl QC samples are with
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lWorking order of instruments and e
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8.0 CORRECTIVE ACTIONCorrective act
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Table A-lSampling SummarySample Typ
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AppendixBSample LabelCustody SealCh
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3 CHAIN-OF-CUSTODY RECORDOI IM Corp
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IA== B OHM Renmhtionavices Corp\&FC
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BOHM RemediationServices Corp.SITE-
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TABLE OF CONTENTS - CONTINUED6.0 DE
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This Health and Safety Plan (HASP)
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_OHM RemediationServices Corp. HEAL
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OHM RemediationServices Corp. HEALT
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OHMRemediationconnection between th
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OHMRemediationTask No. 4: SoilSampl
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OHM RemediatioaServices Corp. HEALT
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5.0 PROTECTIVE EQUIPMENTThis sectio
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6.0 DECONTAMINATION PROCEDURESThis
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. . . --..7.0 AIR MONITORINGAir mon
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OHMRemediationServices Corp. HEALTH
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ci@- OHM RemediationServices Corp.
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9.0 TRAINING REQUIREMENTSAs a prere
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HEALTH-AND-SAFETYPLAN CERTlFICATION
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APPENDIX B - OHM HAZARD COMMUNICATI
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8. Know what you are expected to do
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Page 164 and 165: msPhysical propertiesAcute/Chronic
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Page 170 and 171: e5P (518)37%8854Genium Publishing C
Page 172 and 173: apSix.lion 1. Material Identificati
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Page 182 and 183: .UrRPLS= ?UXiURE OF PARAFFIHTC, CTt
Page 184 and 185: APPxavg a5twfIc vAPUR'C!fE?!XCAL CA
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Page 203 and 204: SECTION 5c- HEALTH HAZAROS4lllmsnol
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Page 240 and 241: APPENDIXDHEALTH AND SAFETY FORMSAcc
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HAZARD ANALYSISEM 38s i1 Ott 92nLll
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