Genium Publishing CorporationMaterial Safety Datu Sheets Collection:one Gexliunl Plaza Sheet No. 313Schenectady, NY 123044690 USA PerchloroethyleneaP(518) 377-8854 issued: 11/78 Revision: E, 9192Section 1. Materiai Identification ,.. .. :. .:. 39Perchloroethylene (C&lJ Description: By chlorination of hydrocarbons <strong>and</strong> pyrolysis of the carbon tetrachlorideNFPAthat is <strong>for</strong>med, or by catalytic oxidation of 1.1,2,2-tetrachlo~oethane~ Used in dry cleaning <strong>and</strong> textile processing, F :metal degreasing. insulating fluid <strong>and</strong> cooling gas in electrical trans<strong>for</strong>mers. pmduction of adhesives. aerosols, paints,0S 2* 2 0<strong>and</strong> coatings: as a chemical intermediate, a solvent <strong>for</strong> various applications, extractant <strong>for</strong> pharmaceuticals, a pesticide K 0intermediate. <strong>and</strong> an antihelminthic (parasitic worm removal) agent in veterinary medicine. *skill 49Other Designations: CAS No. 127-18-4, Ankilostin. carbon dichloride. Didakene, ethylene tetaachloride, Perchlor. **on I-MISPerciene, Perk, Tetracap, tetmchloroethylene.Manufacturer: Contact your supplier or distributor. Consult latest Chemical Week Buyers’ Guid@) <strong>for</strong> a supphs list. F :+Cautions: Perchio!uethyiene is a central nervous system depressat& causes liver <strong>and</strong> kidney damage (from acute orchronic exposures), <strong>and</strong> is considered an IARC Class 2B carcinogen (animal sufficient evidence, human inadequate data).-Section 2. Ingredients <strong>and</strong> Occupational Exposure LimitsPerchlotoethylene. < 99%. Impurities include a small amount of amine or phenolic stabilizers.1991 OSHA PEL 1992-93 ACGIH TLVs 19gS-86 Toxicity Data’I 8-hr ‘WA: 25 ppm (170 mg/m3) IWA: 50 ppm (339 mg/m3) Man. inhalation, TCb: 280 pp& hr caused conjunctival1990 IDLH LevelSTEL: 200 ppm (1357 mg/m3) irritation <strong>and</strong> anesthesia.500 mm1990 DFG (Germany) MAKHuman, lung: 100 mg/L caused unscheduled DNA synthesis.1990 NIOSH RELTWA: 50 ppm (345 mg/m’)Rak oraL LD,: 3005 mgkg; caused somnolence, tremor,NIOSH-X CarcinogenCategory II: substances with systemic <strong>and</strong>ataxh.Limit of Quantitation: 0.4 ppmeffectsRa& iuhalatiou, TC,,,: 200 ppmla hr given intermittentlyHalf-life: < 2 hrover 2 yarn produced leakania <strong>and</strong> ksticalar tumors.Peak Exposure Limit: 100 ppm. 30 min Rabbit, eye: 162 mg caused mild irritation.average value, 4lshiBRabbit, skin: 810 mg/24 hr caused severe irritation.I * See NIOSH, RIECS (ICX3WlOOO). fcr additional irritatioa, mutatioa, rqrcdu&ve, tumcrigeaic, &toxicity data.:@&&dn 3, physidData::,r~.~.::::.;;:.IIii;:::,‘.: I:: .;:+$: .:..,-j;.:: :::: ;,; :::::~i.~:i-‘.::~.: ..: ; ~~.::‘j,,::-_~~~:i,~.l.::.:,,.i::i.!:-,.:~.~~:~,~.~~~~ . :IjBoiling Point: 250 ‘F (121.2‘C) Density: 1.6311 at 59 ‘F ( 1514 ‘C)Freezing Point: -8 ‘F (-2335 ‘C) Water Solubility: 0.02% at 77 ‘F (25 ‘C)Vapor Prcssurr: 13 mh Hg at 68 ‘F (20 ‘C) Other Solubilities: Miscible with alcohol, ether. benxene, chloro<strong>for</strong>m, <strong>and</strong> oils.Surface Tension: 31.74 dyne/cm at 68 ‘F (20‘C) Odor Threshold: 47 to 71 ppm (poor warning propertiesince olfactory fatigueViscosity: 0.84 CP at 77 ‘F (25‘C) is probable)Refhction Index: 1.50534 at 68 l F (20 ‘C) EvaporatSon Ratez 0.15 gal/f&lay at 77 ‘F (25 ‘C)Molecular Weight: 165.82 Saturated Vapor Density (Air = 0.075 lb@ or 1.2 kg/& 0.081 lb/g or 1.296 kg/m3Appearance <strong>and</strong> Odor: Colorless liquid with an ether-like odor.~‘Seclion4, Fire<strong>and</strong>.ExpiosionData ..: ,. .: .‘.. : .: :. .. : ~YL:~::~.;.:~ .:.i: .;.!:.;.:ji::.::.. .::.likrlr Point: Nonflammable 1 Autoignition Temperature: Nonflammable 1 LEL: None reported 1 UEL: None reportedbthguishing Media: For small fires, use dry chemical. carbon dioxide (COJ. For large fires, use water spray, fog, or regular foam.Unumal Fire or Explosion Hgurds: Vapors are heavier than air <strong>and</strong> collect in low-lying areas.Special Flrcflgbtlng Procedures: Because fire may produce toxic thermal decomposition producrs. wear a selfcontained bmathing apparatus(SCBA) with a full facepiece operated in pressuredem<strong>and</strong> or positive-pressurn mode. Apply cooliig water to sides of container until well afterfire is out. Stay away from ends of tanks. Do not release runoff from fire control methods to sewers or waterways.Section 5. Reactivity DataStability/Polymerization: Perchloroethylene is stable up to 932 ‘F (500‘C) in the absence of catalysts, moisture, <strong>and</strong> oxygen but deterioratesrapidly in warm. moist climates. It is slowly decomposed by light. Amine or phenolic stabilixers are usually added. Hazardous polymerizationcannot occur. Chemical Incompatibilities: Slowly (faster in presence of water) corrodes ahnninum, iron. <strong>and</strong> zinc. It is incompatible withchemically active metals (i.e., barium. beryllium, <strong>and</strong> lithium (explodes with lithium shavings), strong oxidii sodium hydroxide, caustic soda,potash, <strong>and</strong> nitric acid. Perchloroethylene <strong>for</strong>ms an explosive mixture with dinitrogen tetraoxide <strong>and</strong> reacts with activated charcoal at 392 ‘F (200l C) to yield hexachlomethane <strong>and</strong> hexachlorobenzene. Conditions to Avoid: Contact with moisture <strong>and</strong> incompatibles.Hazardous Products of Decomposition: Thermal oxidative decomposition of perchloroethylene can produce carbon dioxide <strong>and</strong> toxic chlorine,hydrogen chloride. <strong>and</strong> phosgene gas (also produced by contact with UV light).Section 6. Health Hazard DataCarchgenicity: Perchloroethylene is listed as a carcinogen by The IARC (Group 2B. animal sufficient evidence. human inadequate data)!‘ti)NTP (Class 2. reasonably anticipated as a carcinogen. with limited human evidence <strong>and</strong> sufficient animal evidence)$tes) NIOSH (Class-X,carcinogen defined with no further ex<strong>plan</strong>ation), (la) <strong>and</strong> DFG (MAK-8. justifiably suspected of having carcinogenic potential)(‘@). There issome controversy regarding human carcinogenicity becauseven though there is an increased number of cancers of the skin. colon. lung.mogemtal tract <strong>and</strong> lympho-sarcomas; the dry cleaning <strong>work</strong>ers studied were also exposed to other chemicals. Summary of Rlslux Perchloroethyleneis stored in the fatty tissue <strong>and</strong> slowly metabolized with the loss of chlorine. The half-life of its urinary metabolite (trichlomacetic acid)is 144 hours. Perchloroethylenexerts the majority of its toxicity on the centml nervous system causing. symptoms ranging from tightheadedness<strong>and</strong> slight ‘inebriation’ to unconsciousness. Liver damage is possible after severe acute or mmor long-term exposure. It has asynergistic effect with toluene.continue on next pgeCb@gbt 8 1992 Ckmum Publishing Ccfpmatioa. Any cammrdal ut or WCliop nUnn Ihe pblidM* prmvloa is pohibiOaR 0
Section 6. Health Hazard Data,continuedMedkal Conditions Aggravated by Long-Term Rxposum: Nervous. liver. kidney. or skin disorders. Target Organs: Liver. kidney, eyes.upper respiratory tract. skin, <strong>and</strong> central nervous system. primary Entry Routes: Inhalation snd skin <strong>and</strong> eye contsct. Acute Effects: Exposure tohigh levels can cause liver damage which may take several weeks to develop. Vapor exposum can cause slight smarting of the eyes <strong>and</strong> thmat (inm~ high concentrations). In human studies, exposum to 2000 ppm/5 min caused mild CNS depression: 600 ppm/lO min caused numbness around thelouth, dizziness, <strong>and</strong> incoordination; 180 ppfl hr caused mild eye. nose, <strong>and</strong> throat irritation. flushing of the face <strong>and</strong> neck, headache, somnoma,<strong>and</strong> slurred speech. Skin contact may produce dermatitis because of perchlomethylene’s defatting action (more common after repeatedexposure). Direct eye contact causes tearing <strong>and</strong> burning but no permanent damage. Ingestion is mm but can cause irritation of the lips, mouth adgastrointestinal tract irregular heartbeat nausea I% vomiting diarrhea (possibly blood stained), drowsiness. unconsciousness, <strong>and</strong> rifk of puhonaryedema (fluid in lungs). Chronic Effects: Prolonged exposure can cause impaired memory, extremity (h<strong>and</strong>s, feet) weakness, peripheralneumpathies, impaired vision, muscle cramps, liver damage (fatty degeneration, necrosis, yellow jaundice, <strong>and</strong> dark urine) <strong>and</strong> kidney damage(oliguric uremia, amjesfion <strong>and</strong> granular swelling).FIRST AID Rescuers must not enter areas with potentiaUy high peddoroethykne kvek without a se&contained breathing apparatus.Eyes: Do not allow victim to tub or keep eyes tightly shut. Gently lift eyelids <strong>and</strong> flush immediately <strong>and</strong> continuously with flooding amounts ofwater until transported to an emergency medical facility. Consult a physician immediately. Skin: Quicwy remove contaminated clothing. Rinsewith flooding amounts of water <strong>for</strong> at least 15 min. Wash exposed area with soap <strong>and</strong> water. For reddened or blistered skin, consult a physician.Inhaiation: Remove exposed petson to Besh air <strong>and</strong> suppott breathing as needed Never adminirtcr u&nalinr Ingestion: Never give anything bymouth to an unconscious or convulsing person. Contact a poison control center <strong>and</strong> unless otherwise advised, have that cons&ru uad ufen persondrink 1 to 2 glasses of water. then induce vomiting. Be sure victims head is positioned to avoid aspiration of vomitus into the lungs. Note toPhysicians: Monitor level of consciousness, EEG (abnormalaties may indicate chronic toxicity), blood enyme levels (<strong>for</strong> 2 to 3 wk after exposure),EKG, adequacy of respirations & oxygenation. <strong>and</strong> liver <strong>and</strong> kidney function. BEZs: C$& io expired air (10 ppm). sample prior to last shiftof <strong>work</strong> week; C+& in blood (1 mg/L). sample prior to last shift of <strong>work</strong> week; trichlomacetic acid in urine (7 mg/L). sample at end of <strong>work</strong>week.Section 7. Spill, Leak, <strong>and</strong> Disposal Procedures :Spill/Leak: Notify safety personnel, isolate <strong>and</strong> ventilate area. deny enlay. <strong>and</strong> stay upwind. Shut off ignition sources (although noncombustible, it<strong>for</strong>ms toxic vapors from thermal decomposition). For small spills. take up with earth, s<strong>and</strong>, vermiculite, or other absorbent, noncombustiblematerial <strong>and</strong> place in suitable containers <strong>for</strong> later disposal. For large spills, dike far ahead of spill <strong>and</strong> await reclamation or disposal. Report anyrelease in excess of 1 lb. Follow applicable OSHA regulations (29 CFR 1910.120). Environmental Transport: If released to <strong>soil</strong>, perchloroethyleneevaporates <strong>and</strong> some leaches to groundwater. It may absorb slightly to <strong>soil</strong>s with heavy organic matter. Biodegradation may be important inanaerobic <strong>soil</strong>s. In water, it is subjecto rapid volatilization with an estimated half-life from
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1.0 INTRODUCTIONThis Work Plan (WP)
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2.0 SITE BACKGROUNDMCB Camp Lejeune
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HAZARD ANALYSISEM 38s i1 Ott 92nLll