work plan for soil remediation, sampling and analysis plan, site ...

. .SECTION 6. HEXLTH HAZARD. IfiFORMATIOIV. cont. . . . . . . - -- . . . . ..- -..---,.Ias gas is almost Lwiec as dca~e as ;lit &if (see SOX, 3). ;Mcdicrl Conditions Aggravated by I~ng-Term &OSW~ None f~?ontd.“arget Organs: None rcponcd. Primary Entry: IahJtioa. .h~te EKects: Initial sympmas of Ihe effas of simple asphyxianrpa arc rapid respiration and air hunger. dimiuished mead akncss, aad &paired muscular coordiaxtioe CoUiauing lack of oxygencues faulty judgmczL depression of all sczsakons. rapid ftig?% aad c=otioaal iasubilicy. As rhe asphyxia coatiaues. aausca: vomitiaq;pmstioa; loss of consciousness; and. finally, coavulsiort; deep COEU; and dexth cxa occur. Chronic EKeco: None mpohd.FIRST AID: Inhalation. would-be mscuc~s aced (0 be coaczzd about rhcir owg sxf~y whca eatig conf%cd, porfy vc~&M,axygcadeficicar areas. Seif-caataiacd bretiag quipazeat I=*SL be rexdily available for rcscxax. StaJioa srandby wozkcs outside theimmc&iarc area so rhac rhcy cm summon additional help if it is ~czded. Remove the exposed ~CTSO~ LO ~IZA air. I#UJTC andlor supporthis or her breathing as needed. Have qualified atcdicxl pcsoa--. -4 adaiaisur oxygen as rquimd. Commcna: The uueze fldiliryof isobutyleac gas wva~u spccixl aucasioa evca during rcscz opcrarioas. RCSXC pcnoancl mu% UOL smoke AU czzeqcacy iz’“ls andhodligh~ thxt must be low& inro cac!oscd areas for rescue opcyiol~ azust be explosion proof. Obka this quipmnt before xayemerge-Xy OCM aad make iL accessible co cmcrgucy-rcsporw paxoannci. CcC med1a.i help (Ia plan& PanLttediC, communi~) for111 exposures. Seek pr0cqX malicxi assisuncc for funha Irc--,U -‘---L obscvtioa, aad support after fit aid.SECTION 7. SPILL. LEAK. AND DISPOSAL PROCEDURESSpiillkk Tnzax any iwhqluu gru leak a M enwpcy. If the leaking gas has aoc yet ignited, use water sprxy to direct fixmmxble gxsairmirrucs away from sourca of igaidoo. Extiaguisb all SOIEU of igaidoa as quickly as possible; homvcr. if the lakiag gxs is burning,do not a~~cmpr 10 cxbguis& rho flama uaril UC sauxcc of the iobutylcac gxs is loufed aad sealed. OthcrwiK, fhxaabie is0bucyicac gasairatixatres cfo explode without wxrniag and cause widesp& dmxge char might uoc have oamrcd if the original fat hxd baa aowedIO bum i&elf OUL 11 ir is aazssary ~3 extiaguish isobulyiuc Ilazzs ia order 10 gain access V) a shutoff valve, use dry Chtzi~a! or carb0afioxidc as extiguishiag ageart. WYU Disposal: Coatxct you supplier or a liceascd wamxor for dcticd recammadacioas. FollowFcda-d, scau, and local cegulaLious.OS&i DexigaadoasAirCoouminaar(29 CFR 1910.1000 Subparct): Not LisudEPA Desfgaarhas (40 CFR 5024): Not L&dSECTION 8. SPECIAL PROTECTIOti LiFOR.M.4TION : .. ...I’...- .,.Rapiraror. Follow OSHA rapiracar rcguladoas (29 CPR 1910.134). For emergency ar aoaroaLiae opcrxtiom (leaks or clexaiag rcxctarvessels and storage tanks). wear an !XBA. Waraingz Air-pur@iag respinton will n0l proreCr Workers in Oxyecn-detideat ~sphtrrt.which lack warning w to wack in them safely mquirs rlw a Sc8A be warn. Vcntfladoa: hall aad opaate gaicral ad locala cxplosioa-proof vcacilacion syslcrm powerful caough 10 mxiauia xizbome levels of this matah! b&w the lower explosive limirJcd in h 4. Locd cxhausc vcatilarioa is prcfd beuusc ir prevents dispersion of the conrrminmc into he gead work xca by4tlimia~ is at i0 saurce. Coasuk the Usr edition of Ccniua dcratce 103 for &tied n2ammadarioru Safefy Stations: M&e ancrgeacyeyewash St&a& ufety/quick-dIcaCh showm, aad wu.Siag facilities avxiIxble in urork xrws. Coatamiaati Equipment CaauCrleases pose a spaiai hazard; saft leasa mxy absarb irritants, aad ail leasa coaccarrxte tha Da IWI wear coatxct kasa ia say wark arex.Commcnb: Practice good pcrsaaxl hygiuc; always wash thoroughly after uxiag &is mxtcrial aad befare cuing. drinking, smoking. usingLb roiltr, or applying cosaluia. Keep it off yoor &hiag tad equipment Avoid ~aasfcrriag it from your hrndt TV .wur rrrouth while eadngd&king, ar samking. Da mt cak cfdak or smoke in say work area Da aoc inhale hobutyiaxe vapor.SECTION 9. SPECIAL PRECAUTIOfiS AND COMMENTS . .. ::-s. ,. . ,.‘.“S~dSegregatloo: Stam itobu~lcac ia closed, ptess&& conuinen ia a cool, dry, well-vcafilrrcd arca away iha sources of ignirioa,ombustibic azarrrials. aad moag oxidiza~ Prarccr eoaraiaa fmm physical damage. !Zagiaeering Coatr0k Make sarc all eagiactringsysum @uductiou tm7sspoKaKioa) ace of auxialum explosion-proof desigz EIecdulIy gmuad md bond an caataha% pipdim ctc,a& ia shippiag, uaasferriag, &g, pradacrion, aad sampiiig 0pu&ms to prcvatr static sparks. Comments: Isabutykae is aacxucmeiy explosive md nlmmnhlc gxs. It amst not be cx~osd ta my possible source of ignition ia work or age trcuTmasportltlon Data (49 CFR 172.101-t)DOT Shippbg Nama: Iiqucfkd Peoolcum GasDOT Hard CIassz Ramaable GasID so. UN1055DOT Label: Flammxblc GasDOT Packaging Rquiremena: 49 C!Zl1733W, 3 14,3 ISDOT Packaging Excepdons: 49 CX 173.306MO Shipping Same: IrobutyleaeCd0 Honrd CIus: 21510 Lab& Ramrzlblc Gasrferenccs: 1.6. Q4-94. 116.117. 120.111._