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Report from the Sub-comittee on the environment and health

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Fuzzy Expert model<br />

Expert assessment<br />

Deterministic models: <str<strong>on</strong>g>the</str<strong>on</strong>g><br />

MACRO model<br />

148<br />

c<strong>on</strong>centrati<strong>on</strong> of pesticides in <str<strong>on</strong>g>the</str<strong>on</strong>g> uppermost groundwater by means of<br />

<str<strong>on</strong>g>the</str<strong>on</strong>g> deterministic model PESTLA, using data for degradati<strong>on</strong> <strong>and</strong><br />

adsorpti<strong>on</strong> to soil. The Yardstick operates with s<strong>and</strong>y soil, which is<br />

typical for <str<strong>on</strong>g>the</str<strong>on</strong>g> Ne<str<strong>on</strong>g>the</str<strong>on</strong>g>rl<strong>and</strong>s. The results are given for five classes of soil<br />

<strong>and</strong> spring <strong>and</strong> autumn spraying, where <str<strong>on</strong>g>the</str<strong>on</strong>g> temperature <strong>and</strong> precipitati<strong>on</strong><br />

vary. Since <str<strong>on</strong>g>the</str<strong>on</strong>g> method is based <strong>on</strong> <str<strong>on</strong>g>the</str<strong>on</strong>g> same simple indexing methods or<br />

<strong>on</strong> <str<strong>on</strong>g>the</str<strong>on</strong>g> deterministic model PESTLA, it does not produce results<br />

fundamentally different <str<strong>on</strong>g>from</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g>se. Like <str<strong>on</strong>g>the</str<strong>on</strong>g> Dutch point system, <str<strong>on</strong>g>the</str<strong>on</strong>g><br />

method is based <strong>on</strong> risk thinking <strong>and</strong> <str<strong>on</strong>g>the</str<strong>on</strong>g>refore cannot be used directly for<br />

ranking pesticides because it depends partly <strong>on</strong> local envir<strong>on</strong>mental<br />

c<strong>on</strong>diti<strong>on</strong>s <strong>and</strong> partly <strong>on</strong> <str<strong>on</strong>g>the</str<strong>on</strong>g> actual cultivati<strong>on</strong> practice.<br />

This method was developed in <str<strong>on</strong>g>the</str<strong>on</strong>g> Ne<str<strong>on</strong>g>the</str<strong>on</strong>g>rl<strong>and</strong>s (van der Werf, Zimmer<br />

1998). The risk of groundwater polluti<strong>on</strong> is assessed partly <strong>on</strong> <str<strong>on</strong>g>the</str<strong>on</strong>g> basis<br />

of a GUS index <strong>and</strong> partly <strong>on</strong> <str<strong>on</strong>g>the</str<strong>on</strong>g> basis of a “leaching risk” parameter.<br />

This parameter requires supplementary c<strong>on</strong>siderati<strong>on</strong>s or model analyses.<br />

A high level of expert knowledge is needed to use <str<strong>on</strong>g>the</str<strong>on</strong>g> method, making it<br />

difficult to work with. The method can <str<strong>on</strong>g>the</str<strong>on</strong>g>refore not be used under<br />

Danish c<strong>on</strong>diti<strong>on</strong>s without c<strong>on</strong>siderable input <str<strong>on</strong>g>from</str<strong>on</strong>g> a variety of experts.<br />

For this reas<strong>on</strong>, <str<strong>on</strong>g>the</str<strong>on</strong>g> model has not been used here to assess leaching.<br />

However, <str<strong>on</strong>g>the</str<strong>on</strong>g> method also covers o<str<strong>on</strong>g>the</str<strong>on</strong>g>r envir<strong>on</strong>mental aspects than<br />

groundwater so its use could be c<strong>on</strong>sidered in c<strong>on</strong>tinuing work <strong>on</strong><br />

envir<strong>on</strong>mental indices.<br />

In an expert assessment, <strong>on</strong>e or more experienced experts designate<br />

substances <strong>on</strong> <str<strong>on</strong>g>the</str<strong>on</strong>g> basis of existing data <strong>and</strong> an integrated assessment. An<br />

expert assessment thus includes a systematic review of data <strong>and</strong><br />

assessment elements that can be classified <strong>and</strong> ranked in <str<strong>on</strong>g>the</str<strong>on</strong>g> normal way,<br />

but must at <str<strong>on</strong>g>the</str<strong>on</strong>g> same time be combined with an experience-based<br />

assessment of lacking data <strong>and</strong> unclassifiable elements. A large number<br />

of factors are c<strong>on</strong>sidered in <str<strong>on</strong>g>the</str<strong>on</strong>g> assessment of <str<strong>on</strong>g>the</str<strong>on</strong>g> risk of leaching to <str<strong>on</strong>g>the</str<strong>on</strong>g><br />

groundwater within <str<strong>on</strong>g>the</str<strong>on</strong>g> framework of <str<strong>on</strong>g>the</str<strong>on</strong>g> authorisati<strong>on</strong> scheme for<br />

pesticides. They include <str<strong>on</strong>g>the</str<strong>on</strong>g> inherent properties of <str<strong>on</strong>g>the</str<strong>on</strong>g> substances <strong>and</strong><br />

<str<strong>on</strong>g>the</str<strong>on</strong>g>ir metabolites <strong>and</strong> degradati<strong>on</strong> products, combined with <str<strong>on</strong>g>the</str<strong>on</strong>g> dosage,<br />

<str<strong>on</strong>g>the</str<strong>on</strong>g> time of applicati<strong>on</strong> <strong>and</strong> any finds in groundwater. On <str<strong>on</strong>g>the</str<strong>on</strong>g> basis of<br />

experience, some substances are judged to lie closer to <str<strong>on</strong>g>the</str<strong>on</strong>g> critical limit<br />

for leaching to groundwater than o<str<strong>on</strong>g>the</str<strong>on</strong>g>rs. This assessment determines<br />

whe<str<strong>on</strong>g>the</str<strong>on</strong>g>r a product can be authorised or not. Precise designati<strong>on</strong> of <str<strong>on</strong>g>the</str<strong>on</strong>g><br />

most problematical substances requires a thorough examinati<strong>on</strong> of <str<strong>on</strong>g>the</str<strong>on</strong>g><br />

documentati<strong>on</strong> <strong>and</strong> assessment of m<strong>on</strong>itoring results, <strong>and</strong> possibly<br />

calculati<strong>on</strong>s with a leaching model, e.g. MACRO (see below). This form<br />

of assessment has been used in <str<strong>on</strong>g>the</str<strong>on</strong>g> assessment of many of <str<strong>on</strong>g>the</str<strong>on</strong>g> pesticides<br />

that have been placed <strong>on</strong> <str<strong>on</strong>g>the</str<strong>on</strong>g> blacklist.<br />

A number of actual transport models that describe <str<strong>on</strong>g>the</str<strong>on</strong>g> transport of<br />

pesticides down through <str<strong>on</strong>g>the</str<strong>on</strong>g> root z<strong>on</strong>e have been developed (e.g.<br />

LEACHM, PELMO, PESTLA <strong>and</strong> MACRO). These are so-called<br />

deterministic models in which it is assumed that <str<strong>on</strong>g>the</str<strong>on</strong>g> outcome under given<br />

assumpti<strong>on</strong>s will always be <str<strong>on</strong>g>the</str<strong>on</strong>g> same. The so-called stochastic (or<br />

probabilistic) models, <strong>on</strong> <str<strong>on</strong>g>the</str<strong>on</strong>g> o<str<strong>on</strong>g>the</str<strong>on</strong>g>r h<strong>and</strong>, take account of variati<strong>on</strong>s in <str<strong>on</strong>g>the</str<strong>on</strong>g><br />

system <strong>and</strong> thus <strong>on</strong>ly talk about <str<strong>on</strong>g>the</str<strong>on</strong>g> probability of a given outcome. There<br />

are as yet no suitable stochastic models for ranking pesticides’ potential<br />

leaching to <str<strong>on</strong>g>the</str<strong>on</strong>g> groundwater. Unlike <str<strong>on</strong>g>the</str<strong>on</strong>g> simple index methods, both

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