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Report from the Sub-comittee on the environment and health

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Soil<br />

Residues in <str<strong>on</strong>g>the</str<strong>on</strong>g> soil<br />

Drain water<br />

The atmosphere<br />

190<br />

Scenarier = Scenarios<br />

Plus-plus = ++scenario<br />

Plus = +scenario<br />

Nul-plus = 0+scenario<br />

Nul = 0-scenario<br />

Nudrift = present producti<strong>on</strong><br />

Anvendt pesticidmængde i t<strong>on</strong>s = Quantity of pesticide used, in t<strong>on</strong>nes)<br />

10.2.2 Pesticides in soil, surface water <strong>and</strong> <str<strong>on</strong>g>the</str<strong>on</strong>g> atmosphere<br />

After spraying, pesticides are broken down <strong>and</strong> absorbed by <str<strong>on</strong>g>the</str<strong>on</strong>g> soil <strong>and</strong><br />

plants. Normally, <strong>on</strong>ly substances with a half-life of max. 3 m<strong>on</strong>ths in<br />

soil at 10°C <strong>and</strong> at 20°C are authorised. In <str<strong>on</strong>g>the</str<strong>on</strong>g> case of substances with<br />

shorter half-lives, <str<strong>on</strong>g>the</str<strong>on</strong>g> residual quantity is much smaller. However, in<br />

field c<strong>on</strong>diti<strong>on</strong>s, where <str<strong>on</strong>g>the</str<strong>on</strong>g> c<strong>on</strong>diti<strong>on</strong>s for degradati<strong>on</strong> are not optimal,<br />

degradati<strong>on</strong> can take l<strong>on</strong>ger. The temperature <strong>and</strong> humidity are important<br />

factors in this c<strong>on</strong>necti<strong>on</strong>, as described in secti<strong>on</strong> 4.6.4. In <str<strong>on</strong>g>the</str<strong>on</strong>g> winter<br />

m<strong>on</strong>ths, <str<strong>on</strong>g>the</str<strong>on</strong>g> degradati<strong>on</strong> process in <str<strong>on</strong>g>the</str<strong>on</strong>g> topsoil thus comes to a st<strong>and</strong>still<br />

at low temperatures, <strong>and</strong> in <str<strong>on</strong>g>the</str<strong>on</strong>g> summer m<strong>on</strong>ths, drying out of <str<strong>on</strong>g>the</str<strong>on</strong>g> soil<br />

halts <str<strong>on</strong>g>the</str<strong>on</strong>g> degradati<strong>on</strong> process. If use of <str<strong>on</strong>g>the</str<strong>on</strong>g> currently authorised pesticides<br />

ends in a given area, <str<strong>on</strong>g>the</str<strong>on</strong>g> residues in <str<strong>on</strong>g>the</str<strong>on</strong>g> soil will normally be degraded<br />

<strong>and</strong> thus not accessible to plants or animals, or leach to <str<strong>on</strong>g>the</str<strong>on</strong>g> groundwater,<br />

after a cultivati<strong>on</strong> seas<strong>on</strong>.<br />

Degradati<strong>on</strong> of <str<strong>on</strong>g>the</str<strong>on</strong>g> residues of all pesticides is prevented by <str<strong>on</strong>g>the</str<strong>on</strong>g> fact that<br />

<str<strong>on</strong>g>the</str<strong>on</strong>g> molecules diffuse into microscopic pores in <str<strong>on</strong>g>the</str<strong>on</strong>g> soil particles, where<br />

<str<strong>on</strong>g>the</str<strong>on</strong>g>y can no l<strong>on</strong>ger be reached by microorganisms. These residues can be<br />

detected with special analytical methods with effective extracti<strong>on</strong> <strong>and</strong><br />

sensitive apparatus <strong>and</strong> are of <str<strong>on</strong>g>the</str<strong>on</strong>g> same order of magnitude as <str<strong>on</strong>g>the</str<strong>on</strong>g><br />

c<strong>on</strong>centrati<strong>on</strong>s supplied to <str<strong>on</strong>g>the</str<strong>on</strong>g> cultivati<strong>on</strong> systems through atmospheric<br />

depositi<strong>on</strong> of pesticides transported over l<strong>on</strong>g distances. Lastly, it should<br />

be menti<strong>on</strong>ed that it is possible to detect formerly authorised persistent<br />

pesticides, such as DDT <strong>and</strong> lindane, in relatively high c<strong>on</strong>centrati<strong>on</strong>s in<br />

<str<strong>on</strong>g>the</str<strong>on</strong>g> soil in areas in which <str<strong>on</strong>g>the</str<strong>on</strong>g>y were used more than 15 years ago. That<br />

applies particularly to orchards. It can thus be c<strong>on</strong>cluded that old,<br />

persistent pesticides that are no l<strong>on</strong>ger authorised are still being detected<br />

in soil, whereas most of <str<strong>on</strong>g>the</str<strong>on</strong>g> authorised pesticides will be degraded <strong>on</strong>e to<br />

two years after use of <str<strong>on</strong>g>the</str<strong>on</strong>g>m ceases.<br />

The supply of pesticides to drain water depends <strong>on</strong> <str<strong>on</strong>g>the</str<strong>on</strong>g> dosage, <str<strong>on</strong>g>the</str<strong>on</strong>g><br />

degradati<strong>on</strong> <strong>and</strong> adsorpti<strong>on</strong> in <str<strong>on</strong>g>the</str<strong>on</strong>g> topsoil <strong>and</strong> evaporati<strong>on</strong>. If pesticides<br />

were totally phased out, <str<strong>on</strong>g>the</str<strong>on</strong>g> amount that could be transported down in <str<strong>on</strong>g>the</str<strong>on</strong>g><br />

soil would disappear. However, leaching of <str<strong>on</strong>g>the</str<strong>on</strong>g> residues in <str<strong>on</strong>g>the</str<strong>on</strong>g> soil could<br />

c<strong>on</strong>tinue for some years, depending <strong>on</strong> precipitati<strong>on</strong> events <strong>and</strong> <str<strong>on</strong>g>the</str<strong>on</strong>g> soil<br />

c<strong>on</strong>diti<strong>on</strong>s, which determine <str<strong>on</strong>g>the</str<strong>on</strong>g> adsorpti<strong>on</strong> <strong>and</strong> degradati<strong>on</strong> of <str<strong>on</strong>g>the</str<strong>on</strong>g><br />

substances.<br />

If pesticides were no l<strong>on</strong>ger used <str<strong>on</strong>g>the</str<strong>on</strong>g> problem of evaporati<strong>on</strong> <strong>and</strong> spray<br />

drift <str<strong>on</strong>g>from</str<strong>on</strong>g> <str<strong>on</strong>g>the</str<strong>on</strong>g> areas in questi<strong>on</strong> would disappear. However, <str<strong>on</strong>g>the</str<strong>on</strong>g>re would<br />

still be a supply of pesticides through l<strong>on</strong>g-range transboundary<br />

atmospheric transport. Pesticides would thus c<strong>on</strong>tinue to be supplied with<br />

precipitati<strong>on</strong>, although less frequently <strong>and</strong> in c<strong>on</strong>siderably smaller<br />

c<strong>on</strong>centrati<strong>on</strong>s than described in secti<strong>on</strong> 4.5. It should be noted here that<br />

<str<strong>on</strong>g>the</str<strong>on</strong>g> finds described cover <strong>on</strong>ly some of <str<strong>on</strong>g>the</str<strong>on</strong>g> pesticides that could be<br />

transported to <str<strong>on</strong>g>the</str<strong>on</strong>g> atmosphere through spray drift <strong>and</strong> evaporati<strong>on</strong> here in

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