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Membrane and Desalination Technologies - TCE Moodle Website

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Advanced <strong>Membrane</strong> Fouling Characterization 113<br />

Permeate flux (ms –1 )<br />

1.2×10 –5<br />

1.1×10 –5<br />

1.0×10 –5<br />

9.0×10 –6<br />

8.0×10<br />

0 100 200 300 400 500<br />

–6<br />

Time (min)<br />

Fig. 3.5. Decline of permeate flux with time in fouling experiments with different colloidal concentrations<br />

of 25 mg/L ( filled square), 50 mg/L ( filled circle), 100 mg/L ( filled triangle), 150 mg/L ( filled<br />

inverted triangle), <strong>and</strong> 200 mg/L ( filled diamond ). Driving pressure = 1.5 10 6 Pa, salt concentration<br />

= 1,000 mg/L NaCl, <strong>and</strong> feed crossflow velocity = 0.15 m/s.<br />

Table 3.2<br />

Properties of the<br />

fitted lines at<br />

different colloidal<br />

concentrations<br />

Colloidal<br />

concentration<br />

(mg/L)<br />

25 1.55 10 10<br />

50 3.19 10 10<br />

100 5.99 10 10<br />

150 8.22 10 10<br />

200 1.11 10 9<br />

Gradient Initial flux (m/s) kf (Pa s/m 2 )<br />

9.84 10 6<br />

9.83 10 6<br />

1.01 10 5<br />

9.69 10 6<br />

1.01 10 5<br />

3.97 10 9<br />

8.32 10 9<br />

1.47 10 10<br />

2.33 10 10<br />

2.87 10 10<br />

synthetic feed water with different colloidal concentrations, determined from the lines best<br />

fitted to the flux data shown in Fig. 3.5.<br />

Table 3.2 shows that the fouling potential of the synthetic water increases with colloidal<br />

concentration. This phenomenon is reasonable because more colloidal particles are brought<br />

onto membrane surface at higher particle concentration. The fouling potentials are plotted<br />

against colloidal concentrations <strong>and</strong> shown in Fig. 3.6. The graph shows that all the data<br />

points can be well fitted with a straight line. The strong linear relationship between fouling<br />

potential <strong>and</strong> colloidal concentration indicates that fouling potential is an excellent indicator<br />

of the amount of foulants in the feed water.

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