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Membrane and Desalination Technologies - TCE Moodle Website

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304 J. Paul Chen et al.<br />

a Feed b<br />

<strong>Membrane</strong><br />

module<br />

Permeate<br />

As cross-flow mode is preferred over a dead-end one, the proper choice of the module is<br />

the next crucial step. For a given module design <strong>and</strong> feed solution, the cross-flow velocity is<br />

the main parameter that determines mass transfer in the module. Four cross-flow operations<br />

shown in Fig. 7.17 are used:<br />

1. Co-current<br />

2. Counter-current<br />

3. Cross-flow with perfect permeate mixing<br />

4. Perfect mixing<br />

Feed<br />

<strong>Membrane</strong> module<br />

Permeate<br />

Dead-end operation Cross-flow operation<br />

Fig. 7.16. Dead-end <strong>and</strong> cross-flow operation.<br />

Retentate<br />

In co- <strong>and</strong> counter-current operations, the feed <strong>and</strong> permeate streams flow co-currently or<br />

counter-currently along the membrane. In the cross-flow mode, it is assumed that mixing<br />

occurs so rapidly on the permeate side that the composition distributes equally. Among these<br />

modes, counter-current flow gives the best results <strong>and</strong> the perfect mixing gives the worst<br />

result.<br />

In practice, systems usually operate in the cross-flow mode with perfect mixing on the<br />

permeate side. In general, two basic flow schemes can be used in the system design (1) a<br />

single-pass system <strong>and</strong> (2) a recycling system, as shown in Fig. 7.18.<br />

In the single-pass system, the feed stream passes through the system only once, <strong>and</strong> there is<br />

no recycling. In a recycling system, a recirculation pump is used to recycle the retentate<br />

stream. For small-scale applications, a batch system can be used, as shown in Fig. 7.19.<br />

Usually, a single-stage operation does not give the desired product quality, <strong>and</strong> a second<br />

stage is required. A combination of stages is called a cascade. In a cascade operation, a large<br />

number of units are used, <strong>and</strong> the permeate of the first stage is the feed for the second stage<br />

<strong>and</strong> so on. An example of a two-stage operation process is shown in Fig. 7.20. When more<br />

stages are required, the optimization of the process becomes very complex <strong>and</strong> difficult.<br />

6.3.2. Nanofiltration <strong>and</strong> Reverse Osmosis<br />

A typical NF or RO unit includes raw water pumps, pre-treatment, membrane modules,<br />

disinfection units, storage, <strong>and</strong> distribution elements (3). The principal design considerations<br />

for NF <strong>and</strong> RO units are:

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