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Membrane and Desalination Technologies - TCE Moodle Website

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<strong>Membrane</strong> Systems Planning <strong>and</strong> Design 373<br />

in TMP at the temperature of interest relative to that at a given reference temperature<br />

(typically 25 C for NF/RO systems) is dependent on the specific proprietary membrane<br />

used <strong>and</strong> can be calculated by means of a TCF, as shown in Eq. (32):<br />

1 1<br />

TCF ¼ exp U þ ; (32Þ<br />

T þ 273 298<br />

where TCF is the temperature correction factor, dimensionless, T is the water temperature,<br />

C, <strong>and</strong> U is the membrane-specific manufacturer-supplied constant, 1/ K.<br />

Alternatively, many NF/RO membrane manufacturers may supply tables specifying TCF<br />

values over a range of temperatures for a given membrane. Once the appropriate TCF is<br />

known, the required TMP at temperature T of interest can be calculated by dividing the TMP<br />

at the reference (i.e., design) temperature (commonly 25 C for NF/RO systems) by the TCF<br />

value, as shown in Eq. (33):<br />

TMPT ¼ TMP25<br />

; (33Þ<br />

TCF<br />

where TMPT is the trans-membrane pressure (temperature-corrected), psi, TMP25 is the<br />

trans-membrane pressure at 25 C reference temperature, psi, <strong>and</strong> TCF is the temperature<br />

correction factor, dimensionless.<br />

Note that Eqs. (6) <strong>and</strong> (32) also allow the calculation of the TMP reduction resulting from<br />

decreased water viscosity at higher feed water temperatures during warmer months of the<br />

year.<br />

5.4. Cross-Connection Control<br />

In the context of membrane filtration systems, cross-connection control measures are<br />

implemented to prevent chemicals from the cleaning process from contaminating the feed<br />

or filtrate streams. States may have particular requirements for cross-connection control,<br />

although in general there are two strategies that are commonly used: a double block <strong>and</strong> bleed<br />

valving arrangement or a removable spool. These strategies are applicable to both MF/UF <strong>and</strong><br />

NF/RO systems; however, because MCF systems typically utilize modules that are disposable<br />

cartridges, these systems are not usually subject to chemical cleaning <strong>and</strong> thus crossconnection<br />

control measure are generally unnecessary for these systems.<br />

The double block <strong>and</strong> bleed valve arrangement is the most common method of crossconnection<br />

control for large membrane filtration systems. A schematic illustrating this<br />

method is shown in Fig. 8.5. In summary, two isolation valves (V-1A <strong>and</strong> V-2A) are placed<br />

in the feed line to isolate it from the cleaning chemicals. These are the block <strong>and</strong> bleed valves,<br />

respectively. During the cleaning process, valve V-4A <strong>and</strong> V-6A are opened to bring cleaning<br />

solution(s) into membrane rack (i.e., unit) A. Although valve V-3A is kept closed during this<br />

operation, if it were to leak it would allow chemicals to pass into the common feed manifold,<br />

causing contamination. In order to prevent this potential contamination, valve V-1A is also<br />

closed <strong>and</strong> valve V-2A is opened. With this configuration, if valve V-3A leaks, the cleaning<br />

solution(s) simply flows through valve V-2A to waste. A similar block <strong>and</strong> bleed valve

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