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Membrane and Desalination Technologies - TCE Moodle Website

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494 P. Kajitvichyanukul et al.<br />

3. Eight reactions that describe the rates of consumption or production of the different species, as<br />

well as the stoichiometric linkages among the rates<br />

4. Reaction with diffusion of all the soluble species in the biofilm<br />

5. Growth, decay, detachment, <strong>and</strong> flux of each biomass type by location in the biofilm<br />

6. Constant or periodic detachment of biofilm, both of which allow for protection of biomass deep<br />

inside the biofilm.<br />

A series of examples illustrates insights that the TSMSBM can provide the transient<br />

development of multiple-species biofilms; the roles of soluble microbial products, <strong>and</strong> detachment<br />

in controlling the distribution of biomass types <strong>and</strong> process performance; <strong>and</strong> how<br />

backwashing affects the biofilm in drinking-water biofiltration.<br />

4.2. <strong>Membrane</strong> Bioreactor<br />

The MBR is usually referred to a bioreactor integrated to a membrane module system. This<br />

technology has been developed over 30 years ago (79) <strong>and</strong> it is mostly applied to treat<br />

industrial wastewater, domestic wastewater, <strong>and</strong> specific small municipal wastewater treatment<br />

plants (80). In drinking water treatment, a promising area of MBR application is NO3 –<br />

removal. Advantages of the MBR include better control of biological activity, effluent that is<br />

free of bacteria <strong>and</strong> pathogens, smaller plant size, <strong>and</strong> higher organic loading rates (81).<br />

In general, membrane bioreactors consist of two compartments, the biological unit <strong>and</strong> the<br />

membrane module (82). The biodegradation of the compounds occur in the biological unit,<br />

while the physical separation of the treated water from the mixed liquor takes place in the<br />

membrane module. MBR systems can be classified into two groups: integrated or submerged<br />

membrane bioreactors <strong>and</strong> external or recirculated membrane bioreactors (82). The first<br />

group, integrated membrane bioreactors, involves outer skin membranes that are internal to<br />

the bioreactor. The driving force across the membrane is achieved by pressurizing the<br />

bioreactor or creating negative pressure on the permeate side (82–85). A diffuser is provided<br />

for mixing <strong>and</strong> facilitating the filtration surface scouring. The second type, external or<br />

recirculated membrane bioreactors, involves the recirculation of the mixed liquor through a<br />

membrane module that is outside the bioreactor (85). The driving force is the pressure created<br />

by high cross-flow velocity along the membrane surface (86, 87). For drinking water <strong>and</strong><br />

groundwater treatment, external membrane bioreactors are widely used for pesticide removal<br />

<strong>and</strong> denitrification.<br />

Types <strong>and</strong> configurations of membranes used in MBR applications include tubular, plate<br />

<strong>and</strong> frame, rotary disk, hollow fiber, organic (polyethylene, polyethersulfone, polysulfone,<br />

polyolefin, etc.), metallic <strong>and</strong> inorganic (ceramic) microfiltration, <strong>and</strong> ultra-filtration membranes<br />

(88). The pore size of membranes ranges from 0.01 to 0.4 mm (82). The fluxes range<br />

from 0.05 to 10 m/day (m 3 /m 2 /day), strongly depending on the configuration <strong>and</strong> membrane<br />

material (82).<br />

In drinking water treatment, major application of membrane bioreactors is denitrification.<br />

This process has many advantages over traditional biological denitrification (22, 82). In<br />

a typical biological denitrification system, post treatment processes are required to separate<br />

microorganisms <strong>and</strong> DOM. By using a membrane bioreactor, the number of post treatment

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