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Part-I - Controller General of Patents Designs and Trademarks

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(12) PATENT APPLICATION PUBLICATION (21) Application No.3073/MUM/2010 A<br />

(19) INDIA<br />

(22) Date <strong>of</strong> filing <strong>of</strong> Application :08/11/2010 (43) Publication Date : 21/06/2013<br />

(54) Title <strong>of</strong> the invention : ROOM TEMPERATURE CHEMICAL METHOD FOR THE SYNTHESIS OF CU2ZNSNS4<br />

ABSORBING LAYER<br />

(51) International classification<br />

(31) Priority Document No :NA<br />

(32) Priority Date :NA<br />

(33) Name <strong>of</strong> priority country :NA<br />

(86) International Application No<br />

:NA<br />

Filing Date<br />

:NA<br />

(87) International Publication No : NA<br />

(61) Patent <strong>of</strong> Addition to Application Number :NA<br />

Filing Date<br />

:NA<br />

(62) Divisional to Application Number<br />

:NA<br />

Filing Date<br />

:NA<br />

:C01G19/00;<br />

C01G3/00<br />

(71)Name <strong>of</strong> Applicant :<br />

1)PROF. CHANDRAKANT DNYANDEV LOKHANDE<br />

Address <strong>of</strong> Applicant :THIN FILM PHYSICS<br />

LABORATORY, DEPARTMENT OF PHYSICS, SHIVAJI<br />

UNIVERSITY, KOLHAPUR 416 004 Maharashtra India<br />

(72)Name <strong>of</strong> Inventor :<br />

1)PROF. CHANDRAKANT DNYANDEV LOKHANDE<br />

2)NANSAHEB MADHUKAR SHINDE<br />

3)DEEPAK PRAKASH DUBAL<br />

(57) Abstract :<br />

The present investigation is related to the preparation <strong>of</strong> polycrystalline <strong>and</strong> compact Cu2ZnSnS4 (CZTS) thin films onto glass<br />

substrates by successive ionic layer adsorption <strong>and</strong> reaction (SILAR) method. This is relatively less expensive <strong>and</strong> convenient for<br />

large area deposition <strong>of</strong> metal chalcogenide thin films. Polycrystalline Cu2ZnSnS4<br />

(CZTS) films have been deposited onto the glass substrates at room temperature using CuS04, ZnS04 <strong>and</strong> SnS04 as cationic<br />

precursors <strong>and</strong> C2H5NS as anionic precursor. As confirmed from X-ray diffraction pattern <strong>and</strong> SEM images, Cu2ZnSnS4 (CZTS)<br />

films were polycrystalline <strong>and</strong> compact with tetragonal crystal structure. The resistivity <strong>of</strong> Cu2ZnSnS4 (CZTS) film is <strong>of</strong> the order<br />

<strong>of</strong> 10 Ω.cm. the Cu2ZnSnS4 (CZTS) film have optical absorption <strong>of</strong> the order <strong>of</strong> 104 cm1.<br />

No. <strong>of</strong> Pages : 14 No. <strong>of</strong> Claims : 9<br />

The Patent Office Journal 21/06/2013 13542

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