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Ion Implantation and Synthesis of Materials - Studium

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Problems 177Behrisch, R., Wittmaack, K. (eds.): Sputtering by Particle Bombardment. III.Characteristics <strong>of</strong> Sputtered Particles, Technical Applications, Topics in AppliedPhysics, vol. 64. Springer, Berlin Heidelberg New York (1991)Matsunami, N., Yamamura, Y., Itikawa, Y., Itoh, N., Kazumata, Y., Miyagawa, S., Morita,K., Shimizu, R., Tawara, H.: Energy dependence <strong>of</strong> the ion-induced sputtering yields<strong>of</strong> monatomic solids. At. Data Nucl. Data Tables 31, 1–84 (1984)Nastasi, M., Mayer, J.W., Hirvonen, J.K.: <strong>Ion</strong>–Solid Interactions: Fundamentals <strong>and</strong>Applications, chap. 9. Cambridge University Press, Cambridge (1996)Sputtering, Y., Yamamura, Y., Itoh, N.: In: Itoh, T. (ed.) <strong>Ion</strong> Beam assisted Film Growth,chap. 4. Elsevier, Amsterdam (1989)Problems12.1 Consider the case <strong>of</strong> (1) Si ions incident on Au; <strong>and</strong> (2) Au ions incidenton Si; both cases for 100 keV incident energies at normal to the sample.Which would have the largest value(a) The dimensionless energy, ε;(b) The electronic energy-loss-rate, dE/dx| e ;(c) Nuclear energy-loss-rate, dE/dx| n ;(d) The projected range, R P(e) Sputtering yield, Y:, (assume binding energy U = 5 eV);(f) Maximum concentration <strong>of</strong> implanted species.12.2 Calculate the sputtering yield values <strong>of</strong> Ne, Ar, <strong>and</strong> Xe incident on Si at45 keV using the expressions for ZBL nuclear stopping given in Chap. 5<strong>and</strong> a binding energy <strong>of</strong> 4.6 eV:(a) Compare your values with the data given in Fig. 12.1(b) Calculate values <strong>of</strong> the dimensionless energy ε for the three cases.Are these ε values in a region where nuclear stopping rates woulddominate? (See Chap. 5.)(c) For a current <strong>of</strong> 10 µA cm −2 <strong>of</strong> Ar, now many monolayers(10 15 atoms cm −2 ) would be removed per second.12.3 (a) Calculate the sputtering yields for 45 keV Ge incident on Si(U = 4.5 eV), <strong>and</strong> compare with the data in Fig. 12.2a for 45 keV Arions incident on Si compare your values with the data given in Fig. 12.1(b) Estimate the maximum concentration <strong>of</strong> implanted Ge forpreferential sputtering factor values <strong>of</strong> 2 <strong>and</strong> 1/212.4 Assume you have a target <strong>of</strong> Si 50 Ge 50 sputtered by 50 keV Ar ions witha preferential sputtering yield <strong>of</strong> Si twice that <strong>of</strong> Ge. AssumeR P (Ar) = 50 nm(a) What is the initial sputter yield ratio Y Si /Y Ge ?(b) What is the steady state yield ratio Y Si /Y Ge ?(c) What is the surface concentration ratio <strong>of</strong> Si to Ge at steady state?(d) How thick a layer <strong>of</strong> SiGe must be removed to achieve steady state?

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