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The genus Cinnamomum

The genus Cinnamomum

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104 U.M. Senanayake and R.O.B. Wijesekera<br />

65–75% of the total volatiles, eugenol accounts for about 70–75% of leaf oil, while<br />

70–90% of the root bark oil accounts for camphor.<br />

Cassia produces only one type of oil, usually called bark oil, obtained by distilling leaves<br />

and bark together. Almost 95% of the oil consists of cinnamic aldehyde. C. camphora is<br />

not a spice, the oil of camphora usually contains only terpenes, camphor and cineole being<br />

the major compounds.<br />

Tracer studies indicate that phenylpropanoids, eugenol and cinnamic aldehydes are<br />

synthesised via the Shikimic acid pathway. <strong>The</strong> phenylalanine skeleton is retained in<br />

the cinnamic aldehyde biosynthesis. <strong>The</strong> end carbon of the alanine chain of phenylalanine<br />

does not contribute to the eugenol biosynthesis. During the eugenol biosynthesis<br />

the end carbon atom of the allyl branch is not derived from phenylalanine, but from<br />

a methyl donor such as methionine.<br />

<strong>The</strong> incorporation of labelled mevalonic acid into terpenes indicated that the normal<br />

mevalonic acid pathway was operating in the cinnamon plant during the biosynthesis of<br />

terpenoid compounds. Tracer studies also indicated that the leaf was the predominant<br />

site of biosynthesis of these compounds.<br />

References<br />

Angmor, J.E., Dicks, D.M., Evans, W.C. and Santra, D.K. (1972) Studies on <strong>Cinnamomum</strong><br />

zeylanicum Part 1. <strong>The</strong> Essential Oil components of C. zeylanicum Nees grown in Ghana.<br />

Planta Med., 21, 416–420.<br />

Angmor, J.E., Dicks, D.M. and Evans, W.C. (1979) Chemical changes in Cinnamon oil during<br />

the preparation of the bark oil. Biosynthesis of cinnamaldehyde and related compounds.<br />

Planta Med., 35, 342–347.<br />

Asakawa, Y., Komatsu, T., Hayashi, S. and Matsuura, T. (1971) Chemical components of the<br />

benzene extracts of <strong>Cinnamomum</strong> loureirii Nees (Lauraceae). <strong>The</strong> Flav. Ind., 2, 114–119.<br />

Attaway, J. and Buslig, B.S. (1968) Conversion of linalool to -terpineol in citrus. Biochem.<br />

Biophys. Acta, 164, 609–610.<br />

Banthorpe, D.V., Charlwood, B.V. and Francis, M.J.O. (1972) <strong>The</strong> biosynthesis of monoterpenes.<br />

Chem. Rev., 72, 115–126.<br />

Banthorpe, D.V. and Wirz-Justice, A. (1969) Terpene biosynthesis. Part 1. Preliminary tracer<br />

studies on terpenoids and chlorophyll of Tanacetum vulgare L. J. Chem. Soc., (C), 2694–2696.<br />

Baruah, A.K.S., Bhagat, S.D., Hazarika, J.N. and Saikia, B.K. (1975) Volatile oil of<br />

<strong>Cinnamomum</strong> camphora grown in Jorhat, Assam. Indian J. Pharm., 37, 39–41.<br />

Battersby, A.R., Laing, D.G. and Ramage, R. (1972) Biosynthesis. Part XIX. Concerning the<br />

biosynthesis of () camphor and ()-borneol in Salvia officinalis. JSC Perkin, 1, 2743–2747.<br />

Beytia, E., Valenzuela, P. and Cori, O. (1969) Terpene biosynthesis: Formation of nerol, geraniol,<br />

and other prenols by an enzyme system from Pinus radiata seedling. Arch. Biochem. Biophys.<br />

129, 346–356.<br />

Bhramaramba, A. and Sidhu, G.S. (1963). Chromatographic Studies on Indian cinnamon leaf<br />

oil. Perfumer & Essential oil Res., 54, 732–738.<br />

Birch, A.J. (1963) Biosynthetic pathways. In: Chemical Plant Taxonomy (ed. T. Swain),<br />

pp. 141–166. Academic Press, London.<br />

Bohm, B.A. (1965). Shikimic Acid. Chem. Rev., 65, 435–466.<br />

Brown, E.G. (1955) Cinnamon and cassia: Sources, production and trade, Part 1. Cinnamon.<br />

Colonial Pl. Anim. Prod., 5, 257–280.<br />

Brown, E.G. (1956) Cinnamon and cassia: Sources, production and trade, Part II. Cassia. Colonial<br />

Pl. Anim. Prod., 6, 96–116.<br />

Bullock, J.D. (1965) <strong>The</strong> Biosynthesis of Natural Products, pp. 77–93. McGraw Hill, London.

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