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The genus Cinnamomum

The genus Cinnamomum

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112 U.M. Senanayake and R.O.B. Wijesekera<br />

Yazaki and Okude (1990) reported that callus and suspensions cultures of C. cassia<br />

produced large amount of condenced tannin. <strong>The</strong>y have isolated (–)-epicatechin and<br />

procyanidins B2, B4 and C1, which are precursors of condensed tannins, from callus<br />

cultures.<br />

Cinnamon bark contains a significant amount of mucilaginous substances, which consists<br />

mainly of a water-extractable L-arabino-D-xylan and an alkali extractable D-glucan.<br />

Gowda and Sarathy (1987) studied the nature of the arbinoxylan from cinnamon bark.<br />

<strong>The</strong> arabinoxylan is composed of L-arabinose and D-xylose in the molar ratio 1.6:1.0. It<br />

contained a (1 : 4)-linked -D-xylan backbone in which each D-xylopyranosyl residue<br />

is substituted at both 0–2 and 0–3 with L-arabinofuranosyl, 3–0--D-xylopyranosyl-Larabinofuranosyl<br />

and 3–0-L-arabinofuranosyl-arabinofuranosyl-L-arabinofuranosyl<br />

groups.<br />

References<br />

Craig, J.C. and Roy, S.K. (1965) Tetrahedron, 21, 401 (cited from Gellert and Summons 1970).<br />

Gellert, E. and Summons, R.E. (1970) Alkaloids of the <strong>genus</strong> <strong>Cinnamomum</strong>. II. <strong>The</strong> alkaloids of<br />

the bark of <strong>Cinnamomum</strong> sp. Aust. J. Chem., 23, 2095–2099.<br />

Gowda, C. and Sarathy, C. (1987) Structure of an L-arabino-D-xylan from the bark of<br />

<strong>Cinnamomum</strong> zeylanicum. Carbohydrate Res., 166, 263–269.<br />

Isogai, A., Suzuki, A., Tamura, S., Murakoshi, S., Ohashi, Y. and Sasada, Y. (1976) Structure of<br />

cinnzeylanine and cinnzeylanol, polyhydroxylated pentacyclic diterpenes from <strong>Cinnamomum</strong><br />

zeylanicum Nees. Agr. Biol. Chem., 40, 2305–2306.<br />

Isogai, A., Suzuki, A. and Tamura, S. (1977) Cinnzeylanine, a new pentacyclic diterpene acetate<br />

from <strong>Cinnamomum</strong> zeylanicum. Acta Cryst., B33, 623–626.<br />

Isogai, A., Murakoshi, S., Suzuki, A. and Tamura, S. (1979) Chemistry and biological activities<br />

of cinnzeylanine and cinnzeylanol, new insecticidal substances from <strong>Cinnamomum</strong> zeylanicum<br />

Nees. Agric. Biol. Chem., 41, 1779–1784.<br />

Morimoto, S., Nonaka, G.-I., Nishioka, I., Ezaki, N. and Takazawa, N. (1985a) Chem. Pharm.<br />

Bull., 33, 2281 (cited from Morimoto, 1986a).<br />

Morimoto, S., Nonaka, G.-I., Nishioka, I., Ezaki, N. and Takazawa, N. (1985b). Tannins<br />

and related compounds xxix. Seven new methyl derivatives of flavan-3-ols and 1,3-diaryl<br />

propan-2-ol from <strong>Cinnamomum</strong> cassia, C. obtusifolium and Lindera umbellata var. membranacea.<br />

Chem. Pharm. Bull., 33, 2281–2286.<br />

Morimoto, S., Nonaka, G.-I. and Nishioka, I. (1986a) Tannins and related compounds XXXVI-<br />

II. Isolation and characterization of flavan-3-ol glucosides and procyanidin oligomers from<br />

cassia bark (<strong>Cinnamomum</strong> cassia Blume). Chem. Pharm. Bull., 34, 633–642.<br />

Morimoto, S., Nonaka, G.-I. and Nishioka, I. (1986b) Tannins and related compounds.<br />

XXXIX. Procyanidin c-glucosides and an acylated flavan-3-ol glucoside from barks of<br />

<strong>Cinnamomum</strong> cassia Blume and C. obtusifolium Nees. Chem. Pharam. Bull., 34, 643–649.<br />

Nohara, T., Tokubuchi, N., Kuroiwa, M. and Nishioka, I. (1980a). <strong>The</strong> constituents of<br />

Cinnamomi cortex. III. Structures of cinncassiol B and its glucoside. Chem. Pharm. Bull., 28,<br />

2682–2686.<br />

Nohara, T., Nishioka, I., Tokubuchi, N., Miyahara, K. and Kawasaki, T. (1980b) <strong>The</strong> constituents<br />

of cinnamomi cortex. II Cinncassiol C. a novel type of diterpene from Cinnamomi cortex. Chem.<br />

Pharma. Bull., 28, 1969–1970.<br />

Nohara, T., Kashiwada, Y., Yomimatsu, T., Kido, C., Tokobuchi, M. and Nishioka, N. (1980c)<br />

Cinncassiol D1 and its glucoside, novel pentacyclic diterpenes from cinnamomi cortex.<br />

Tetrehedron Lett., 21, 2647–2648.<br />

Nohara, T., Kashiwada, Y., Murukami, T., Tomimatsu, T., Kido, M. and Yagi, A. (1981)<br />

Constitution of cinnamomi cortex. V. Structure of five novel diterpenes, cinncassiols D1, D1 glucoside, D2, D2 glucoside and D3. Chem. Pharma. Bull., 29, 2451–2459.

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