preface to fifteenth edition

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PRACTICAL LABORATORY INFORMATION 11.65 TABLE 11.19 Gravimetric Factors (Continued) Factor Factor THALLIUM Tl 204.37 0.87198 Tl 4 Tl 2 CO 3 1.1468 0.85218 Tl 4 TlCl 1.1735 0.61693 Tl 4 Tll 1.6209 0.76724 Tl 4 TlNO 3 1.3034 0.96232 Tl 4 Tl 2 O 1.0391 1.2838 Tl 2 CrO 4 4 Tl 0.77895 1.4750 TlHSO 4 4 Tl 0.67798 1.9977 Tl 2 PtCl 6 4 Tl 0.50057 1.7024 Tl 2 PtCl 6 4 TlCl 0.58740 1.7420 Tl 2 PtCl 6 4 Tl 2 CO 3 0.57406 1.2325 Tl 2 PtCl 6 4 TlI 0.81139 1.5327 Tl 2 PtCl 6 4 TlNO 3 0.65243 1.9225 Tl 2 PtCl 6 4 Tl 2 O 0.52017 1.6176 Tl 2 PtCl 6 4 Tl 2 SO 4 0.61821 1.2350 Tl 2 SO 4 4 Tl 0.80971 THORIUM Th 232.038 1.1379 ThO 2 4 Th 0.87881 0.70627 ThO 2 4 ThCl 4 1.4159 0.44893 ThO 2 4 Th(NO 3 ) 4·6H 2 O 2.2275 TIN Sn 118.69 0.62600 Sn 4 SnCl 2 1.5974 0.52604 Sn 4 SnCl 2·2H 2 O 1.9010 0.45562 Sn 4 SnCl 4 2.1948 0.32297 Sn 4 SnCl 4·(NH 4 Cl) 2 3.0962 0.88121 Sn 4 SnO 1.1348 0.78764 Sn 4 SnO 2 1.2696 0.79478 SnO 2 4 SnCl 2 1.2582 0.66786 SnO 2 4 SnCl 2·2H 2 O 1.4973 0.57846 SnO 2 4 SnCl 4 1.7287 0.41005 SnO 2 4 SnCl 4·(NH 4 Cl) 2 2.4387 1.1188 SnO 2 4 SnO 0.89382 TITANIUM Ti 47.867 2.1059 K 2 TiF 6 4 F 0.47485 3.0699 K 2 TiF 6 4 K 0.32574 2.0660 K 2 TiF 6 4 2KF 0.48403 1.2752 K 2 TiF 6 4 2(KF·2H 2 O) 0.78421 5.0150 K 2 TiF 6 4 Ti 0.19940 3.0057 K 2 TiF 6 4 TiO 2 0.33270 3.9853 Ti 4 C 0.25092 4.9853 TiC 4 C 0.20059 1.2509 TiC 4 Ti 0.79940 1.6299 TiF 4 4 F 0.61354 1.6685 TiO 2 4 Ti 0.59934
11.66 SECTION 11 TABLE 11.19 Gravimetric Factors (Continued) Factor Factor TUNGSTEN W 183.85 3.9348 FeWO 4 4 Fe 3 O 4 0.25414 1.3099 FeWO 4 4 WO 3 0.76344 6.7515 MgWO 4 4 MgO 0.14812 1.1739 MgWO 4 4 WO 3 0.85189 4.2684 MnWO 4 4 MnO 0.23428 1.3060 MnWO 4 4 WO 3 0.76571 2.0387 PbWO 4 4 PbO 0.49051 2.4751 PbWO 4 4 W 0.40403 1.9626 PbWO 4 4 WO 3 0.50952 15.307 W 4 C 0.065330 0.96837 W 4 W 2 C 1.0327 0.93868 W 4 WC 1.0653 31.614 W 2 C 4 C 0.031632 16.307 WC 4 C 0.061324 1.1741 WO 2 4 W 0.85175 4.1515 WO 3 4 Fe 0.24088 1.2611 WO 3 4 W 0.79297 URANIUM U 238.03 1.1344 UO 2 4 U 0.88149 1.1792 U 3 O 8 4 U 0.84800 1.0395 U 3 O 8 4 UO 2 0.96200 0.55901 U 3 O 8 4 UO 2 (NO 3 ) 2·6H 2 O 1.7889 1.4998 U 2 P 2 O 11 4 U 0.66675 1.3221 U 2 P 2 O 11 4 UO 2 0.75639 VANADIUM V 50.941 5.2413 VC 4 C 0.19079 1.7852 V 2 O 5 4 V 0.56017 0.79120 V 2 O 5 4 VO 4 1.2639 YTTERBIUM Yb 173.04 1.1387 Yb 2 O 3 4 Yb 0.87820 ZINC Zn 65.38 2.3955 BaSO 4 4 ZnS 0.41745 0.81171 BaSO 4 4 ZnSO 4·7H 2 O 1.2320 0.80338 Zn 4 ZnO 1.2447 2.7288 ZnNH 4 PO 4 4 Zn 0.36646 2.1922 ZnNH 4 PO 4 4 ZnO 0.45616 0.59707 ZnO 4 ZnCl 2 1.6748 0.64898 ZnO 4 ZnCO 3 1.5409 0.28298 ZnO 4 ZnSO 4·7H 2 O 3.5338 2.3304 Zn 2 P 2 O 7 4 Zn 0.42911 1.8722 Zn 2 P 2 O 7 4 ZnO 0.53413 1.4905 ZnS 4 Zn 0.67091 1.1974 ZnS 4 ZnO 0.83512 0.33885 ZnS 4 ZnSO 4·7H 2 O 2.9511
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LANGE'S HANDBOOK OF CHEMISTRY John
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Grateful acknowledgment is hereby m
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PREFACE TO FIFTEENTH EDITION This n
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PREFACE TO FIFTEENTH EDITION ix inv
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xii PREFACE TO FOURTEENTH EDITION l
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PREFACE TO FIRST EDITION This book
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For the detailed contents of any se
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1.2 SECTION 1 is derived from the G
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1.4 SECTION 1 rather than methylide
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1.6 SECTION 1 Styrene Toluene Xylen
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1.8 SECTION 1 TABLE 1.2 Fused Polyc
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1.10 SECTION 1 1.1.1.6 Bridged Hydr
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1.12 SECTION 1 TABLE 1.4 Suffixes f
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1.14 SECTION 1 TABLE 1.5 Trivial Na
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1.16 SECTION 1 TABLE 1.6 Trivial Na
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1.18 SECTION 1 Selection of the pri
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1.20 SECTION 1 attached to one anot
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1.22 SECTION 1 When side chains of
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1.24 SECTION 1 heterocyclic structu
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1.26 SECTION 1 Bivalent radicals of
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1.28 SECTION 1 Complex linear polya
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1.30 SECTION 1 TABLE 1.11 Names of
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1.32 SECTION 1 hydroxyamino- to the
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1.34 SECTION 1 may be named (1) by
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1.36 SECTION 1 Examples are methyl
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1.38 SECTION 1 tuted acid, respecti
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1.40 SECTION 1 FIGURE 1.2 Newman pr
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1.42 SECTION 1 from the ring are kn
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1.44 SECTION 1 FIGURE 1.11 Two isom
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1.46 SECTION 1 Chiral Center. The c
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1.48 SECTION 1 FIGURE 1.15 Isomers
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1.50 SECTION 1 entries to bring tog
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1.52 SECTION 1 TABLE 1.13 Names and
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1.60 SECTION 1 TABLE 1.14 Empirical
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2.2 SECTION 2 2.3.6 Student’s Dis
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2.4 SECTION 2 TABLE 2.1 Fundamental
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2.6 SECTION 2 TABLE 2.1 Fundamental
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2.8 SECTION 2 TABLE 2.2 Physical an
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2.10 SECTION 2 TABLE 2.2 Physical a
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2.24 SECTION 2 TABLE 2.3 Mathematic
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2.26 SECTION 2 TABLE 2.6 Abbreviati
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2.36 SECTION 2 TABLE 2.7 Conversion
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2.54 SECTION 2 TABLE 2.8 Temperatur
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2.66 SECTION 2 2.1.1 Conversion of
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2.68 SECTION 2 Oleometer. A hydrome
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2.70 SECTION 2 Example 3. 25 1.2500
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2.72 SECTION 2 TABLE 2.9 Barometer
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2.74 SECTION 2 TABLE 2.9 Barometer
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2.76 SECTION 2 TABLE 2.10 Barometri
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2.78 SECTION 2 TABLE 2.12 Reduction
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2.80 SECTION 2 TABLE 2.12 Reduction
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2.82 SECTION 2 TABLE 2.13 Viscosity
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2.84 SECTION 2 TABLE 2.14 Conversio
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2.86 SECTION 2 TABLE 2.15 Hydromete
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2.88 SECTION 2 TABLE 2.17 Correctio
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2.90 SECTION 2 TABLE 2.18 Pressure
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2.96 SECTION 2 TABLE 2.20 Values of
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2.98 SECTION 2 TABLE 2.21 Transmitt
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2.100 SECTION 2 TABLE 2.21 Transmit
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2.102 SECTION 2 2.2 MATHEMATICAL TA
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2.104 SECTION 2 TABLE 2.23 Derivati
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2.106 SECTION 2 TABLE 2.24 Integral
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2.108 SECTION 2 TABLE 2.24 Integral
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2.110 SECTION 2 Regular Polygon of
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2.112 SECTION 2 A h[0.4(y y ) 1.
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2.114 SECTION 2 2.2.3.1 Signs of th
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2.116 SECTION 2 x2 x3 x4 x5 ln(1 x
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2.118 SECTION 2 2.3.2 Errors in Qua
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2.120 SECTION 2 The breadth or spre
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2.122 SECTION 2 TABLE 2.26b Areas U
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2.124 SECTION 2 The distribution of
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2.126 SECTION 2 Should there be mor
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2.128 SECTION 2 Example 10 Six samp
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2.130 SECTION 2 2.3.9 The F Statist
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TABLE 2.29 F Distribution (Continue
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2.134 SECTION 2 mathematical treatm
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2.136 SECTION 2 The confidence limi
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2.138 SECTION 2 situation where rel
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3.2 SECTION 3 The alphabetical orde
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3.4 SECTION 3 When it is required t
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3.6 SECTION 3 PO phosphoryl SeO sel
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3.8 SECTION 3 3.1.5 Acids 3.1.5.1 A
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3.10 SECTION 3 3.1.6.6 Multiplicati
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3.12 SECTION 3 3.2 PHYSICAL PROPERT
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TABLE 3.2 Physical Constants of Ino
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3.62 SECTION 3 TABLE 3.3 Synonyms a
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SECTION 4 PROPERTIES OF ATOMS, RADI
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4.3 Fermium Fm 100 [Rn] 5f 12 7s 2
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Silver (argentum) Ag 47 [Kr] 4d 10
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PROPERTIES OF ATOMS,RADICALS,AND BO
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PROPERTIES OF ATOMS, RADICALS, AND
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SECTION 5 PHYSICAL PROPERTIES 5.1 S
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PHYSICAL PROPERTIES 5.3 5.1 SOLUBIL
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TABLE 5.1 Solubility of Gases in Wa
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TABLE 5.1 Solubility of Gases in Wa
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TABLE 5.2 Solubilities of Inorganic
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formateBa(CHO 2 ) 2 26.2 28.0 29.9
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(III) sulfateCe 2 (SO 4 ) 3 ·9H 2
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iodidePbI 2 0.044 0.056 0.069 0.090
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Nickel sulfateNiSO 4 ·6H 2 O (pale
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Praseodymium bromatePr(BrO 3 ) 3 55
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formate NaCHO 2 43.9 62.5 81.2 102
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Uranyl nitrate UO 2 (NO 3 ) 2 98 10
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PHYSICAL PROPERTIES 5.25 TABLE 5.3
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PHYSICAL PROPERTIES 5.57 5.3 BOILIN
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TABLE 5.12 Ternary Azeotropic Mixtu
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TABLE 5.12 Ternary Azeotropic Mixtu
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PHYSICAL PROPERTIES 5.83 5.4 FREEZI
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PHYSICAL PROPERTIES 5.87 5.5 DENSIT
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PHYSICAL PROPERTIES 5.89 dt Dt P
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PHYSICAL PROPERTIES 5.135 5.6.1 Ref
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PHYSICAL PROPERTIES 5.137 where the
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PHYSICAL PROPERTIES 5.139 5.7 COMBU
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Temperature, C Substance 40 20 0 20
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PHYSICAL PROPERTIES 5.171 This equa
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SECTION 6 THERMODYNAMIC PROPERTIES
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THERMODYNAMICPROPERTIES 6.3 6.1.1.2
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THERMODYNAMICPROPERTIES 6.5 A gener
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THERMODYNAMICPROPERTIES 6.7 TABLE 6
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THERMODYNAMICPROPERTIES 6.9 TABLE 6
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THERMODYNAMICPROPERTIES 6.11 TABLE
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THERMODYNAMIC PROPERTIES 6.21 TABLE
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THERMODYNAMIC PROPERTIES 6.101 TABL
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THERMODYNAMIC PROPERTIES 6.143 The
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SECTION 7 SPECTROSCOPY 7.1 X-RAY ME
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SPECTROSCOPY 7.3 TABLE 7.1 Waveleng
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SPECTROSCOPY 7.9 TABLE 7.3 Critical
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SPECTROSCOPY 7.11 TABLE 7.4 X-Ray E
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SPECTROSCOPY 7.13 Emission line K 1
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SPECTROSCOPY 7.15 TABLE 7.7 Analyzi
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SPECTROSCOPY 7.17 TABLE 7.8 Mass Ab
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SPECTROSCOPY 7.19 TABLE 7.9 Electro
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SPECTROSCOPY 7.21 TABLE 7.11 Absorp
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SPECTROSCOPY 7.23 TABLE 7.13 Solven
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SPECTROSCOPY 7.25 7.3 FLUORESCENCE
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SPECTROSCOPY 7.27 TABLE 7.16 Fluore
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SPECTROSCOPY 7.29 TABLE 7.18 Detect
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SPECTROSCOPY 7.35 TABLE 7.19 Sensit
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SPECTROSCOPY 7.37 TABLE 7.19 Sensit
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SPECTROSCOPY 7.39 In terms of m ,
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SPECTROSCOPY 7.41 The ionization co
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SPECTROSCOPY 7.67 TABLE 7.28 Infrar
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7.69
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SPECTROSCOPY 7.71 7.6 RAMAN SPECTRO
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SPECTROSCOPY 7.73 TABLE 7.30 Raman
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SPECTROSCOPY 7.89 7.7 NUCLEAR MAGNE
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SPECTROSCOPY 7.91 TABLE 7.41 Nuclea
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SPECTROSCOPY 7.93 TABLE 7.42 Proton
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SPECTROSCOPY 7.95 TABLE 7.44 Estima
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SPECTROSCOPY 7.97 TABLE 7.46 Proton
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SPECTROSCOPY 7.99 TABLE 7.48 Solven
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SPECTROSCOPY 7.101 TABLE 7.49 Carbo
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SPECTROSCOPY 7.103 TABLE 7.51 Effec
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SPECTROSCOPY 7.107 TABLE 7.56 One-B
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SPECTROSCOPY 7.113 TABLE 7.63 Nitro
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SPECTROSCOPY 7.115 TABLE 7.64 Nitro
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SPECTROSCOPY 7.117 TABLE 7.69 Fluor
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SPECTROSCOPY 7.119 TABLE 7.72 Silic
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SPECTROSCOPY 7.121 TABLE 7.73 Phosp
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SPECTROSCOPY 7.123 TABLE 7.74 Phosp
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SPECTROSCOPY 7.125 when z 3 and y
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SPECTROSCOPY 7.127 Masses 19 and 31
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SPECTROSCOPY 7.129 TABLE 7.76 Conde
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SECTION 8 ELECTROLYTES, ELECTROMOTI
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ELECTROLYTES, EMF, AND CHEMICAL EQU
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TABLE 8.7 Proton Transfer Reactions
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TABLE 8.7 Proton Transfer Reactions
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TABLE 8.9 Selected Equilibrium Cons
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8.75 3-tert-Butylbenzoic acid (0) 4
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4-Hydroxyproline (1) 1.900 1C 1.850
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N-Propionylglycine (1) 3.728 3.723
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TABLE 8.14 National Bureau of Stand
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1 part 0.1% neutral red in alc. * V
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3,3-Dimethoxybenzidine dihydrochlor
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TABLE 8.35 Equivalent Conductivitie
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KCl 127.3 124.4 122.4 115.8 112.0 1
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NaIO 3 75.2 72.6 70.9 64.4 60.5 1
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9.2 SECTION 9 9.1 LINEAR FREE ENERG
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9.4 SECTION 9 TABLE 9.1 Hammett and
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9.6 SECTION 9 TABLE 9.1 Hammett and
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9.8 SECTION 9 TABLE 9.3 pK a and Rh
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10.2 SECTION 10 10.4.6 Polyacrylate
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10.4 SECTION 10 10.2 ADDITIVES TO P
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10.6 SECTION 10 injection molding.
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10.8 SECTION 10 10.3 FORMULAS AND K
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10.10 SECTION 10 Key properties of
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10.12 SECTION 10 10.3.8 Fluorocarbo
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10.14 SECTION 10 10.3.11 Phenolics
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10.16 SECTION 10 The resin has the
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10.18 SECTION 10 10.3.19 Polyuretha
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10.20 SECTION 10 10.3.22 Sulfones B
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TABLE 10.2 Properties of Commercial
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Page 1076 and 1077:
10.58 SECTION 10 10.4 FORMULAS AND
Page 1078 and 1079:
10.60 SECTION 10 10.4.8 Polychlorop
Page 1080 and 1081:
10.62 SECTION 10 Styrene-butadiene
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10.5 CHEMICAL RESISTANCE TABLE 10.4
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10.6 GAS PERMEABILITY TABLE 10.5 Ga
Page 1086 and 1087:
TABLE 10.5 Gas Permeability Constan
Page 1088 and 1089:
TABLE 10.7 Constants ofFats and Oil
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TABLE 10.8 Constants ofWaxes Wax Me
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SECTION 11 PRACTICAL LABORATORY INF
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11.4 SECTION 11 TABLE 11.2 Molecula
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11.6 SECTION 11 A saturated aqueous
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11.8 SECTION 11 TABLE 11.6 Relative
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11.10 SECTION 11 11.3 BOILING POINT
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11.12 SECTION 11 TABLE 11.8 Organic
Page 1105 and 1106: 11.14 SECTION 11 TABLE 11.9 Molecul
Page 1107 and 1108: 11.4 SEPARATION METHODS TABLE 11.11
Page 1109 and 1110: 11.18 SECTION 11 TABLE 11.12 Solven
Page 1111 and 1112: 11.20 SECTION 11 TABLE 11.12 Solven
Page 1113 and 1114: TABLE 11.13 McReynolds’ Constants
Page 1115 and 1116: TABLE 11.13 McReynolds’ Constants
Page 1117 and 1118: 11.26 SECTION 11 11.4.1 McReynolds
Page 1119 and 1120: 11.28 SECTION 11 11.4.2.2 Partition
Page 1121 and 1122: 11.30 SECTION 11 FIGURE 11.2 Band a
Page 1123 and 1124: 11.32 SECTION 11 11.4.3 Ion-Exchang
Page 1125 and 1126: 11.34 SECTION 11 TABLE 11.16 Guide
Page 1127 and 1128: 11.36 SECTION 11 TABLE 11.16 Guide
Page 1129 and 1130: 11.38 SECTION 11 TABLE 11.18 Relati
Page 1131 and 1132: 11.40 SECTION 11 distribution coeff
Page 1133 and 1134: 11.42 SECTION 11 TABLE 11.19 Gravim
Page 1155: 11.64 SECTION 11 TABLE 11.19 Gravim
Page 1159 and 1160: 11.68 SECTION 11 TABLE 11.20 Elemen
Page 1161 and 1162: 11.70 SECTION 11 TABLE 11.22 Common
Page 1163 and 1164: 11.72 SECTION 11 TABLE 11.25 Tolera
Page 1165 and 1166: 11.74 SECTION 11 TABLE 11.26 Heatin
Page 1167 and 1168: 11.76 SECTION 11 TABLE 11.28 Titrim
Page 1175 and 1176: 11.84 SECTION 11 appears becomes le
Page 1177 and 1178: 11.86 SECTION 11 TABLE 11.29 Equati
Page 1179 and 1180: 11.88 SECTION 11 TABLE 11.29 Equati
Page 1181 and 1182: 11.90 SECTION 11 The more stable th
Page 1183 and 1184: 11.92 SECTION 11 11.6.6.2.5 Buffer
Page 1185 and 1186: 11.94 SECTION 11 TABLE 11.30 Standa
Page 1187 and 1188: TABLE 11.32 Properties and Applicat
Page 1189 and 1190: 11.98 SECTION 11 TABLE 11.36 Maskin
Page 1191 and 1192: 11.100 SECTION 11 TABLE 11.37 Anion
Page 1193 and 1194: 11.102 SECTION 11 TABLE 11.39 Amino
Page 1195 and 1196: 11.104 SECTION 11 TABLE 11.44 Facto
Page 1197 and 1198: 11.106 SECTION 11 11.7 LABORATORY S
Page 1199 and 1200: 11.108 SECTION 11 TABLE 11.48 Stand
Page 1201 and 1202: 11.110 SECTION 11 Alizarin yellow G
Page 1203 and 1204: 11.112 SECTION 11 Bromchlorophenol
Page 1205 and 1206: 11.114 SECTION 11 p-Ethoxychrysoidi
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11.116 SECTION 11 Mercurous nitrate
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11.118 SECTION 11 Potassium carbona
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11.120 SECTION 11 until the ammoniu
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11.122 SECTION 11 TABLE 11.49 TLV C
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Page 1221 and 1222:
11.130 SECTION 11 TABLE 11.50 Chemi
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Page 1229 and 1230:
11.138 SECTION 11 of water which is
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TABLE 11.55 Thermoelectric Values i
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TABLE 11.56 Type B Thermocouples: P
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TABLE 11.58 Type J Thermocouples: I
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TABLE 11.60 Type N Thermocouples: N
Page 1239 and 1240:
TABLE 11.62 Type S Thermocouples: P
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11.150 SECTION 11 11.11 CORRECTION
Page 1243 and 1244:
Index Terms Links 2 Acid-base indic
Page 1245 and 1246:
Index Terms Links 4 Alkynes, nomenc
Page 1247 and 1248:
Index Terms Links 6 Aurintricarboxy
Page 1249 and 1250:
Index Terms Links 8 Boron-11 chemic
Page 1251 and 1252:
Index Terms Links 10 Cellulose acet
Page 1253 and 1254:
Index Terms Links 12 Collective ino
Page 1255 and 1256:
Index Terms Links 14 Degree Fahrenh
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Index Terms Links 16 Electrical res
Page 1259 and 1260:
Index Terms Links 18 Equivalent wei
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Index Terms Links 20 Fluorocarbon p
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Index Terms Links 22 Halogenated hy
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Index Terms Links 24 Impact strengt
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Index Terms Links 26 Kα 1 lines, m
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Index Terms Links 28 Melmine phenol
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Index Terms Links 30 Neon-neon bond
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Index Terms Links 32 One-tailed tes
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Index Terms Links 34 Physical chemi
Page 1277 and 1278:
Index Terms Links 36 Polyolefin the
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Index Terms Links 38 Pyridine: bina
Page 1281 and 1282:
Index Terms Links 40 Rho values: fo
Page 1283 and 1284:
Index Terms Links 42 Single-bond ra
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Index Terms Links 44 Stereoisomers
Page 1287 and 1288:
Index Terms Links 46 Tension, aqueo
Page 1289 and 1290:
Index Terms Links 48 Triethylenetet
Page 1291 and 1292:
Index Terms Links 50 Water (Cont.)
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