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TABLE 3.2 Physical Constants of Inorganic Compounds (Continued) Name Formula Formula weight Density Melting point, C Boiling point, C Solubility in 100 parts solvent 3.52 Sodium (continued) perchlorate NaClO 4 122.44 2.52 480 d g/100 mL 25 ; 114 aq, 1.5 BuOH, 8.4 EtOAc periodate KIO 4 213.89 3.865 d 300 10.3 g/100 mL 20 aq peroxide Na 2 O 2 77.98 2.805 675 d v s aq (dec) peroxoborate 4-water NaBO 3 ·4H 2 O 153.88 d 60 2.5 g/100 mL aq peroxodisulfate(VI) Na 2 S 2 O 8 238.11 d 55 g/100 mL aq; d by alc perrhenate NaReO 4 273.19 5.24 300 33 g/100 mL 20 aq phosphate Na 3 PO 4 163.94 2.537 1340 12.1 g/100 mL 20 aq phosphate 12-water Na 3 PO 4 · 12H 2 O 380.12 1.62 73.4 11H 2 O, 100 28.3 g/100 mL 20 aq; i alc phosphinate hydrate NaPH 2 O 2 ·H 2 O 105.99 anhyd 200 d to PH 3 100 g/100 mL 20 aq; s glyc, alc propanoate NaOOCC 2 H 5 96.06 g/100 mL 25 : 100 aq, 4.1 alc salicylate NaOOCC 6 H 4 OH 160.10 g/100 mL: 110 20 aq, 11 alc, 25 glyc selenate(VI) Na 2 SeO 4 188.94 3.098 27 g/100 mL 20 aq silicate(2) meta- Na 2 SiO 3 122.06 2.614 1089 s aq; hyd by hot aq; i alc silicate(2) 5-water Na 2 SiO 3 ·5H 2 O 212.14 1.749 72.2 anhyd 100 v s aq silicate(4) Na 4 SiO 4 184.04 1018 s aq stannate(IV) 3-water Na 2 SnO 3 ·3H 2 O 266.71 d 140 (slow) 59 g/100 mL 20 aq; i alc stearate NaOOCC 17 H 35 306.47 d sl s aq sulfate Na 2 SO 4 142.04 2.7 8800 d 2227 28 g/100 mL 20 aq sulfate 10-water Na 2 SO 4 · 10H 2 O 322.20 1.46 32.4 anhyd 100 67 g/100 mL 25 aq; s glyc; i alc sulfide Na 2 S78.05 1.856 1172 vacuo 18.6 g/100 mL 20 aq; sl s alc sulfide 9-water Na 2 S·9H 2 O 240.18 1.43 d 50 200 g/100 mL aq; sl s alc sulfite Na 2 SO 3 126.04 2.63 d 31 g/100 mL 20 aq; s glyc; i alc tartrate dihydrate Na 2 C 4 H 4 O 6 ·2H 2 O 230.08 1.82 anhyd 120 29 g/100 mL 6 aq; i alc tetraborate Na 2 B 4 O 7 201.22 2.4 742.5 2.6 20 aq tetraborate 10-water (borax) Na 2 B 4 O 7 · 10H 2 O 381.37 1.73 75 d anhyd 320 g/100 mL: 6.3 aq, 100 glyc tetrachloroaluminate Na[AlCl 4 ] 191.78 2.01 151 s aq tetrachloroaurate Na[AuCl 4 ]·2H 2 O 397.80 d 100 166 g/100 mL 27 aq; s alc, chl tetrafluoroborate Na[BF 4 ] 109.82 2.47 384 d 108 g/100 mL 27 aq tetrahydridoborate Na[BH 4 ] 37.83 1.074 497 d 315 18 25 DMF; 16.4 20 MeOH (reacts)
3.53 thiocyanate NaSCN 81.07 287 134 g/100 mL 20 aq thiosulfate Na 2 S 2 O 3 158.11 2.345 s aq; i alc thiosulfate 5-water Na 2 S 2 O 3 ·5H 2 O 248.19 1.69 anhyd 100 d 100 70 g/100 mL 20 aq (dec slowly) trimetaphosphate 6-water (NaPO 3 ) 3 ·6H 2 O 414.04 1.786 53 anhyd 100 22 g/100 mL aq; i alc tungstate(VI) dihydrate Na 2 WO 4 ·2H 2 O 329.85 3.25 anhyd 100 mp: 695.6 88 g/100 mL 0 aq; i alc vanadate(V) NaVO 3 121.93 s hot aq Strontium Sr 87.62 2.64 757 1366 d to Sr(OH) 2 in water bromide SrBr 2 247.43 4.216 657 2045 100 g/100 mL 20 aq carbonate SrCO 3 147.63 3.5 d 1100 to SrO i aq; s acids CO 2 chlorate Sr(ClO 3 ) 2 254.52 3.152 120 d : O 2 167 g/100 mL 20 aq chloride SrCl 2 158.53 3.052 874 1250 52.9 g/100 mL 20 aq chromate(VI) SrCrO 4 203.61 3.89 d 0.12 20 aq; s HCl fluoride SrF 2 125.62 4.24 1477 2460 0.011 20 aq; s hot HCl hydrogen phosphate SrHPO 4 183.60 3.544 i aq; s acids hydroxide Sr(OH) 2 121.64 3.625 535 H 2 O, 744 0.8 20 aq iodate Sr(IO 2 ) 2 437.43 5.045 15 0.03 15 aq iodide SrI 2 341.43 4.42 402 1773 d 178 g/100 mL 20 aq; s alc lactate 3-water Sr(OOCCHOHCH 3 ) 2 ·3H 2 O 319.81 anhyd 150 33 g/100 mL aq nitrate Sr(NO 3 ) 2 211.63 2.99 570 645 69.5 g/100 mL 20 aq; sl s alc, acet oxide SrO 103.62 4.7 2430 0.69 20 aq perchlorate Sr(ClO 4 ) 2 286.52 3.00 25 g/100 mL 25 : 157 aq, 71 BuOH, 77 EtOAc, 90 acet peroxide SrO 2 119.62 4.78 215 d 0.018 20 aq; d hot aq sulfate SrSO 4 183.68 3.96 1607 0.013 20 aq; sl s acid sulfide SrS 119.69 3.70 2227 sl s aq; s acid (dec) Sulfinyl bromide (Thionyl) SOBr 2 207.87 2.68820 4 52 140 hyd aq (slow); misc bz, chl, CCl 4 chloride SOCl 2 118.97 1.638 104.5 76 hyd aq; misc bz, chl, CCl 4 fluoride SOF 2 86.06 3.776 g/L 129.5 43.8 hyd aq; s bz, chl, eth Sulfonyl chloride (Sulfuryl) SO 2 Cl 2 134.97 1.667420 4 54.1 69.3 hyd aq; misc bz, eth, HOAc diamide SO 2 (NH 2 ) 2 96.11 1.807 93 d 250 s aq, hot EtOH, acet fluoride SO 2 F 2 102.06 4.478 g/L 135.8 55.38 mL gas/100 mL: 4 aq, 24 alc, 136 CCl 4 , 210 toluene Sulfur (gamma) S 32.066 1.92 106.8 444.72 23 g/100 mL 0 CS 2 ; s alc, bz (alpha) orthorhombic S 8 256.53 2.08 20 tr 94.5 to beta 444.6 i aq; s organic solvents (beta) monoclinic tr slowly to rhombic form S 8 256.53 1.96 115.21 444.6 23 g/100 mL 0 CS; s alc, bz
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LANGE'S HANDBOOK OF CHEMISTRY John
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Grateful acknowledgment is hereby m
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PREFACE TO FIFTEENTH EDITION This n
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PREFACE TO FIFTEENTH EDITION ix inv
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xii PREFACE TO FOURTEENTH EDITION l
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PREFACE TO FIRST EDITION This book
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For the detailed contents of any se
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1.2 SECTION 1 is derived from the G
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1.4 SECTION 1 rather than methylide
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1.6 SECTION 1 Styrene Toluene Xylen
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1.8 SECTION 1 TABLE 1.2 Fused Polyc
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1.10 SECTION 1 1.1.1.6 Bridged Hydr
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1.12 SECTION 1 TABLE 1.4 Suffixes f
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1.14 SECTION 1 TABLE 1.5 Trivial Na
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1.16 SECTION 1 TABLE 1.6 Trivial Na
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1.18 SECTION 1 Selection of the pri
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1.20 SECTION 1 attached to one anot
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1.22 SECTION 1 When side chains of
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1.24 SECTION 1 heterocyclic structu
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1.26 SECTION 1 Bivalent radicals of
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1.28 SECTION 1 Complex linear polya
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1.30 SECTION 1 TABLE 1.11 Names of
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1.32 SECTION 1 hydroxyamino- to the
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1.34 SECTION 1 may be named (1) by
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1.36 SECTION 1 Examples are methyl
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1.38 SECTION 1 tuted acid, respecti
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1.40 SECTION 1 FIGURE 1.2 Newman pr
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1.42 SECTION 1 from the ring are kn
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1.44 SECTION 1 FIGURE 1.11 Two isom
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1.46 SECTION 1 Chiral Center. The c
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1.48 SECTION 1 FIGURE 1.15 Isomers
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1.50 SECTION 1 entries to bring tog
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1.52 SECTION 1 TABLE 1.13 Names and
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1.60 SECTION 1 TABLE 1.14 Empirical
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2.2 SECTION 2 2.3.6 Student’s Dis
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2.4 SECTION 2 TABLE 2.1 Fundamental
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2.6 SECTION 2 TABLE 2.1 Fundamental
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2.8 SECTION 2 TABLE 2.2 Physical an
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2.10 SECTION 2 TABLE 2.2 Physical a
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2.24 SECTION 2 TABLE 2.3 Mathematic
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2.26 SECTION 2 TABLE 2.6 Abbreviati
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2.36 SECTION 2 TABLE 2.7 Conversion
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2.54 SECTION 2 TABLE 2.8 Temperatur
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2.66 SECTION 2 2.1.1 Conversion of
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2.68 SECTION 2 Oleometer. A hydrome
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2.70 SECTION 2 Example 3. 25 1.2500
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2.72 SECTION 2 TABLE 2.9 Barometer
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2.74 SECTION 2 TABLE 2.9 Barometer
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2.76 SECTION 2 TABLE 2.10 Barometri
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2.78 SECTION 2 TABLE 2.12 Reduction
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2.80 SECTION 2 TABLE 2.12 Reduction
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2.82 SECTION 2 TABLE 2.13 Viscosity
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2.84 SECTION 2 TABLE 2.14 Conversio
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2.86 SECTION 2 TABLE 2.15 Hydromete
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2.88 SECTION 2 TABLE 2.17 Correctio
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2.90 SECTION 2 TABLE 2.18 Pressure
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2.96 SECTION 2 TABLE 2.20 Values of
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2.98 SECTION 2 TABLE 2.21 Transmitt
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2.100 SECTION 2 TABLE 2.21 Transmit
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2.102 SECTION 2 2.2 MATHEMATICAL TA
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2.104 SECTION 2 TABLE 2.23 Derivati
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2.106 SECTION 2 TABLE 2.24 Integral
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2.108 SECTION 2 TABLE 2.24 Integral
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2.110 SECTION 2 Regular Polygon of
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2.112 SECTION 2 A h[0.4(y y ) 1.
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2.114 SECTION 2 2.2.3.1 Signs of th
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2.116 SECTION 2 x2 x3 x4 x5 ln(1 x
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2.118 SECTION 2 2.3.2 Errors in Qua
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2.120 SECTION 2 The breadth or spre
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2.122 SECTION 2 TABLE 2.26b Areas U
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2.124 SECTION 2 The distribution of
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2.126 SECTION 2 Should there be mor
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2.128 SECTION 2 Example 10 Six samp
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2.130 SECTION 2 2.3.9 The F Statist
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TABLE 2.29 F Distribution (Continue
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2.134 SECTION 2 mathematical treatm
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2.136 SECTION 2 The confidence limi
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2.138 SECTION 2 situation where rel
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PROPERTIES OF ATOMS, RADICALS, AND
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SECTION 5 PHYSICAL PROPERTIES 5.1 S
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PHYSICAL PROPERTIES 5.3 5.1 SOLUBIL
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TABLE 5.1 Solubility of Gases in Wa
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TABLE 5.1 Solubility of Gases in Wa
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TABLE 5.2 Solubilities of Inorganic
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formateBa(CHO 2 ) 2 26.2 28.0 29.9
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(III) sulfateCe 2 (SO 4 ) 3 ·9H 2
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iodidePbI 2 0.044 0.056 0.069 0.090
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Nickel sulfateNiSO 4 ·6H 2 O (pale
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Praseodymium bromatePr(BrO 3 ) 3 55
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formate NaCHO 2 43.9 62.5 81.2 102
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Uranyl nitrate UO 2 (NO 3 ) 2 98 10
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PHYSICAL PROPERTIES 5.25 TABLE 5.3
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PHYSICAL PROPERTIES 5.57 5.3 BOILIN
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TABLE 5.12 Ternary Azeotropic Mixtu
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TABLE 5.12 Ternary Azeotropic Mixtu
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PHYSICAL PROPERTIES 5.83 5.4 FREEZI
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PHYSICAL PROPERTIES 5.87 5.5 DENSIT
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PHYSICAL PROPERTIES 5.89 dt Dt P
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PHYSICAL PROPERTIES 5.135 5.6.1 Ref
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PHYSICAL PROPERTIES 5.137 where the
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PHYSICAL PROPERTIES 5.139 5.7 COMBU
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Temperature, C Substance 40 20 0 20
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PHYSICAL PROPERTIES 5.171 This equa
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SECTION 6 THERMODYNAMIC PROPERTIES
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THERMODYNAMICPROPERTIES 6.3 6.1.1.2
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THERMODYNAMICPROPERTIES 6.5 A gener
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THERMODYNAMICPROPERTIES 6.7 TABLE 6
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THERMODYNAMICPROPERTIES 6.9 TABLE 6
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THERMODYNAMICPROPERTIES 6.11 TABLE
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THERMODYNAMIC PROPERTIES 6.21 TABLE
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THERMODYNAMIC PROPERTIES 6.101 TABL
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THERMODYNAMIC PROPERTIES 6.143 The
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SECTION 7 SPECTROSCOPY 7.1 X-RAY ME
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SPECTROSCOPY 7.3 TABLE 7.1 Waveleng
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SPECTROSCOPY 7.9 TABLE 7.3 Critical
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SPECTROSCOPY 7.11 TABLE 7.4 X-Ray E
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SPECTROSCOPY 7.13 Emission line K 1
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SPECTROSCOPY 7.15 TABLE 7.7 Analyzi
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SPECTROSCOPY 7.17 TABLE 7.8 Mass Ab
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SPECTROSCOPY 7.19 TABLE 7.9 Electro
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SPECTROSCOPY 7.21 TABLE 7.11 Absorp
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SPECTROSCOPY 7.23 TABLE 7.13 Solven
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SPECTROSCOPY 7.25 7.3 FLUORESCENCE
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SPECTROSCOPY 7.27 TABLE 7.16 Fluore
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SPECTROSCOPY 7.29 TABLE 7.18 Detect
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SPECTROSCOPY 7.35 TABLE 7.19 Sensit
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SPECTROSCOPY 7.37 TABLE 7.19 Sensit
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SPECTROSCOPY 7.39 In terms of m ,
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SPECTROSCOPY 7.41 The ionization co
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SPECTROSCOPY 7.67 TABLE 7.28 Infrar
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7.69
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SPECTROSCOPY 7.71 7.6 RAMAN SPECTRO
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SPECTROSCOPY 7.73 TABLE 7.30 Raman
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SPECTROSCOPY 7.89 7.7 NUCLEAR MAGNE
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SPECTROSCOPY 7.91 TABLE 7.41 Nuclea
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SPECTROSCOPY 7.93 TABLE 7.42 Proton
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SPECTROSCOPY 7.95 TABLE 7.44 Estima
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SPECTROSCOPY 7.97 TABLE 7.46 Proton
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SPECTROSCOPY 7.99 TABLE 7.48 Solven
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SPECTROSCOPY 7.101 TABLE 7.49 Carbo
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SPECTROSCOPY 7.103 TABLE 7.51 Effec
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SPECTROSCOPY 7.107 TABLE 7.56 One-B
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SPECTROSCOPY 7.113 TABLE 7.63 Nitro
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SPECTROSCOPY 7.115 TABLE 7.64 Nitro
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SPECTROSCOPY 7.117 TABLE 7.69 Fluor
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SPECTROSCOPY 7.119 TABLE 7.72 Silic
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SPECTROSCOPY 7.121 TABLE 7.73 Phosp
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SPECTROSCOPY 7.123 TABLE 7.74 Phosp
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SPECTROSCOPY 7.125 when z 3 and y
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SPECTROSCOPY 7.127 Masses 19 and 31
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SPECTROSCOPY 7.129 TABLE 7.76 Conde
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SECTION 8 ELECTROLYTES, ELECTROMOTI
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ELECTROLYTES, EMF, AND CHEMICAL EQU
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TABLE 8.7 Proton Transfer Reactions
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TABLE 8.7 Proton Transfer Reactions
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TABLE 8.9 Selected Equilibrium Cons
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8.75 3-tert-Butylbenzoic acid (0) 4
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4-Hydroxyproline (1) 1.900 1C 1.850
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N-Propionylglycine (1) 3.728 3.723
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TABLE 8.14 National Bureau of Stand
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1 part 0.1% neutral red in alc. * V
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3,3-Dimethoxybenzidine dihydrochlor
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TABLE 8.35 Equivalent Conductivitie
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KCl 127.3 124.4 122.4 115.8 112.0 1
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NaIO 3 75.2 72.6 70.9 64.4 60.5 1
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9.2 SECTION 9 9.1 LINEAR FREE ENERG
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9.4 SECTION 9 TABLE 9.1 Hammett and
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9.6 SECTION 9 TABLE 9.1 Hammett and
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9.8 SECTION 9 TABLE 9.3 pK a and Rh
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10.2 SECTION 10 10.4.6 Polyacrylate
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10.4 SECTION 10 10.2 ADDITIVES TO P
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10.6 SECTION 10 injection molding.
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10.8 SECTION 10 10.3 FORMULAS AND K
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10.10 SECTION 10 Key properties of
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10.12 SECTION 10 10.3.8 Fluorocarbo
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10.14 SECTION 10 10.3.11 Phenolics
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10.16 SECTION 10 The resin has the
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10.18 SECTION 10 10.3.19 Polyuretha
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10.20 SECTION 10 10.3.22 Sulfones B
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TABLE 10.2 Properties of Commercial
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10.58 SECTION 10 10.4 FORMULAS AND
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10.60 SECTION 10 10.4.8 Polychlorop
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10.62 SECTION 10 Styrene-butadiene
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10.5 CHEMICAL RESISTANCE TABLE 10.4
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10.6 GAS PERMEABILITY TABLE 10.5 Ga
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TABLE 10.5 Gas Permeability Constan
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TABLE 10.7 Constants ofFats and Oil
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TABLE 10.8 Constants ofWaxes Wax Me
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SECTION 11 PRACTICAL LABORATORY INF
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11.4 SECTION 11 TABLE 11.2 Molecula
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11.6 SECTION 11 A saturated aqueous
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11.8 SECTION 11 TABLE 11.6 Relative
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11.10 SECTION 11 11.3 BOILING POINT
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11.12 SECTION 11 TABLE 11.8 Organic
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11.14 SECTION 11 TABLE 11.9 Molecul
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11.4 SEPARATION METHODS TABLE 11.11
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11.18 SECTION 11 TABLE 11.12 Solven
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11.20 SECTION 11 TABLE 11.12 Solven
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TABLE 11.13 McReynolds’ Constants
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TABLE 11.13 McReynolds’ Constants
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11.26 SECTION 11 11.4.1 McReynolds
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11.28 SECTION 11 11.4.2.2 Partition
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11.30 SECTION 11 FIGURE 11.2 Band a
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11.32 SECTION 11 11.4.3 Ion-Exchang
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11.34 SECTION 11 TABLE 11.16 Guide
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11.36 SECTION 11 TABLE 11.16 Guide
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11.38 SECTION 11 TABLE 11.18 Relati
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11.40 SECTION 11 distribution coeff
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11.42 SECTION 11 TABLE 11.19 Gravim
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11.68 SECTION 11 TABLE 11.20 Elemen
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11.70 SECTION 11 TABLE 11.22 Common
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11.72 SECTION 11 TABLE 11.25 Tolera
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11.74 SECTION 11 TABLE 11.26 Heatin
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11.76 SECTION 11 TABLE 11.28 Titrim
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11.84 SECTION 11 appears becomes le
Page 1177 and 1178:
11.86 SECTION 11 TABLE 11.29 Equati
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11.88 SECTION 11 TABLE 11.29 Equati
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11.90 SECTION 11 The more stable th
Page 1183 and 1184:
11.92 SECTION 11 11.6.6.2.5 Buffer
Page 1185 and 1186:
11.94 SECTION 11 TABLE 11.30 Standa
Page 1187 and 1188:
TABLE 11.32 Properties and Applicat
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11.98 SECTION 11 TABLE 11.36 Maskin
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11.100 SECTION 11 TABLE 11.37 Anion
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11.102 SECTION 11 TABLE 11.39 Amino
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11.104 SECTION 11 TABLE 11.44 Facto
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11.106 SECTION 11 11.7 LABORATORY S
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11.108 SECTION 11 TABLE 11.48 Stand
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11.110 SECTION 11 Alizarin yellow G
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11.112 SECTION 11 Bromchlorophenol
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11.114 SECTION 11 p-Ethoxychrysoidi
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11.116 SECTION 11 Mercurous nitrate
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11.118 SECTION 11 Potassium carbona
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11.120 SECTION 11 until the ammoniu
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11.122 SECTION 11 TABLE 11.49 TLV C
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11.130 SECTION 11 TABLE 11.50 Chemi
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11.138 SECTION 11 of water which is
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TABLE 11.55 Thermoelectric Values i
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TABLE 11.56 Type B Thermocouples: P
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TABLE 11.58 Type J Thermocouples: I
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TABLE 11.60 Type N Thermocouples: N
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TABLE 11.62 Type S Thermocouples: P
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11.150 SECTION 11 11.11 CORRECTION
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Index Terms Links 2 Acid-base indic
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Index Terms Links 4 Alkynes, nomenc
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Index Terms Links 6 Aurintricarboxy
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Index Terms Links 8 Boron-11 chemic
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Index Terms Links 10 Cellulose acet
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Index Terms Links 12 Collective ino
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Index Terms Links 14 Degree Fahrenh
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Index Terms Links 16 Electrical res
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Index Terms Links 18 Equivalent wei
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Index Terms Links 20 Fluorocarbon p
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Index Terms Links 22 Halogenated hy
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Index Terms Links 24 Impact strengt
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Index Terms Links 26 Kα 1 lines, m
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Index Terms Links 28 Melmine phenol
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Index Terms Links 30 Neon-neon bond
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Index Terms Links 32 One-tailed tes
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Index Terms Links 34 Physical chemi
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Index Terms Links 36 Polyolefin the
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Index Terms Links 38 Pyridine: bina
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Index Terms Links 40 Rho values: fo
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Index Terms Links 42 Single-bond ra
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Index Terms Links 44 Stereoisomers
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Index Terms Links 46 Tension, aqueo
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Index Terms Links 48 Triethylenetet
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Index Terms Links 50 Water (Cont.)
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