preface to fifteenth edition

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TABLE 3.2 Physical Constants of Inorganic Compounds (Continued) Name Formula Formula weight Density Melting point, C Boiling point, C Solubility in 100 parts solvent 3.14 Aluminum (continued) potassium bis(sulfate) AlK(SO 4 ) 2 · 12H 2 O 474.39 1.757 20 9H 2 O, 92 anhyd, 200 11.4 g/100 mL aq; v s glyc; i alc 12-water propoxide Al(C 3 H 7 O) 3 204.25 1.0578 20 0 106 248 14mm daq;salc selenide Al 2 Se 3 290.84 3.437 20 4 947 d aq, acid silicon oxide (1/1)Al 2 O 3 · SiO 2 162.05 3.247 i aq; d HF; s fused alkali sodium bis(sulfate) AlNa(SO 4 ) 2 · 12H 2 O 458.28 1.675 20 61 110 g/100 mL 15 aq; i alc 12-water stearate Al(C 18 H 35 O 2 ) 3 877.41 1.070 117–120 i aq, alc; s bz, alk sulfate Al 2 (SO 4 ) 3 342.15 1.61 770 d 36.4 g/100 mL 20 aq; sl s alc sulfate 18-water Al 2 (SO 4 ) 3 · 18H 2 O 666.46 1.69 17 d 86.5 87 g/100 mL 0 aq; i alc sulfide Al 2 S 3 150.16 2.20 13 1097 subl 1500 hyd aq; s acid tetrahydridoborate Al(BH 4 ) 3 71.53 64.5 44.5 d aq; ign air; expl in O 2 ,20 Americium Am 243 12 1176 2011 s a Ammonia NH 3 17.03 lq: 0.6818 at bp g: 0.6175 15, 7.2atm 77.75 33.35 g/100 mL: 34 aq; 13.2 alc; s eth, organic solvents Ammonium acetate NH 4 C 2 H 3 O 2 77.08 1.17 20 114 d g/100 mL: 148 4 aq, 7.9 15 MeOH; s alc amidosulfate NH 4 SO 3 NH 2 114.13 131 d 160 v s aq; sl s alc benzoate NH 4 C 6 H 5 O 2 139.15 1.260 198 subl 160 g/100 mL: 20 15 aq, 2.8 alc; s glyc bromide NH 4 Br 97.94 2.429 452 (subl under d 397 vacuo 76 g/100 mL 20 aq; v s acet, alc, eth pressure) calcium arsenate 6-water NH 4 CaAsO 4 ·6H 2 O 305.13 1.905 15 d 140 0.02 aq; s NH 4 Cl carbamate NH 4 COONH 2 78.07 subl 60 v s aq; sl s alc; i eth carbonate 1-water (NH 4 ) 2 CO 3 ·H 2 O 114.10 volatilizes 60 v s aq; i alc chloride NH 4 Cl 53.49 1.5274 25 237.8 520 g/100 mL: 26 15 aq, 0.6 19 abs alc; i acet, eth chromate(VI)(NH 4 ) 2 CrO 4 152.07 1.91 12 d 185 34 g/100 mL 20 aq; sl s MeOH chromium(III)bissulfate NH 4 Cr(SO 4 ) 2 · 12H 2 O 478.34 1.72 94 d 7.2 g/100 mL 0 aq 12-water copper(II)tetrachloride 2-water (NH 4 ) 2 CuCl 4 ·2H 2 O 277.46 1.993 anhyd, 110 d 120 40.3 g/100 mL 20 aq; s alc
3.15 cyanide NH 4 CN 44.06 1.10 d 36 v s aq, alc dichromate(VI)(NH 4 ) 2 Cr 2 O 7 252.07 2.155 d 180 to Cr 2 O 3 35.6 g/100 mL 20 aq; s alc; flammable dihydrogen arsenate NH 4 H 2 AsO 4 158.97 2.311 d 300 v s aq dihydrogen phosphate NH 4 H 2 PO 4 115.03 1.803 19 d 190 37 g/100 mL 20 aq; sl s alc; i acet disulfatocobatate(II) (NH 4 ) 2 [Co(SO 4 ) 2 ]·6H 2 O 395.23 1.902 18 g/100 mL 20 aq; v sl s alc 6-water disulfatoferrate(II)6-water (NH 4 ) 2 [Fe(SO 4 ) 2 ]·6H 2 O 392.14 1.864 d 100 36.4 g/100 mL 20 aq; i alc disulfatoferrate(III) NH 4 [Fe(SO 4 ) 2 ] · 12H 2 O 482.19 1.71 39–41 d 230 124 g/100 mL aq 12-water disulfatonickelate(II) (NH 4 ) 2 [Ni(SO 4 ) 2 ]·6H 2 O 395.00 1.923 8.95 g/100 mL 20 aq 6-water dithiocarbamate NH 4 S(CS)NH 2 110.20 20 1.451 4 99 d v s aq; s alc; sl s eth diuranate(VI)(NH 4 ) 2 U 2 O 7 624.22 v sl s aq, alk; s acids fluoride NH 4 F 37.04 1.009 25 dtoNH 3 HF 100 g/100 mL 0 aq; s alc formate NH 4 OOCH 63.06 1.27 116 d 180 143 g/100 mL 20 aq; s alc, eth heptamolybdate(VI)(6) (NH 4 ) 2 Mo 7 O 24 ·4H 2 O 1235.86 2.498 anhyd 90 d 190 43 g/100 mL aq; s acids; i alc 4-water hexachloropalladate(IV)(NH 4 ) 2 [PdCl 6 ] 355.20 2.418 d sl s aq hexachloroplatinate(IV)(NH 4 ) 2 [PtCl 6 ] 443.87 3.065 d 380 0.5 aq hexadecanoate NH 4 OOC(CH 2 ) 14 CH 3 273.45 21–22 s aq; sl s bz; i alc, acet hexafluoroaluminate(3)(NH 4 ) 3 [AlF 6 ] 195.09 1.78 d 100 v s aq hexafluorogallate (NH 4 ) 3 GaF 6 237.83 2.10 d 200 hexafluorogermanate (NH 4 ) 2 GeF 6 222.68 2.564 380 subl s aq; i eth hexafluorophosphate NH 4 [PF 6 ] 163.00 18 2.180 4 d 68 74.8 g/100 mL 20 aq; s alc, acet hexafluorosilicate (NH 4 ) 2 [SiF 6 ] 178.15 2.011 d 18.6 g/100 mL 20 aq; i alc, acet hexanitratocerate(IV)(NH 4 ) 2 [Ce(NO 3 ) 6 ] 548.22 135 g/100 mL 20 aq; s alc, HNO hydrogen carbonate NH 4 HCO 3 79.06 1.586 107 (rapid g/100 mL: 17.4 20 aq, 10 glyc heating) hydrogen citrate (NH 4 ) 2 HC 6 H 5 O 7 226.19 1.48 100 g/100 mL aq; sl s alc hydrogen difluoride NH 4 HF 2 57.04 1.51 124.6 240 d v s aq; sl s alc hydrogen oxalate hydrate NH 4 HC 2 O 4 ·H 2 O 125.08 1.556 anhyd, 170 s aq, alc; i bz, eth hydrogen phosphate (NH 4 ) 2 HPO 4 132.06 1.619 d 155 69 g/100 mL 20 aq; i alc, acet hydrogen sulfate NH 4 HSO 4 115.11 1.78 146.9 d 350 100 g/100 mL aq; i alc, acet hydrogen sulfide NH 4 HS 51.11 1.17 d 25 to NH 3 128 g/100 mL 0 aq; s glyc; i alc, acet H 2 S hydrogen sulfite NH 4 HSO 3 99.11 2.03 subl 150 in N 2 267 g/100 mL 10 aq
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LANGE'S HANDBOOK OF CHEMISTRY John
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Grateful acknowledgment is hereby m
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PREFACE TO FIFTEENTH EDITION This n
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PREFACE TO FIFTEENTH EDITION ix inv
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xii PREFACE TO FOURTEENTH EDITION l
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PREFACE TO FIRST EDITION This book
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For the detailed contents of any se
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1.2 SECTION 1 is derived from the G
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1.4 SECTION 1 rather than methylide
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1.6 SECTION 1 Styrene Toluene Xylen
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1.8 SECTION 1 TABLE 1.2 Fused Polyc
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1.10 SECTION 1 1.1.1.6 Bridged Hydr
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1.12 SECTION 1 TABLE 1.4 Suffixes f
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1.14 SECTION 1 TABLE 1.5 Trivial Na
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1.16 SECTION 1 TABLE 1.6 Trivial Na
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1.18 SECTION 1 Selection of the pri
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1.20 SECTION 1 attached to one anot
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1.22 SECTION 1 When side chains of
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1.24 SECTION 1 heterocyclic structu
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1.26 SECTION 1 Bivalent radicals of
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1.28 SECTION 1 Complex linear polya
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1.30 SECTION 1 TABLE 1.11 Names of
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1.32 SECTION 1 hydroxyamino- to the
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1.34 SECTION 1 may be named (1) by
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1.36 SECTION 1 Examples are methyl
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1.38 SECTION 1 tuted acid, respecti
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1.40 SECTION 1 FIGURE 1.2 Newman pr
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1.42 SECTION 1 from the ring are kn
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1.44 SECTION 1 FIGURE 1.11 Two isom
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1.46 SECTION 1 Chiral Center. The c
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1.48 SECTION 1 FIGURE 1.15 Isomers
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1.50 SECTION 1 entries to bring tog
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1.52 SECTION 1 TABLE 1.13 Names and
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1.60 SECTION 1 TABLE 1.14 Empirical
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2.2 SECTION 2 2.3.6 Student’s Dis
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2.4 SECTION 2 TABLE 2.1 Fundamental
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2.6 SECTION 2 TABLE 2.1 Fundamental
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2.8 SECTION 2 TABLE 2.2 Physical an
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2.10 SECTION 2 TABLE 2.2 Physical a
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2.24 SECTION 2 TABLE 2.3 Mathematic
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2.26 SECTION 2 TABLE 2.6 Abbreviati
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2.36 SECTION 2 TABLE 2.7 Conversion
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2.54 SECTION 2 TABLE 2.8 Temperatur
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2.66 SECTION 2 2.1.1 Conversion of
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2.68 SECTION 2 Oleometer. A hydrome
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2.70 SECTION 2 Example 3. 25 1.2500
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2.72 SECTION 2 TABLE 2.9 Barometer
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2.74 SECTION 2 TABLE 2.9 Barometer
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2.76 SECTION 2 TABLE 2.10 Barometri
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2.78 SECTION 2 TABLE 2.12 Reduction
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2.80 SECTION 2 TABLE 2.12 Reduction
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2.82 SECTION 2 TABLE 2.13 Viscosity
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2.84 SECTION 2 TABLE 2.14 Conversio
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2.86 SECTION 2 TABLE 2.15 Hydromete
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2.88 SECTION 2 TABLE 2.17 Correctio
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2.90 SECTION 2 TABLE 2.18 Pressure
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2.96 SECTION 2 TABLE 2.20 Values of
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2.98 SECTION 2 TABLE 2.21 Transmitt
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2.100 SECTION 2 TABLE 2.21 Transmit
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SECTION 4 PROPERTIES OF ATOMS, RADI
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4.3 Fermium Fm 100 [Rn] 5f 12 7s 2
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Silver (argentum) Ag 47 [Kr] 4d 10
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PROPERTIES OF ATOMS,RADICALS,AND BO
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PROPERTIES OF ATOMS, RADICALS, AND
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SECTION 5 PHYSICAL PROPERTIES 5.1 S
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PHYSICAL PROPERTIES 5.3 5.1 SOLUBIL
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TABLE 5.1 Solubility of Gases in Wa
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TABLE 5.1 Solubility of Gases in Wa
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TABLE 5.2 Solubilities of Inorganic
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formateBa(CHO 2 ) 2 26.2 28.0 29.9
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(III) sulfateCe 2 (SO 4 ) 3 ·9H 2
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iodidePbI 2 0.044 0.056 0.069 0.090
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Nickel sulfateNiSO 4 ·6H 2 O (pale
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Praseodymium bromatePr(BrO 3 ) 3 55
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formate NaCHO 2 43.9 62.5 81.2 102
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Uranyl nitrate UO 2 (NO 3 ) 2 98 10
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PHYSICAL PROPERTIES 5.25 TABLE 5.3
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PHYSICAL PROPERTIES 5.57 5.3 BOILIN
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TABLE 5.12 Ternary Azeotropic Mixtu
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TABLE 5.12 Ternary Azeotropic Mixtu
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PHYSICAL PROPERTIES 5.83 5.4 FREEZI
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PHYSICAL PROPERTIES 5.87 5.5 DENSIT
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PHYSICAL PROPERTIES 5.89 dt Dt P
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PHYSICAL PROPERTIES 5.135 5.6.1 Ref
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PHYSICAL PROPERTIES 5.137 where the
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PHYSICAL PROPERTIES 5.139 5.7 COMBU
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Temperature, C Substance 40 20 0 20
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PHYSICAL PROPERTIES 5.171 This equa
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SECTION 6 THERMODYNAMIC PROPERTIES
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THERMODYNAMICPROPERTIES 6.3 6.1.1.2
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THERMODYNAMICPROPERTIES 6.5 A gener
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THERMODYNAMICPROPERTIES 6.7 TABLE 6
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THERMODYNAMICPROPERTIES 6.9 TABLE 6
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THERMODYNAMICPROPERTIES 6.11 TABLE
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THERMODYNAMIC PROPERTIES 6.21 TABLE
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THERMODYNAMIC PROPERTIES 6.101 TABL
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THERMODYNAMIC PROPERTIES 6.143 The
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SECTION 7 SPECTROSCOPY 7.1 X-RAY ME
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SPECTROSCOPY 7.3 TABLE 7.1 Waveleng
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SPECTROSCOPY 7.9 TABLE 7.3 Critical
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SPECTROSCOPY 7.11 TABLE 7.4 X-Ray E
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SPECTROSCOPY 7.13 Emission line K 1
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SPECTROSCOPY 7.15 TABLE 7.7 Analyzi
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SPECTROSCOPY 7.17 TABLE 7.8 Mass Ab
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SPECTROSCOPY 7.19 TABLE 7.9 Electro
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SPECTROSCOPY 7.21 TABLE 7.11 Absorp
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SPECTROSCOPY 7.23 TABLE 7.13 Solven
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SPECTROSCOPY 7.25 7.3 FLUORESCENCE
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SPECTROSCOPY 7.27 TABLE 7.16 Fluore
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SPECTROSCOPY 7.29 TABLE 7.18 Detect
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SPECTROSCOPY 7.35 TABLE 7.19 Sensit
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SPECTROSCOPY 7.37 TABLE 7.19 Sensit
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SPECTROSCOPY 7.39 In terms of m ,
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SPECTROSCOPY 7.41 The ionization co
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SPECTROSCOPY 7.67 TABLE 7.28 Infrar
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7.69
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SPECTROSCOPY 7.71 7.6 RAMAN SPECTRO
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SPECTROSCOPY 7.73 TABLE 7.30 Raman
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SPECTROSCOPY 7.89 7.7 NUCLEAR MAGNE
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SPECTROSCOPY 7.91 TABLE 7.41 Nuclea
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SPECTROSCOPY 7.93 TABLE 7.42 Proton
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SPECTROSCOPY 7.95 TABLE 7.44 Estima
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SPECTROSCOPY 7.97 TABLE 7.46 Proton
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SPECTROSCOPY 7.99 TABLE 7.48 Solven
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SPECTROSCOPY 7.101 TABLE 7.49 Carbo
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SPECTROSCOPY 7.103 TABLE 7.51 Effec
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SPECTROSCOPY 7.107 TABLE 7.56 One-B
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SPECTROSCOPY 7.113 TABLE 7.63 Nitro
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SPECTROSCOPY 7.115 TABLE 7.64 Nitro
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SPECTROSCOPY 7.117 TABLE 7.69 Fluor
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SPECTROSCOPY 7.119 TABLE 7.72 Silic
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SPECTROSCOPY 7.121 TABLE 7.73 Phosp
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SPECTROSCOPY 7.123 TABLE 7.74 Phosp
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SPECTROSCOPY 7.125 when z 3 and y
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SPECTROSCOPY 7.127 Masses 19 and 31
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SPECTROSCOPY 7.129 TABLE 7.76 Conde
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SECTION 8 ELECTROLYTES, ELECTROMOTI
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ELECTROLYTES, EMF, AND CHEMICAL EQU
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TABLE 8.7 Proton Transfer Reactions
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TABLE 8.7 Proton Transfer Reactions
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TABLE 8.9 Selected Equilibrium Cons
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8.75 3-tert-Butylbenzoic acid (0) 4
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4-Hydroxyproline (1) 1.900 1C 1.850
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N-Propionylglycine (1) 3.728 3.723
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TABLE 8.14 National Bureau of Stand
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1 part 0.1% neutral red in alc. * V
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3,3-Dimethoxybenzidine dihydrochlor
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TABLE 8.35 Equivalent Conductivitie
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KCl 127.3 124.4 122.4 115.8 112.0 1
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NaIO 3 75.2 72.6 70.9 64.4 60.5 1
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9.2 SECTION 9 9.1 LINEAR FREE ENERG
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9.4 SECTION 9 TABLE 9.1 Hammett and
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9.6 SECTION 9 TABLE 9.1 Hammett and
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9.8 SECTION 9 TABLE 9.3 pK a and Rh
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10.2 SECTION 10 10.4.6 Polyacrylate
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10.4 SECTION 10 10.2 ADDITIVES TO P
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10.6 SECTION 10 injection molding.
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10.8 SECTION 10 10.3 FORMULAS AND K
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10.10 SECTION 10 Key properties of
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10.12 SECTION 10 10.3.8 Fluorocarbo
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10.14 SECTION 10 10.3.11 Phenolics
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10.16 SECTION 10 The resin has the
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10.18 SECTION 10 10.3.19 Polyuretha
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10.20 SECTION 10 10.3.22 Sulfones B
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TABLE 10.2 Properties of Commercial
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10.58 SECTION 10 10.4 FORMULAS AND
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10.60 SECTION 10 10.4.8 Polychlorop
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10.62 SECTION 10 Styrene-butadiene
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10.5 CHEMICAL RESISTANCE TABLE 10.4
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10.6 GAS PERMEABILITY TABLE 10.5 Ga
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TABLE 10.5 Gas Permeability Constan
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TABLE 10.7 Constants ofFats and Oil
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TABLE 10.8 Constants ofWaxes Wax Me
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SECTION 11 PRACTICAL LABORATORY INF
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11.4 SECTION 11 TABLE 11.2 Molecula
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11.6 SECTION 11 A saturated aqueous
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11.8 SECTION 11 TABLE 11.6 Relative
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11.10 SECTION 11 11.3 BOILING POINT
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11.12 SECTION 11 TABLE 11.8 Organic
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11.14 SECTION 11 TABLE 11.9 Molecul
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11.4 SEPARATION METHODS TABLE 11.11
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11.18 SECTION 11 TABLE 11.12 Solven
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11.20 SECTION 11 TABLE 11.12 Solven
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TABLE 11.13 McReynolds’ Constants
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TABLE 11.13 McReynolds’ Constants
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11.26 SECTION 11 11.4.1 McReynolds
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11.28 SECTION 11 11.4.2.2 Partition
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11.30 SECTION 11 FIGURE 11.2 Band a
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11.32 SECTION 11 11.4.3 Ion-Exchang
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11.34 SECTION 11 TABLE 11.16 Guide
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11.36 SECTION 11 TABLE 11.16 Guide
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11.38 SECTION 11 TABLE 11.18 Relati
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11.40 SECTION 11 distribution coeff
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11.42 SECTION 11 TABLE 11.19 Gravim
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11.68 SECTION 11 TABLE 11.20 Elemen
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11.70 SECTION 11 TABLE 11.22 Common
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11.72 SECTION 11 TABLE 11.25 Tolera
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11.74 SECTION 11 TABLE 11.26 Heatin
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11.76 SECTION 11 TABLE 11.28 Titrim
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11.84 SECTION 11 appears becomes le
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11.86 SECTION 11 TABLE 11.29 Equati
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11.88 SECTION 11 TABLE 11.29 Equati
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11.90 SECTION 11 The more stable th
Page 1183 and 1184:
11.92 SECTION 11 11.6.6.2.5 Buffer
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11.94 SECTION 11 TABLE 11.30 Standa
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TABLE 11.32 Properties and Applicat
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11.98 SECTION 11 TABLE 11.36 Maskin
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11.100 SECTION 11 TABLE 11.37 Anion
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11.102 SECTION 11 TABLE 11.39 Amino
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11.104 SECTION 11 TABLE 11.44 Facto
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11.106 SECTION 11 11.7 LABORATORY S
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11.108 SECTION 11 TABLE 11.48 Stand
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11.110 SECTION 11 Alizarin yellow G
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11.112 SECTION 11 Bromchlorophenol
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11.114 SECTION 11 p-Ethoxychrysoidi
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11.116 SECTION 11 Mercurous nitrate
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11.118 SECTION 11 Potassium carbona
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11.120 SECTION 11 until the ammoniu
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11.122 SECTION 11 TABLE 11.49 TLV C
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11.130 SECTION 11 TABLE 11.50 Chemi
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11.138 SECTION 11 of water which is
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TABLE 11.55 Thermoelectric Values i
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TABLE 11.56 Type B Thermocouples: P
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TABLE 11.58 Type J Thermocouples: I
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TABLE 11.60 Type N Thermocouples: N
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TABLE 11.62 Type S Thermocouples: P
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11.150 SECTION 11 11.11 CORRECTION
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Index Terms Links 2 Acid-base indic
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Index Terms Links 4 Alkynes, nomenc
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Index Terms Links 6 Aurintricarboxy
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Index Terms Links 8 Boron-11 chemic
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Index Terms Links 10 Cellulose acet
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Index Terms Links 12 Collective ino
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Index Terms Links 14 Degree Fahrenh
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Index Terms Links 16 Electrical res
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Index Terms Links 18 Equivalent wei
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Index Terms Links 20 Fluorocarbon p
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Index Terms Links 22 Halogenated hy
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Index Terms Links 24 Impact strengt
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Index Terms Links 26 Kα 1 lines, m
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Index Terms Links 28 Melmine phenol
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Index Terms Links 30 Neon-neon bond
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Index Terms Links 32 One-tailed tes
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Index Terms Links 34 Physical chemi
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Index Terms Links 36 Polyolefin the
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Index Terms Links 38 Pyridine: bina
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Index Terms Links 40 Rho values: fo
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Index Terms Links 42 Single-bond ra
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Index Terms Links 44 Stereoisomers
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Index Terms Links 46 Tension, aqueo
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Index Terms Links 48 Triethylenetet
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Index Terms Links 50 Water (Cont.)
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