preface to fifteenth edition

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TABLE 3.2 Physical Constants of Inorganic Compounds (Continued) Name Formula Formula weight Density Melting point, C Boiling point, C Solubility in 100 parts solvent 3.22 Calcium (continued) chromate(VI) 2-water CaCrO 4 ·2H 2 O 192.10 2.50 anhyd 200 sl s aq; s dil acids citrate 4-water CaC 6 H 6 O 7 ·4H 2 O 570.51 anhyd 120 0.10 aq; i alc cyanamide CaCN 2 80.10 2.29 ca. 1340 subl no known solv without dec cyanide Ca(CN) 2 92.11 s 350 s aq dichromate(VI) CaCr 2 O 7 256.10 30 2.370 4 d 100 v s aq; i eth; d alc dihydrogen phosphate Ca(H 2 PO 4 ) 2 ·H 2 O 252.07 18 2.220 4 anhyd 100 d 200 1.8 30 aq hydrate diphosphate (pyrophosphate) Ca 2 P 2 O 7 254.10 3.09 1353 i aq; s HCl, HNO 3 fluoride CaF 2 78.08 3.180 1418 2533 0.0015 20 aq; s conc mineral acids formate Ca(CHO 2 ) 2 130.11 2.015 300 d 16.6 g/100 mL 20 aq; i alc ()gluconate Ca[OOC(CHOH) 2 CH 4 OH] 2 430.38 3.72 20 aq glycerophosphate Ca[C 3 H 5 (OH) 3 ]PO 4 210.16 d 170 1.66 20 aq; i alc hexafluorosilicate Ca[SiF 6 ] 182.17 2.662 i aq, acet hydride CaH 2 42.09 1.70 1000 d aq, alc hydroxide Ca(OH) 2 74.09 2.343 H 2 O, 580 0.17 10 aq; s acids hypochlorite Ca(OCl) 2 142.99 2.35 100 d d aq evolving Cl 2 ; i alc iodate Ca(IO 3 ) 2 389.88 15 4.519 4 d 540 0.10 0 aq; i alc iodide CaI 2 293.89 3.956 783 1755 68 g/100 mL 20 aq; v s alc, acet; i eth lactate 5-water Ca(C 3 H 5 O 3 ) 2 ·5H 2 O 308.30 3H 2 O, 100 anhyd 120 5.4 15 aq; v sl s alc magnesium carbonate Ca[Mg(CO 3 ) 2 ] 184.41 2.872 d 730 0.032 18 aq; s HCl molybdate(VI)(2) CaMoO 4 200.02 4.35 s conc mineral acids nitrate Ca(NO 3 ) 2 164.09 2.504 56l 152 g/100 mL 30 aq nitride Ca 3 N 2 148.25 2.67 1195 d aq; s dilute acids (d) nitrite 4-water Ca(NO 2 ) 2 ·4H 2 O 204.15 1.674 d 84.5 g/100 mL 18 aq; sl s alc oleate Ca(C 18 H 33 O 2 ) 2 603.01 83–84 d 400 0.04 aq; s chl, bz; v sl s alc, eth oxalate hydrate CaC 2 O 4 ·H 2 O 146.11 2.2 anhyd 200 0.0006 aq; s acids oxide CaO 56.08 3.34 2900 3500 0.13 25 aq; s acids palmitate Ca(C 16 H 31 O 2 ) 2 550.93 d 155 0.003 aq; sl s bz, chl, HOAc ()panthothenate (vitamin B 3 ) Ca[O 2 CH 2 CH 2 NHO- 476.55 d 195–196 36 g/100 mL aq; sl s alc, acet CH(OH)C(CH 3 ) 2 CH 2 OH] 2
3.23 perchlorate Ca(ClO 4 ) 2 238.98 2.65 d 270 g/100 mL 25 : 112 aq, 89.5 EtOH, 68 BuOH, 57 EtOAc, 43 acet permanganate 5-water Ca(MnO 4 ) 2 ·5H 2 O 368.03 2.4 d 338 g/100 mL aq peroxide CaO 2 72.08 2.92 explodes 275 sl s aq; s acids phenoxide Ca(OC 6 H 5 ) 2 226.28 d in air sl s aq, alc phosphate Ca 3 (PO 4 ) 2 310.18 3.14 1670 0.03 25 aq; s HCl, HNO 3 ; i alc phosphide Ca 3 P 2 182.18 2.51 ca. 1600 d aq; s acids; i alc, eth phosphinate Ca(PH 2 O 2 ) 2 170.06 d 300 15.4 g/100 mL aq; sl s glyc propanoate Ca(OOCC 3 H 5 ) 2 186.22 s aq; sl s alc; i acet, bz salicylate 2-water Ca(C 7 H 5 O 3 ) 2 ·2H 2 O 350.34 anhyd 200 d 240 2.8 15 aq; 0.015 16 EtOH selenate 2-water CaSeO 4 ·2H 2 O 219.07 2.75 anhyd 200 d 698 9.2 g/100 mL 25 aq selenide CaSe 119.04 3.82 silicate Ca 2 SiO 4 172.24 3.27 2130 i aq stearate Ca(C 18 H 35 O 2 ) 2 607.04 179–180 0.004 15 aq; s hot pyr; i acet, chl succinate 3-water CaC 4 H 6 O 4 ·3H 2 O 212.22 1.28 20 aq; s acids; i alc sulfate CaSO 4 136.14 2.960 1460 0.20 aq; s acids sulfate hemihydrate CaSO 4 · 0.5H 2 O 145.15 anhyd 163 0.3 20 aq; s acids, glyc sulfate 2-water CaSO 4 ·2H 2 O 172.17 2.32 1.5 H 2 O, 128 anhyd 163 0.26 20 aq; s acid, glyc sulfide CaS 72.14 2.59 2525 0.02 (d) aq; d acids sulfite 2-water CaSO 3 ·2H 2 O 156.17 anhyd 100 0.004 aq; s acids d; sl s alc ()tartrate 4-water CaC 4 H 4 O 6 ·4H 2 O 260.21 anhyd 200 0.0045 25 aq; s acids; sl s alc telluride CaTe 167.68 4.873 tetraborate CaB 4 O 7 195.36 s dil acids tetrahydridoaluminate Ca[AlH 4 ] 2 102.10 ign moist air d viol aq, alc; i bz, eth thiocyanate 3-water Ca(SCN) 2 ·3H 2 O 210.29 d 160 150 g/100 mL aq; v s alc thioglycollate 3-water Ca(-OOCCH 2 S-) · 3H 2 O 184.24 H 2 O, 95 d 220 s aq; v sl s alc, chl; i bz, eth thiosulfate 6-water CaS 2 O 3 ·6H 2 O 260.30 1.872 d 45 92 g/100 mL 25 aq; i alc titanate CaTiO 3 135.84 3.98 1980 tungstate(VI)(2) CaWO 4 287.93 6.062 20 0.0032 aq; d hot acids Californium-252 Cf 252.1 900 chloride CfCl 3 358.5 5.88 Carbon (diamond) C 12.011 3.513 3500 63.5atm 3930 i aq, alc (graphite) C 2.267 subl 3915–4020 dioxide CO 2 44.01 c: 1.56 79 78.44 subl 88 mL/100 mL 20 aq g: 1.975 g/L 0 diselenide CSe 2 169.93 2.6626 25 4 45.5 125.1 i aq; s acet, eth; misc CCl 4 ; d alc disulfide CS 2 76.14 1.2555 111.6 46.56 FP 30; 0.29 20 aq; s alc, eth
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LANGE'S HANDBOOK OF CHEMISTRY John
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Grateful acknowledgment is hereby m
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PREFACE TO FIFTEENTH EDITION This n
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PREFACE TO FIFTEENTH EDITION ix inv
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xii PREFACE TO FOURTEENTH EDITION l
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PREFACE TO FIRST EDITION This book
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For the detailed contents of any se
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1.2 SECTION 1 is derived from the G
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1.4 SECTION 1 rather than methylide
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1.6 SECTION 1 Styrene Toluene Xylen
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1.8 SECTION 1 TABLE 1.2 Fused Polyc
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1.10 SECTION 1 1.1.1.6 Bridged Hydr
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1.12 SECTION 1 TABLE 1.4 Suffixes f
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1.14 SECTION 1 TABLE 1.5 Trivial Na
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1.16 SECTION 1 TABLE 1.6 Trivial Na
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1.18 SECTION 1 Selection of the pri
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1.20 SECTION 1 attached to one anot
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1.22 SECTION 1 When side chains of
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1.24 SECTION 1 heterocyclic structu
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1.26 SECTION 1 Bivalent radicals of
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1.28 SECTION 1 Complex linear polya
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1.30 SECTION 1 TABLE 1.11 Names of
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1.32 SECTION 1 hydroxyamino- to the
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1.34 SECTION 1 may be named (1) by
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1.36 SECTION 1 Examples are methyl
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1.38 SECTION 1 tuted acid, respecti
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1.40 SECTION 1 FIGURE 1.2 Newman pr
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1.42 SECTION 1 from the ring are kn
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1.44 SECTION 1 FIGURE 1.11 Two isom
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1.46 SECTION 1 Chiral Center. The c
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1.48 SECTION 1 FIGURE 1.15 Isomers
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1.50 SECTION 1 entries to bring tog
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1.52 SECTION 1 TABLE 1.13 Names and
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1.60 SECTION 1 TABLE 1.14 Empirical
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2.2 SECTION 2 2.3.6 Student’s Dis
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2.4 SECTION 2 TABLE 2.1 Fundamental
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2.6 SECTION 2 TABLE 2.1 Fundamental
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2.8 SECTION 2 TABLE 2.2 Physical an
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2.10 SECTION 2 TABLE 2.2 Physical a
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2.24 SECTION 2 TABLE 2.3 Mathematic
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2.26 SECTION 2 TABLE 2.6 Abbreviati
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2.36 SECTION 2 TABLE 2.7 Conversion
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2.54 SECTION 2 TABLE 2.8 Temperatur
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2.66 SECTION 2 2.1.1 Conversion of
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2.68 SECTION 2 Oleometer. A hydrome
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2.70 SECTION 2 Example 3. 25 1.2500
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2.72 SECTION 2 TABLE 2.9 Barometer
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2.74 SECTION 2 TABLE 2.9 Barometer
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2.76 SECTION 2 TABLE 2.10 Barometri
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2.78 SECTION 2 TABLE 2.12 Reduction
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2.80 SECTION 2 TABLE 2.12 Reduction
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2.82 SECTION 2 TABLE 2.13 Viscosity
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2.84 SECTION 2 TABLE 2.14 Conversio
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2.86 SECTION 2 TABLE 2.15 Hydromete
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2.88 SECTION 2 TABLE 2.17 Correctio
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2.90 SECTION 2 TABLE 2.18 Pressure
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2.96 SECTION 2 TABLE 2.20 Values of
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2.98 SECTION 2 TABLE 2.21 Transmitt
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2.100 SECTION 2 TABLE 2.21 Transmit
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2.102 SECTION 2 2.2 MATHEMATICAL TA
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2.104 SECTION 2 TABLE 2.23 Derivati
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2.106 SECTION 2 TABLE 2.24 Integral
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2.108 SECTION 2 TABLE 2.24 Integral
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PROPERTIES OF ATOMS,RADICALS,AND BO
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PROPERTIES OF ATOMS, RADICALS, AND
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SECTION 5 PHYSICAL PROPERTIES 5.1 S
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PHYSICAL PROPERTIES 5.3 5.1 SOLUBIL
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TABLE 5.1 Solubility of Gases in Wa
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TABLE 5.1 Solubility of Gases in Wa
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TABLE 5.2 Solubilities of Inorganic
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formateBa(CHO 2 ) 2 26.2 28.0 29.9
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(III) sulfateCe 2 (SO 4 ) 3 ·9H 2
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iodidePbI 2 0.044 0.056 0.069 0.090
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Nickel sulfateNiSO 4 ·6H 2 O (pale
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Praseodymium bromatePr(BrO 3 ) 3 55
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formate NaCHO 2 43.9 62.5 81.2 102
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Uranyl nitrate UO 2 (NO 3 ) 2 98 10
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PHYSICAL PROPERTIES 5.25 TABLE 5.3
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PHYSICAL PROPERTIES 5.57 5.3 BOILIN
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TABLE 5.12 Ternary Azeotropic Mixtu
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TABLE 5.12 Ternary Azeotropic Mixtu
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PHYSICAL PROPERTIES 5.83 5.4 FREEZI
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PHYSICAL PROPERTIES 5.87 5.5 DENSIT
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PHYSICAL PROPERTIES 5.89 dt Dt P
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PHYSICAL PROPERTIES 5.135 5.6.1 Ref
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PHYSICAL PROPERTIES 5.137 where the
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PHYSICAL PROPERTIES 5.139 5.7 COMBU
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Temperature, C Substance 40 20 0 20
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PHYSICAL PROPERTIES 5.171 This equa
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SECTION 6 THERMODYNAMIC PROPERTIES
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THERMODYNAMICPROPERTIES 6.3 6.1.1.2
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THERMODYNAMICPROPERTIES 6.5 A gener
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THERMODYNAMICPROPERTIES 6.7 TABLE 6
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THERMODYNAMICPROPERTIES 6.9 TABLE 6
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THERMODYNAMICPROPERTIES 6.11 TABLE
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THERMODYNAMIC PROPERTIES 6.21 TABLE
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THERMODYNAMIC PROPERTIES 6.101 TABL
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THERMODYNAMIC PROPERTIES 6.143 The
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SECTION 7 SPECTROSCOPY 7.1 X-RAY ME
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SPECTROSCOPY 7.3 TABLE 7.1 Waveleng
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SPECTROSCOPY 7.9 TABLE 7.3 Critical
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SPECTROSCOPY 7.11 TABLE 7.4 X-Ray E
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SPECTROSCOPY 7.13 Emission line K 1
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SPECTROSCOPY 7.15 TABLE 7.7 Analyzi
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SPECTROSCOPY 7.17 TABLE 7.8 Mass Ab
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SPECTROSCOPY 7.19 TABLE 7.9 Electro
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SPECTROSCOPY 7.21 TABLE 7.11 Absorp
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SPECTROSCOPY 7.23 TABLE 7.13 Solven
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SPECTROSCOPY 7.25 7.3 FLUORESCENCE
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SPECTROSCOPY 7.27 TABLE 7.16 Fluore
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SPECTROSCOPY 7.29 TABLE 7.18 Detect
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SPECTROSCOPY 7.35 TABLE 7.19 Sensit
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SPECTROSCOPY 7.37 TABLE 7.19 Sensit
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SPECTROSCOPY 7.39 In terms of m ,
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SPECTROSCOPY 7.41 The ionization co
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SPECTROSCOPY 7.67 TABLE 7.28 Infrar
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7.69
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SPECTROSCOPY 7.71 7.6 RAMAN SPECTRO
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SPECTROSCOPY 7.73 TABLE 7.30 Raman
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SPECTROSCOPY 7.89 7.7 NUCLEAR MAGNE
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SPECTROSCOPY 7.91 TABLE 7.41 Nuclea
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SPECTROSCOPY 7.93 TABLE 7.42 Proton
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SPECTROSCOPY 7.95 TABLE 7.44 Estima
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SPECTROSCOPY 7.97 TABLE 7.46 Proton
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SPECTROSCOPY 7.99 TABLE 7.48 Solven
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SPECTROSCOPY 7.101 TABLE 7.49 Carbo
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SPECTROSCOPY 7.103 TABLE 7.51 Effec
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SPECTROSCOPY 7.107 TABLE 7.56 One-B
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SPECTROSCOPY 7.113 TABLE 7.63 Nitro
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SPECTROSCOPY 7.115 TABLE 7.64 Nitro
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SPECTROSCOPY 7.117 TABLE 7.69 Fluor
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SPECTROSCOPY 7.119 TABLE 7.72 Silic
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SPECTROSCOPY 7.121 TABLE 7.73 Phosp
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SPECTROSCOPY 7.123 TABLE 7.74 Phosp
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SPECTROSCOPY 7.125 when z 3 and y
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SPECTROSCOPY 7.127 Masses 19 and 31
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SPECTROSCOPY 7.129 TABLE 7.76 Conde
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SECTION 8 ELECTROLYTES, ELECTROMOTI
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ELECTROLYTES, EMF, AND CHEMICAL EQU
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TABLE 8.7 Proton Transfer Reactions
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TABLE 8.7 Proton Transfer Reactions
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TABLE 8.9 Selected Equilibrium Cons
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8.75 3-tert-Butylbenzoic acid (0) 4
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4-Hydroxyproline (1) 1.900 1C 1.850
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N-Propionylglycine (1) 3.728 3.723
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TABLE 8.14 National Bureau of Stand
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1 part 0.1% neutral red in alc. * V
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3,3-Dimethoxybenzidine dihydrochlor
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TABLE 8.35 Equivalent Conductivitie
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KCl 127.3 124.4 122.4 115.8 112.0 1
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NaIO 3 75.2 72.6 70.9 64.4 60.5 1
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9.2 SECTION 9 9.1 LINEAR FREE ENERG
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9.4 SECTION 9 TABLE 9.1 Hammett and
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9.6 SECTION 9 TABLE 9.1 Hammett and
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9.8 SECTION 9 TABLE 9.3 pK a and Rh
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10.2 SECTION 10 10.4.6 Polyacrylate
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10.4 SECTION 10 10.2 ADDITIVES TO P
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10.6 SECTION 10 injection molding.
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10.8 SECTION 10 10.3 FORMULAS AND K
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10.10 SECTION 10 Key properties of
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10.12 SECTION 10 10.3.8 Fluorocarbo
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10.14 SECTION 10 10.3.11 Phenolics
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10.16 SECTION 10 The resin has the
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10.18 SECTION 10 10.3.19 Polyuretha
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10.20 SECTION 10 10.3.22 Sulfones B
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TABLE 10.2 Properties of Commercial
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10.58 SECTION 10 10.4 FORMULAS AND
Page 1078 and 1079:
10.60 SECTION 10 10.4.8 Polychlorop
Page 1080 and 1081:
10.62 SECTION 10 Styrene-butadiene
Page 1082 and 1083:
10.5 CHEMICAL RESISTANCE TABLE 10.4
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10.6 GAS PERMEABILITY TABLE 10.5 Ga
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TABLE 10.5 Gas Permeability Constan
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TABLE 10.7 Constants ofFats and Oil
Page 1090 and 1091:
TABLE 10.8 Constants ofWaxes Wax Me
Page 1092:
SECTION 11 PRACTICAL LABORATORY INF
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11.4 SECTION 11 TABLE 11.2 Molecula
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11.6 SECTION 11 A saturated aqueous
Page 1099 and 1100:
11.8 SECTION 11 TABLE 11.6 Relative
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11.10 SECTION 11 11.3 BOILING POINT
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11.12 SECTION 11 TABLE 11.8 Organic
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11.14 SECTION 11 TABLE 11.9 Molecul
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11.4 SEPARATION METHODS TABLE 11.11
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11.18 SECTION 11 TABLE 11.12 Solven
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11.20 SECTION 11 TABLE 11.12 Solven
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TABLE 11.13 McReynolds’ Constants
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TABLE 11.13 McReynolds’ Constants
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11.26 SECTION 11 11.4.1 McReynolds
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11.28 SECTION 11 11.4.2.2 Partition
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11.30 SECTION 11 FIGURE 11.2 Band a
Page 1123 and 1124:
11.32 SECTION 11 11.4.3 Ion-Exchang
Page 1125 and 1126:
11.34 SECTION 11 TABLE 11.16 Guide
Page 1127 and 1128:
11.36 SECTION 11 TABLE 11.16 Guide
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11.38 SECTION 11 TABLE 11.18 Relati
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11.40 SECTION 11 distribution coeff
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11.42 SECTION 11 TABLE 11.19 Gravim
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11.68 SECTION 11 TABLE 11.20 Elemen
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11.70 SECTION 11 TABLE 11.22 Common
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11.72 SECTION 11 TABLE 11.25 Tolera
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11.74 SECTION 11 TABLE 11.26 Heatin
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11.76 SECTION 11 TABLE 11.28 Titrim
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11.84 SECTION 11 appears becomes le
Page 1177 and 1178:
11.86 SECTION 11 TABLE 11.29 Equati
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11.88 SECTION 11 TABLE 11.29 Equati
Page 1181 and 1182:
11.90 SECTION 11 The more stable th
Page 1183 and 1184:
11.92 SECTION 11 11.6.6.2.5 Buffer
Page 1185 and 1186:
11.94 SECTION 11 TABLE 11.30 Standa
Page 1187 and 1188:
TABLE 11.32 Properties and Applicat
Page 1189 and 1190:
11.98 SECTION 11 TABLE 11.36 Maskin
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11.100 SECTION 11 TABLE 11.37 Anion
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11.102 SECTION 11 TABLE 11.39 Amino
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11.104 SECTION 11 TABLE 11.44 Facto
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11.106 SECTION 11 11.7 LABORATORY S
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11.108 SECTION 11 TABLE 11.48 Stand
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11.110 SECTION 11 Alizarin yellow G
Page 1203 and 1204:
11.112 SECTION 11 Bromchlorophenol
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11.114 SECTION 11 p-Ethoxychrysoidi
Page 1207 and 1208:
11.116 SECTION 11 Mercurous nitrate
Page 1209 and 1210:
11.118 SECTION 11 Potassium carbona
Page 1211 and 1212:
11.120 SECTION 11 until the ammoniu
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11.122 SECTION 11 TABLE 11.49 TLV C
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Page 1221 and 1222:
11.130 SECTION 11 TABLE 11.50 Chemi
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Page 1227 and 1228:
Page 1229 and 1230:
11.138 SECTION 11 of water which is
Page 1231 and 1232:
TABLE 11.55 Thermoelectric Values i
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TABLE 11.56 Type B Thermocouples: P
Page 1235 and 1236:
TABLE 11.58 Type J Thermocouples: I
Page 1237 and 1238:
TABLE 11.60 Type N Thermocouples: N
Page 1239 and 1240:
TABLE 11.62 Type S Thermocouples: P
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11.150 SECTION 11 11.11 CORRECTION
Page 1243 and 1244:
Index Terms Links 2 Acid-base indic
Page 1245 and 1246:
Index Terms Links 4 Alkynes, nomenc
Page 1247 and 1248:
Index Terms Links 6 Aurintricarboxy
Page 1249 and 1250:
Index Terms Links 8 Boron-11 chemic
Page 1251 and 1252:
Index Terms Links 10 Cellulose acet
Page 1253 and 1254:
Index Terms Links 12 Collective ino
Page 1255 and 1256:
Index Terms Links 14 Degree Fahrenh
Page 1257 and 1258:
Index Terms Links 16 Electrical res
Page 1259 and 1260:
Index Terms Links 18 Equivalent wei
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Index Terms Links 20 Fluorocarbon p
Page 1263 and 1264:
Index Terms Links 22 Halogenated hy
Page 1265 and 1266:
Index Terms Links 24 Impact strengt
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Index Terms Links 26 Kα 1 lines, m
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Index Terms Links 28 Melmine phenol
Page 1271 and 1272:
Index Terms Links 30 Neon-neon bond
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Index Terms Links 32 One-tailed tes
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Index Terms Links 34 Physical chemi
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Index Terms Links 36 Polyolefin the
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Index Terms Links 38 Pyridine: bina
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Index Terms Links 40 Rho values: fo
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Index Terms Links 42 Single-bond ra
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Index Terms Links 44 Stereoisomers
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Index Terms Links 46 Tension, aqueo
Page 1289 and 1290:
Index Terms Links 48 Triethylenetet
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Index Terms Links 50 Water (Cont.)
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