preface to fifteenth edition

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1.2 SECTION 1 is derived from the Greek prefix (see Table 2.4) that cites the number of carbons in the alkane followed by -ane with elision of the terminal -a from the prefix, as shown in Table 1.1. TABLE 1.1 Names of Straight-Chain Alkanes n* Name n* Name n* Name n* Name 1 Methane 11 Undecane‡ 21 Henicosane 60 Hexacontane 2 Ethane 12 Dodecane 22 Docosane 70 Heptacontane 3 Propane 13 Tridecane 23 Tricosane 80 Octacontane 4 Butane 14 Tetradecane 90 Nonacontane 5 Pentane 15 Pentadecane 30 Triacontane 100 Hectane 6 Hexane 16 Hexadecane 31 Hentriacontane 110 Decahectane 7 Heptane 17 Heptadecane 32 Dotriacontane 120 Icosahectane 8 Octane 18 Octadecane 121 Henicosahectane 9 Nonane† 19 Nonadecane 40 Tetracontane 10 Decane 20 Icosane§ 50 Pentacontane * n total number of carbon atoms. † Formerly called enneane. ‡ Formerly called hendecane. § Formerly called eicosane. For branching compounds, the parent structure is the longest continuous chain present in the compound. Consider the compound to have been derived from this structure by replacement of hydrogen by various alkyl groups. Arabic number prefixes indicate the carbon to which the alkyl group is attached. Start numbering at whichever end of the parent structure that results in the lowestnumbered locants. The arabic prefixes are listed in numerical sequence, separated from each other by commas and from the remainder of the name by a hyphen. If the same alkyl group occurs more than once as a side chain, this is indicated by the prefixes di-, tri-, tetra-, etc. Side chains are cited in alphabetical order (before insertion of any multiplying prefix). The name of a complex radical (side chain) is considered to begin with the first letter of its complete name. Where names of complex radicals are composed of identical words, priority for citation is given to that radical which contains the lowest-numbered locant at the first cited point of difference in the radical. If two or more side chains are in equivalent positions, the one to be assigned the lowest-numbered locant is that cited first in the name. The complete expression for the side chain may be enclosed in parentheses for clarity or the carbon atoms in side chains may be indicated by primed locants. If hydrocarbon chains of equal length are competing for selection as the parent, the choice goes in descending order to (1) the chain that has the greatest number of side chains, (2) the chain whose side chains have the lowest-numbered locants, (3) the chain having the greatest number of carbon atoms in the smaller side chains, or (4) the chain having the least-branched side chains. These trivial names may be used for the unsubstituted hydrocarbon only: Isobutane (CH 3 ) 2 CHCH 3 Neopentane (CH 3 ) 4 C Isopentane (CH 3 ) 2 CHCH 2 CH 3 Isohexane (CH 3 ) 2 CHCH 2 CH 2 CH 3 Univalent radicals derived from saturated unbranched alkanes by removal of hydrogen from a terminal carbon atom are named by adding -yl in place of -ane to the stem name. Thus the alkane
ORGANIC COMPOUNDS 1.3 ethane becomes the radical ethyl. These exceptions are permitted for unsubstituted radicals only: Isopropyl (CH 3 ) 2 CH9 Isopentyl (CH 3 ) 2 CHCH 2 CH 2 9 Isobutyl (CH 3 ) 2 CHCH 2 9 Neopentyl (CH 3 ) 3 CCH 2 9 sec-Butyl CH 3 CH 2 CH(CH 3 )9 tert-Pentyl CH 3 CH 2 C(CH 3 ) 2 9 tert-Butyl (CH 3 ) 3 C9 Isohexyl (CH 3 ) 2 CHCH 2 CH 2 CH 2 9 Note the usage of the prefixes iso-, neo-, sec-, and tert-, and note when italics are employed. Italicized prefixes are never involved in alphabetization, except among themselves; thus sec-butyl would precede isobutyl, isohexyl would precede isopropyl, and sec-butyl would precede tert-butyl. Examples of alkane nomenclature are 2-Methylbutane (or the trivial name, isopentane) 3-Methylpentane (not 2-ethylbutane) 5-Ethyl-2,2-dimethyloctane (note cited order) 3-Ethyl-6-methyloctane (note locants reversed) 4,4-Bis(1,1-dimethylethyl)-2-methyloctane 4,4-Bis-1,1-dimethylethyl-2-methyloctane 4,4-Bis(tert-butyl)-2-methyloctane Bivalent radicals derived from saturated unbranched alkanes by removal of two hydrogen atoms are named as follows: (1) If both free bonds are on the same carbon atom, the ending -ane of the hydrocarbon is replaced with -ylidene. However, for the first member of the alkanes it is methylene
Page 2 and 3: LANGE'S HANDBOOK OF CHEMISTRY John
Page 4 and 5: Grateful acknowledgment is hereby m
Page 6 and 7: PREFACE TO FIFTEENTH EDITION This n
Page 8 and 9: PREFACE TO FIFTEENTH EDITION ix inv
Page 10 and 11: xii PREFACE TO FOURTEENTH EDITION l
Page 12 and 13: PREFACE TO FIRST EDITION This book
Page 14 and 15: For the detailed contents of any se
Page 18 and 19: 1.4 SECTION 1 rather than methylide
Page 20 and 21: 1.6 SECTION 1 Styrene Toluene Xylen
Page 22 and 23: 1.8 SECTION 1 TABLE 1.2 Fused Polyc
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Page 28 and 29: 1.14 SECTION 1 TABLE 1.5 Trivial Na
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Page 38 and 39: 1.24 SECTION 1 heterocyclic structu
Page 40 and 41: 1.26 SECTION 1 Bivalent radicals of
Page 42 and 43: 1.28 SECTION 1 Complex linear polya
Page 44 and 45: 1.30 SECTION 1 TABLE 1.11 Names of
Page 46 and 47: 1.32 SECTION 1 hydroxyamino- to the
Page 48 and 49: 1.34 SECTION 1 may be named (1) by
Page 50 and 51: 1.36 SECTION 1 Examples are methyl
Page 52 and 53: 1.38 SECTION 1 tuted acid, respecti
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Page 56 and 57: 1.42 SECTION 1 from the ring are kn
Page 58 and 59: 1.44 SECTION 1 FIGURE 1.11 Two isom
Page 60 and 61: 1.46 SECTION 1 Chiral Center. The c
Page 62 and 63: 1.48 SECTION 1 FIGURE 1.15 Isomers
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1.52 SECTION 1 TABLE 1.13 Names and
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1.60 SECTION 1 TABLE 1.14 Empirical
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2.2 SECTION 2 2.3.6 Student’s Dis
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2.4 SECTION 2 TABLE 2.1 Fundamental
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2.6 SECTION 2 TABLE 2.1 Fundamental
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2.8 SECTION 2 TABLE 2.2 Physical an
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2.10 SECTION 2 TABLE 2.2 Physical a
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2.24 SECTION 2 TABLE 2.3 Mathematic
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2.26 SECTION 2 TABLE 2.6 Abbreviati
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2.36 SECTION 2 TABLE 2.7 Conversion
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2.54 SECTION 2 TABLE 2.8 Temperatur
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2.66 SECTION 2 2.1.1 Conversion of
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2.68 SECTION 2 Oleometer. A hydrome
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2.70 SECTION 2 Example 3. 25 1.2500
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2.72 SECTION 2 TABLE 2.9 Barometer
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2.74 SECTION 2 TABLE 2.9 Barometer
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2.76 SECTION 2 TABLE 2.10 Barometri
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2.78 SECTION 2 TABLE 2.12 Reduction
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2.80 SECTION 2 TABLE 2.12 Reduction
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2.82 SECTION 2 TABLE 2.13 Viscosity
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2.84 SECTION 2 TABLE 2.14 Conversio
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2.86 SECTION 2 TABLE 2.15 Hydromete
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2.88 SECTION 2 TABLE 2.17 Correctio
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2.90 SECTION 2 TABLE 2.18 Pressure
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2.96 SECTION 2 TABLE 2.20 Values of
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2.98 SECTION 2 TABLE 2.21 Transmitt
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2.100 SECTION 2 TABLE 2.21 Transmit
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2.102 SECTION 2 2.2 MATHEMATICAL TA
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2.104 SECTION 2 TABLE 2.23 Derivati
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2.106 SECTION 2 TABLE 2.24 Integral
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2.108 SECTION 2 TABLE 2.24 Integral
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2.110 SECTION 2 Regular Polygon of
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2.112 SECTION 2 A h[0.4(y y ) 1.
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2.114 SECTION 2 2.2.3.1 Signs of th
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2.116 SECTION 2 x2 x3 x4 x5 ln(1 x
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2.118 SECTION 2 2.3.2 Errors in Qua
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2.120 SECTION 2 The breadth or spre
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2.122 SECTION 2 TABLE 2.26b Areas U
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2.124 SECTION 2 The distribution of
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2.126 SECTION 2 Should there be mor
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2.128 SECTION 2 Example 10 Six samp
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2.130 SECTION 2 2.3.9 The F Statist
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TABLE 2.29 F Distribution (Continue
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2.134 SECTION 2 mathematical treatm
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2.136 SECTION 2 The confidence limi
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2.138 SECTION 2 situation where rel
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3.2 SECTION 3 The alphabetical orde
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3.4 SECTION 3 When it is required t
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3.6 SECTION 3 PO phosphoryl SeO sel
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3.8 SECTION 3 3.1.5 Acids 3.1.5.1 A
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3.10 SECTION 3 3.1.6.6 Multiplicati
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3.12 SECTION 3 3.2 PHYSICAL PROPERT
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TABLE 3.2 Physical Constants of Ino
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3.62 SECTION 3 TABLE 3.3 Synonyms a
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SECTION 4 PROPERTIES OF ATOMS, RADI
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4.3 Fermium Fm 100 [Rn] 5f 12 7s 2
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Silver (argentum) Ag 47 [Kr] 4d 10
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PROPERTIES OF ATOMS,RADICALS,AND BO
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PROPERTIES OF ATOMS, RADICALS, AND
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SECTION 5 PHYSICAL PROPERTIES 5.1 S
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PHYSICAL PROPERTIES 5.3 5.1 SOLUBIL
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TABLE 5.1 Solubility of Gases in Wa
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TABLE 5.1 Solubility of Gases in Wa
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TABLE 5.2 Solubilities of Inorganic
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formateBa(CHO 2 ) 2 26.2 28.0 29.9
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(III) sulfateCe 2 (SO 4 ) 3 ·9H 2
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iodidePbI 2 0.044 0.056 0.069 0.090
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Nickel sulfateNiSO 4 ·6H 2 O (pale
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Praseodymium bromatePr(BrO 3 ) 3 55
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formate NaCHO 2 43.9 62.5 81.2 102
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Uranyl nitrate UO 2 (NO 3 ) 2 98 10
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PHYSICAL PROPERTIES 5.25 TABLE 5.3
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PHYSICAL PROPERTIES 5.57 5.3 BOILIN
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TABLE 5.12 Ternary Azeotropic Mixtu
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TABLE 5.12 Ternary Azeotropic Mixtu
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PHYSICAL PROPERTIES 5.83 5.4 FREEZI
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PHYSICAL PROPERTIES 5.87 5.5 DENSIT
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PHYSICAL PROPERTIES 5.89 dt Dt P
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PHYSICAL PROPERTIES 5.135 5.6.1 Ref
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PHYSICAL PROPERTIES 5.137 where the
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PHYSICAL PROPERTIES 5.139 5.7 COMBU
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Temperature, C Substance 40 20 0 20
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PHYSICAL PROPERTIES 5.171 This equa
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SECTION 6 THERMODYNAMIC PROPERTIES
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THERMODYNAMICPROPERTIES 6.3 6.1.1.2
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THERMODYNAMICPROPERTIES 6.5 A gener
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THERMODYNAMICPROPERTIES 6.7 TABLE 6
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THERMODYNAMICPROPERTIES 6.9 TABLE 6
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THERMODYNAMICPROPERTIES 6.11 TABLE
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THERMODYNAMIC PROPERTIES 6.21 TABLE
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THERMODYNAMIC PROPERTIES 6.101 TABL
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THERMODYNAMIC PROPERTIES 6.143 The
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SECTION 7 SPECTROSCOPY 7.1 X-RAY ME
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SPECTROSCOPY 7.3 TABLE 7.1 Waveleng
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SPECTROSCOPY 7.9 TABLE 7.3 Critical
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SPECTROSCOPY 7.11 TABLE 7.4 X-Ray E
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SPECTROSCOPY 7.13 Emission line K 1
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SPECTROSCOPY 7.15 TABLE 7.7 Analyzi
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SPECTROSCOPY 7.17 TABLE 7.8 Mass Ab
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SPECTROSCOPY 7.19 TABLE 7.9 Electro
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SPECTROSCOPY 7.21 TABLE 7.11 Absorp
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SPECTROSCOPY 7.23 TABLE 7.13 Solven
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SPECTROSCOPY 7.25 7.3 FLUORESCENCE
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SPECTROSCOPY 7.27 TABLE 7.16 Fluore
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SPECTROSCOPY 7.29 TABLE 7.18 Detect
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SPECTROSCOPY 7.35 TABLE 7.19 Sensit
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SPECTROSCOPY 7.37 TABLE 7.19 Sensit
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SPECTROSCOPY 7.39 In terms of m ,
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SPECTROSCOPY 7.41 The ionization co
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SPECTROSCOPY 7.67 TABLE 7.28 Infrar
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7.69
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SPECTROSCOPY 7.71 7.6 RAMAN SPECTRO
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SPECTROSCOPY 7.73 TABLE 7.30 Raman
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SPECTROSCOPY 7.89 7.7 NUCLEAR MAGNE
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SPECTROSCOPY 7.91 TABLE 7.41 Nuclea
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SPECTROSCOPY 7.93 TABLE 7.42 Proton
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SPECTROSCOPY 7.95 TABLE 7.44 Estima
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SPECTROSCOPY 7.97 TABLE 7.46 Proton
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SPECTROSCOPY 7.99 TABLE 7.48 Solven
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SPECTROSCOPY 7.101 TABLE 7.49 Carbo
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SPECTROSCOPY 7.103 TABLE 7.51 Effec
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SPECTROSCOPY 7.107 TABLE 7.56 One-B
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SPECTROSCOPY 7.113 TABLE 7.63 Nitro
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SPECTROSCOPY 7.115 TABLE 7.64 Nitro
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SPECTROSCOPY 7.117 TABLE 7.69 Fluor
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SPECTROSCOPY 7.119 TABLE 7.72 Silic
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SPECTROSCOPY 7.121 TABLE 7.73 Phosp
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SPECTROSCOPY 7.123 TABLE 7.74 Phosp
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SPECTROSCOPY 7.125 when z 3 and y
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SPECTROSCOPY 7.127 Masses 19 and 31
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SPECTROSCOPY 7.129 TABLE 7.76 Conde
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SECTION 8 ELECTROLYTES, ELECTROMOTI
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ELECTROLYTES, EMF, AND CHEMICAL EQU
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TABLE 8.7 Proton Transfer Reactions
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TABLE 8.7 Proton Transfer Reactions
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TABLE 8.9 Selected Equilibrium Cons
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8.75 3-tert-Butylbenzoic acid (0) 4
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4-Hydroxyproline (1) 1.900 1C 1.850
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N-Propionylglycine (1) 3.728 3.723
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TABLE 8.14 National Bureau of Stand
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1 part 0.1% neutral red in alc. * V
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3,3-Dimethoxybenzidine dihydrochlor
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TABLE 8.35 Equivalent Conductivitie
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KCl 127.3 124.4 122.4 115.8 112.0 1
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NaIO 3 75.2 72.6 70.9 64.4 60.5 1
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9.2 SECTION 9 9.1 LINEAR FREE ENERG
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9.4 SECTION 9 TABLE 9.1 Hammett and
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9.6 SECTION 9 TABLE 9.1 Hammett and
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9.8 SECTION 9 TABLE 9.3 pK a and Rh
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10.2 SECTION 10 10.4.6 Polyacrylate
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10.4 SECTION 10 10.2 ADDITIVES TO P
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10.6 SECTION 10 injection molding.
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10.8 SECTION 10 10.3 FORMULAS AND K
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10.10 SECTION 10 Key properties of
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10.12 SECTION 10 10.3.8 Fluorocarbo
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10.14 SECTION 10 10.3.11 Phenolics
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10.16 SECTION 10 The resin has the
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10.18 SECTION 10 10.3.19 Polyuretha
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10.20 SECTION 10 10.3.22 Sulfones B
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TABLE 10.2 Properties of Commercial
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10.58 SECTION 10 10.4 FORMULAS AND
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10.60 SECTION 10 10.4.8 Polychlorop
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10.62 SECTION 10 Styrene-butadiene
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10.5 CHEMICAL RESISTANCE TABLE 10.4
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10.6 GAS PERMEABILITY TABLE 10.5 Ga
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TABLE 10.5 Gas Permeability Constan
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TABLE 10.7 Constants ofFats and Oil
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TABLE 10.8 Constants ofWaxes Wax Me
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SECTION 11 PRACTICAL LABORATORY INF
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11.4 SECTION 11 TABLE 11.2 Molecula
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11.6 SECTION 11 A saturated aqueous
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11.8 SECTION 11 TABLE 11.6 Relative
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11.10 SECTION 11 11.3 BOILING POINT
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11.12 SECTION 11 TABLE 11.8 Organic
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11.14 SECTION 11 TABLE 11.9 Molecul
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11.4 SEPARATION METHODS TABLE 11.11
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11.18 SECTION 11 TABLE 11.12 Solven
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11.20 SECTION 11 TABLE 11.12 Solven
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TABLE 11.13 McReynolds’ Constants
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TABLE 11.13 McReynolds’ Constants
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11.26 SECTION 11 11.4.1 McReynolds
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11.28 SECTION 11 11.4.2.2 Partition
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11.30 SECTION 11 FIGURE 11.2 Band a
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11.32 SECTION 11 11.4.3 Ion-Exchang
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11.34 SECTION 11 TABLE 11.16 Guide
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11.36 SECTION 11 TABLE 11.16 Guide
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11.38 SECTION 11 TABLE 11.18 Relati
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11.40 SECTION 11 distribution coeff
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11.42 SECTION 11 TABLE 11.19 Gravim
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11.68 SECTION 11 TABLE 11.20 Elemen
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11.70 SECTION 11 TABLE 11.22 Common
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11.72 SECTION 11 TABLE 11.25 Tolera
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11.74 SECTION 11 TABLE 11.26 Heatin
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11.76 SECTION 11 TABLE 11.28 Titrim
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11.84 SECTION 11 appears becomes le
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11.86 SECTION 11 TABLE 11.29 Equati
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11.88 SECTION 11 TABLE 11.29 Equati
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11.90 SECTION 11 The more stable th
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11.92 SECTION 11 11.6.6.2.5 Buffer
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11.94 SECTION 11 TABLE 11.30 Standa
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TABLE 11.32 Properties and Applicat
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11.98 SECTION 11 TABLE 11.36 Maskin
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11.100 SECTION 11 TABLE 11.37 Anion
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11.102 SECTION 11 TABLE 11.39 Amino
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11.104 SECTION 11 TABLE 11.44 Facto
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11.106 SECTION 11 11.7 LABORATORY S
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11.108 SECTION 11 TABLE 11.48 Stand
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11.110 SECTION 11 Alizarin yellow G
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11.112 SECTION 11 Bromchlorophenol
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11.114 SECTION 11 p-Ethoxychrysoidi
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11.116 SECTION 11 Mercurous nitrate
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11.118 SECTION 11 Potassium carbona
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11.120 SECTION 11 until the ammoniu
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11.122 SECTION 11 TABLE 11.49 TLV C
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11.130 SECTION 11 TABLE 11.50 Chemi
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11.138 SECTION 11 of water which is
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TABLE 11.55 Thermoelectric Values i
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TABLE 11.56 Type B Thermocouples: P
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TABLE 11.58 Type J Thermocouples: I
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TABLE 11.60 Type N Thermocouples: N
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TABLE 11.62 Type S Thermocouples: P
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11.150 SECTION 11 11.11 CORRECTION
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Index Terms Links 2 Acid-base indic
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Index Terms Links 4 Alkynes, nomenc
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Index Terms Links 6 Aurintricarboxy
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Index Terms Links 8 Boron-11 chemic
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Index Terms Links 10 Cellulose acet
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Index Terms Links 12 Collective ino
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Index Terms Links 14 Degree Fahrenh
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Index Terms Links 16 Electrical res
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Index Terms Links 18 Equivalent wei
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Index Terms Links 20 Fluorocarbon p
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Index Terms Links 22 Halogenated hy
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Index Terms Links 24 Impact strengt
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Index Terms Links 26 Kα 1 lines, m
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Index Terms Links 28 Melmine phenol
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Index Terms Links 30 Neon-neon bond
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Index Terms Links 32 One-tailed tes
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Index Terms Links 34 Physical chemi
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Index Terms Links 36 Polyolefin the
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Index Terms Links 38 Pyridine: bina
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Index Terms Links 40 Rho values: fo
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Index Terms Links 42 Single-bond ra
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Index Terms Links 44 Stereoisomers
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Index Terms Links 46 Tension, aqueo
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Index Terms Links 48 Triethylenetet
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Index Terms Links 50 Water (Cont.)
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