preface to fifteenth edition

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PHYSICAL PROPERTIES 5.99 TABLE 5.16 Viscosity and Surface Tension of Various Organic Substances (Continued) Surface tension, mN · m 1 Substance a b Liquid range, C Viscosity, mN · s · m 2 2-Methyl-1-butene 18.81 0.1148 137.6to 31 2-Methyl-2-butene 19.70 0.1271 133.8 to 38.6 3-Methyl-1-butene 16.42 0.1031 168to20 2-Methylbutyl acetate 26.75 0.0989 99 to 117 0.872(20) 3-Methylbutyronitrile 27.58 0.0827 101 to 129 Methyl chloroacetate 37.90 0.1304 32 to 130 Methyl cyanoacetate 41.32 0.1074 22.5 to 201 3.824(50), 3.398(55), 2.687(65) Methylcyclohexane 26.11 0.1130 126.6 to 100.9 0.679(25), 0.501(50), 0.390(75) cis-2-Methylcyclohexanol 32.45 0.0770 7 to 165 18.08(25), 13.60(30) (mixed isomers) trans-2-Methylcyclohexanol 2 to 167.5 37.13(25), 25.14(30) cis-3-Methylcyclohexanol 29.08 0.0629 6to 168 19.7(25), 17.23(30) (mixed isomers) trans-3-Methylcyclohexanol 28.80(30) 0.5 to 167 25.62(16), 15.60(30) cis-4-Methylcyclohexanol 29.07 0.0690 9.2 to 173 (mixed isomers) 2-Methylcyclohexanone 34.060.1027 up to 162 3-Methylcyclohexanone 33.060.0925 up to 169 4-Methylcyclohexanone 32.83 0.0935 up to 171 Methylcyclopentane 24.63 0.1163 142.2 to 71.8 0.653(0), 0.478(25), 0.364(50) Methyl decanoate 30.33 0.0912 18 to 223 Methyl dichloroacetate 37.00 0.1219 52 to 143 Methyl dodecanoate 31.37 0.0893 4.8 to 262 N-Methylformamide 37.96(30) 35.02(50) 4 to 199.5 1.678(25), 1.155(50), 0.824(75) Methyl formate 28.29 0.1572 99 to 31.7 0.424(0), 0.360(15), 0.325(25) Methyl heptanoate 28.95 0.0987 55.8 to 173.5 4-Methyl-3-heptanol 123 to 170 1.085(25), 0.702(50), 0.497(75) 5-Methyl-3-heptanol 91 to 172 1.178(25), 0.762(50), 0.536(75) Methyl hexadecanoate 31.50 0.0775 32 to 196 (palmitate) 2-Methylhexane 21.22 0.0966 118 to 90 0.378(20) 3-Methylhexane 21.73 0.0970 119 to 92 0.372(20), 0.350(25) Methyl hexanoate 28.47 0.1045 71 to 151 Methyl isobutanoate 25.99 0.1131 84.7 to 92.5 0.672(0), 0.523(20), 0.419(40) 1-Methyl-4-isopropylbenzene 28.83 0.0877 3.402(20) (p-cymene) Methyl methacrylate 28- 48 to 100 0.632(20) 29(30) 1-Methylnaphthalene 39.960.0934 30.4 to 245 Methyl octadecanoate 32.20 0.0775 38 to 215 2-Methyloctane 23.760.0940 80.3 to 143.2 4-Methyloctane 24.22 0.0940 113 to 142 Methyl octanoate 29.93 0.1002 40 to 192.9 Methyl oleate 31.3(25) 25.4(100) 19.9 to 218 4.88(20) 2-Methylpentane 19.37 0.0997 154 to 60.3 0.372(0), 0.286(25), 0.226(50) 3-Methylpentane 20.260.1060 163 to 63 0.395(0), 0.307(25), 0.292(30)
5.100 SECTION 5 TABLE 5.16 Viscosity and Surface Tension of Various Organic Substances (Continued) Surface tension, mN · m 1 Substance a b Liquid range, C Viscosity, mN · s · m 2 4-Methylpentanenitrile 28.89 0.0917 51.1 to 156.5 0.980(20), 0.843(30) Methyl pentanoate 27.85 0.1044 up to 128 0.713(20) 2-Methyl-1-pentanol 26.98 0.0819 up to 148 3-Methyl-1-pentanol 26.92 0.0789 up to 153 4-Methyl-1-pentanol 25.93 0.0743 up to 152 2-Methyl-2-pentanol 25.07 0.0861 103 to 121 3-Methyl-2-pentanol 27.14 0.0919 up to 134 4-Methyl-2-pentanol 24.67 0.0821 90 to 122 4.074(25) 2-Methyl-3-pentanol 26.43 0.0914 up to 126 3-Methyl-3-pentanol 25.48 0.0888 23.6to 123 4-Methyl-2-pentanone 23.64(20) 19.62(60) 84 to 116.5 0.585(20), 0.522(30), 0.406(50) Methyl phenyl sulfide 42.81 0.1238 15 to 188 N-Methyl propanamide 31.29(20) 29.12(50) 43 to 146 6.06(20), 4.58(30), 3.56(40) 2-Methylpropanenitrile 72 to 108 0.551(15), 0.456(30) Methyl propanoate 27.58 0.1258 88 to 80 0.581(0), 0.431(25), 0.333(50) 2-Methylpropanoic acid 25.55(20) 25.13(25) 47 to 154 1.857(0), 1.226(25), 0.863(50) 2-Methyl-1-propanol 24.53 0.0795 108 to 108 4.70(15), 2.876(30) 2-Methyl-2-propanol 20.02(15) 19.10(30) 25.8 to 82.4 1.421(50), 0.678(75) 2-Methylpropene 14.84 0.1319 140 to 6.9 1-Methylpropyl acetate 25.72 0.1054 2-Methyl-1-propylamine 24.48 0.1092 87 to 68 21.7(25) 2-Methylpropyl formate 26.14 0.1122 96to 98 0.680(20) 2-Methylpyridine 36.11 0.1243 66.7 to 129 0.805(20), 0.710(30) 3-Methylpyridine 37.35 0.1153 18.3 to 144 4-Methylpyridine 37.71 0.1141 3.8 to 145 N-Methyl-2-pyrrolidinone 24.4 to 202 1.666(25) Methyl salicylate 42.15 0.1174 8 to 223 1.102(75), 0.815(100) Methyl tetradecanoate 31.00 0.0800 18.4 to 323 2-Methyltetrahydrofuran 75 to 78 0.777(20), 0.601(0), 0.536(10) Methyl thiocyanate 40.66 0.1305 5 to 133 64.3(0) Morpholine 37.63(20) 36.24(30) 4.9 to 128 2.53(15), 1.79(30), 1.247(50) Naphthalene 80 to 217.7 0.967(80), 0.780(100) p-Nitroaniline 60.62 0.0923 147 to 332 Nitrobenzene 48.62 0.1185 5.8 to 210.8 2.165(15), 1.863(25), 1.262(50) Nitroethane 35.27 0.1255 90 to 114 0.940(0), 0.688(25), 0.526(50) Nitromethane 40.72 0.1678 28.4 to 101.2 0.692(15), 0.596(30), 0.481(50) 1-Nitro-2-methoxybenzene 48.62 0.1185 95 to 273 o-Nitrophenol 47.35 0.1174 45 to 2162.343(45) 1-Nitropropane 32.62 0.1009 108 to 131.1 0.798(25), 0.589(50), 0.460(75) 2-Nitropropane 32.18 0.1158 91.3 to 120.3 0.750(25) o-Nitrotoluene 44.10 0.1174 10 to 222 2.37(20), 1.63(40) m-Nitrotoluene 43.54 0.1118 15.5 to 231.9 0.233(20), 1.60(40) p-Nitrotoluene 42.260.0974 52 to 238 1.20(60) Nonane 24.72 0.0935 53.5 to 150.8 0.964(0), 0.666(25), 0.488(50) Nonanoic acid 12.5 to 254.5 7.011(25), 3.712(50), 2.234(75) 1-Nonanol 29.79 0.0789 5.5 to 215 14.3(20), 9.123(25), 4.032(50) 5-Nonanone 28.72 0.0975 50 to 187 1.199(25), 0.834(50), 0.619(75) 1-Nonene 24.90 0.0938 81 to 146 0.620(20), 0.586(25) Octadecane 29.98 0.0843 28.1 to 316.3 2.487(50), 1.609(75), 1.132(100)
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LANGE'S HANDBOOK OF CHEMISTRY John
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Grateful acknowledgment is hereby m
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PREFACE TO FIFTEENTH EDITION This n
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PREFACE TO FIFTEENTH EDITION ix inv
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xii PREFACE TO FOURTEENTH EDITION l
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PREFACE TO FIRST EDITION This book
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For the detailed contents of any se
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1.2 SECTION 1 is derived from the G
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1.4 SECTION 1 rather than methylide
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1.6 SECTION 1 Styrene Toluene Xylen
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1.8 SECTION 1 TABLE 1.2 Fused Polyc
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1.10 SECTION 1 1.1.1.6 Bridged Hydr
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1.12 SECTION 1 TABLE 1.4 Suffixes f
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1.14 SECTION 1 TABLE 1.5 Trivial Na
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1.16 SECTION 1 TABLE 1.6 Trivial Na
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1.18 SECTION 1 Selection of the pri
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1.20 SECTION 1 attached to one anot
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1.22 SECTION 1 When side chains of
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1.24 SECTION 1 heterocyclic structu
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1.26 SECTION 1 Bivalent radicals of
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1.28 SECTION 1 Complex linear polya
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1.30 SECTION 1 TABLE 1.11 Names of
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1.32 SECTION 1 hydroxyamino- to the
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1.34 SECTION 1 may be named (1) by
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1.36 SECTION 1 Examples are methyl
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1.38 SECTION 1 tuted acid, respecti
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1.40 SECTION 1 FIGURE 1.2 Newman pr
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1.42 SECTION 1 from the ring are kn
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1.44 SECTION 1 FIGURE 1.11 Two isom
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1.46 SECTION 1 Chiral Center. The c
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1.48 SECTION 1 FIGURE 1.15 Isomers
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1.50 SECTION 1 entries to bring tog
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1.52 SECTION 1 TABLE 1.13 Names and
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1.60 SECTION 1 TABLE 1.14 Empirical
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2.2 SECTION 2 2.3.6 Student’s Dis
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2.4 SECTION 2 TABLE 2.1 Fundamental
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2.6 SECTION 2 TABLE 2.1 Fundamental
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2.8 SECTION 2 TABLE 2.2 Physical an
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2.10 SECTION 2 TABLE 2.2 Physical a
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2.24 SECTION 2 TABLE 2.3 Mathematic
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2.26 SECTION 2 TABLE 2.6 Abbreviati
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2.36 SECTION 2 TABLE 2.7 Conversion
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2.54 SECTION 2 TABLE 2.8 Temperatur
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2.66 SECTION 2 2.1.1 Conversion of
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2.68 SECTION 2 Oleometer. A hydrome
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2.70 SECTION 2 Example 3. 25 1.2500
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2.72 SECTION 2 TABLE 2.9 Barometer
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2.74 SECTION 2 TABLE 2.9 Barometer
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2.76 SECTION 2 TABLE 2.10 Barometri
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2.78 SECTION 2 TABLE 2.12 Reduction
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2.80 SECTION 2 TABLE 2.12 Reduction
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2.82 SECTION 2 TABLE 2.13 Viscosity
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2.84 SECTION 2 TABLE 2.14 Conversio
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2.86 SECTION 2 TABLE 2.15 Hydromete
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2.88 SECTION 2 TABLE 2.17 Correctio
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2.90 SECTION 2 TABLE 2.18 Pressure
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2.96 SECTION 2 TABLE 2.20 Values of
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2.98 SECTION 2 TABLE 2.21 Transmitt
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2.100 SECTION 2 TABLE 2.21 Transmit
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2.102 SECTION 2 2.2 MATHEMATICAL TA
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2.104 SECTION 2 TABLE 2.23 Derivati
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2.106 SECTION 2 TABLE 2.24 Integral
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2.108 SECTION 2 TABLE 2.24 Integral
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2.110 SECTION 2 Regular Polygon of
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2.112 SECTION 2 A h[0.4(y y ) 1.
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2.114 SECTION 2 2.2.3.1 Signs of th
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2.116 SECTION 2 x2 x3 x4 x5 ln(1 x
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2.118 SECTION 2 2.3.2 Errors in Qua
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2.120 SECTION 2 The breadth or spre
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2.122 SECTION 2 TABLE 2.26b Areas U
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2.124 SECTION 2 The distribution of
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2.126 SECTION 2 Should there be mor
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2.128 SECTION 2 Example 10 Six samp
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2.130 SECTION 2 2.3.9 The F Statist
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TABLE 2.29 F Distribution (Continue
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2.134 SECTION 2 mathematical treatm
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2.136 SECTION 2 The confidence limi
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2.138 SECTION 2 situation where rel
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3.2 SECTION 3 The alphabetical orde
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3.4 SECTION 3 When it is required t
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3.6 SECTION 3 PO phosphoryl SeO sel
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3.8 SECTION 3 3.1.5 Acids 3.1.5.1 A
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3.10 SECTION 3 3.1.6.6 Multiplicati
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3.12 SECTION 3 3.2 PHYSICAL PROPERT
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TABLE 3.2 Physical Constants of Ino
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3.62 SECTION 3 TABLE 3.3 Synonyms a
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SECTION 4 PROPERTIES OF ATOMS, RADI
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4.3 Fermium Fm 100 [Rn] 5f 12 7s 2
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Silver (argentum) Ag 47 [Kr] 4d 10
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PROPERTIES OF ATOMS,RADICALS,AND BO
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PROPERTIES OF ATOMS, RADICALS, AND
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SECTION 5 PHYSICAL PROPERTIES 5.1 S
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PHYSICAL PROPERTIES 5.3 5.1 SOLUBIL
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TABLE 5.1 Solubility of Gases in Wa
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TABLE 5.1 Solubility of Gases in Wa
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TABLE 5.2 Solubilities of Inorganic
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formateBa(CHO 2 ) 2 26.2 28.0 29.9
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(III) sulfateCe 2 (SO 4 ) 3 ·9H 2
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iodidePbI 2 0.044 0.056 0.069 0.090
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Nickel sulfateNiSO 4 ·6H 2 O (pale
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Praseodymium bromatePr(BrO 3 ) 3 55
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formate NaCHO 2 43.9 62.5 81.2 102
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Uranyl nitrate UO 2 (NO 3 ) 2 98 10
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PHYSICAL PROPERTIES 5.25 TABLE 5.3
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Temperature, C Substance 40 20 0 20
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PHYSICAL PROPERTIES 5.171 This equa
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SECTION 6 THERMODYNAMIC PROPERTIES
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THERMODYNAMICPROPERTIES 6.3 6.1.1.2
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THERMODYNAMICPROPERTIES 6.5 A gener
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THERMODYNAMICPROPERTIES 6.7 TABLE 6
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THERMODYNAMICPROPERTIES 6.9 TABLE 6
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THERMODYNAMICPROPERTIES 6.11 TABLE
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THERMODYNAMIC PROPERTIES 6.21 TABLE
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THERMODYNAMIC PROPERTIES 6.101 TABL
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THERMODYNAMIC PROPERTIES 6.143 The
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SECTION 7 SPECTROSCOPY 7.1 X-RAY ME
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SPECTROSCOPY 7.3 TABLE 7.1 Waveleng
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SPECTROSCOPY 7.9 TABLE 7.3 Critical
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SPECTROSCOPY 7.11 TABLE 7.4 X-Ray E
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SPECTROSCOPY 7.13 Emission line K 1
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SPECTROSCOPY 7.15 TABLE 7.7 Analyzi
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SPECTROSCOPY 7.17 TABLE 7.8 Mass Ab
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SPECTROSCOPY 7.19 TABLE 7.9 Electro
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SPECTROSCOPY 7.21 TABLE 7.11 Absorp
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SPECTROSCOPY 7.23 TABLE 7.13 Solven
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SPECTROSCOPY 7.25 7.3 FLUORESCENCE
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SPECTROSCOPY 7.27 TABLE 7.16 Fluore
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SPECTROSCOPY 7.29 TABLE 7.18 Detect
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SPECTROSCOPY 7.35 TABLE 7.19 Sensit
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SPECTROSCOPY 7.37 TABLE 7.19 Sensit
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SPECTROSCOPY 7.39 In terms of m ,
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SPECTROSCOPY 7.41 The ionization co
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SPECTROSCOPY 7.67 TABLE 7.28 Infrar
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7.69
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SPECTROSCOPY 7.71 7.6 RAMAN SPECTRO
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SPECTROSCOPY 7.73 TABLE 7.30 Raman
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SPECTROSCOPY 7.89 7.7 NUCLEAR MAGNE
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SPECTROSCOPY 7.91 TABLE 7.41 Nuclea
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SPECTROSCOPY 7.93 TABLE 7.42 Proton
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SPECTROSCOPY 7.95 TABLE 7.44 Estima
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SPECTROSCOPY 7.97 TABLE 7.46 Proton
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SPECTROSCOPY 7.99 TABLE 7.48 Solven
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SPECTROSCOPY 7.101 TABLE 7.49 Carbo
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SPECTROSCOPY 7.103 TABLE 7.51 Effec
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SPECTROSCOPY 7.107 TABLE 7.56 One-B
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SPECTROSCOPY 7.113 TABLE 7.63 Nitro
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SPECTROSCOPY 7.115 TABLE 7.64 Nitro
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SPECTROSCOPY 7.117 TABLE 7.69 Fluor
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SPECTROSCOPY 7.119 TABLE 7.72 Silic
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SPECTROSCOPY 7.121 TABLE 7.73 Phosp
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SPECTROSCOPY 7.123 TABLE 7.74 Phosp
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SPECTROSCOPY 7.125 when z 3 and y
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SPECTROSCOPY 7.127 Masses 19 and 31
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SPECTROSCOPY 7.129 TABLE 7.76 Conde
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SECTION 8 ELECTROLYTES, ELECTROMOTI
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ELECTROLYTES, EMF, AND CHEMICAL EQU
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TABLE 8.7 Proton Transfer Reactions
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TABLE 8.7 Proton Transfer Reactions
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TABLE 8.9 Selected Equilibrium Cons
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8.75 3-tert-Butylbenzoic acid (0) 4
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4-Hydroxyproline (1) 1.900 1C 1.850
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N-Propionylglycine (1) 3.728 3.723
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TABLE 8.14 National Bureau of Stand
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1 part 0.1% neutral red in alc. * V
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3,3-Dimethoxybenzidine dihydrochlor
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TABLE 8.35 Equivalent Conductivitie
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KCl 127.3 124.4 122.4 115.8 112.0 1
Page 1008 and 1009:
NaIO 3 75.2 72.6 70.9 64.4 60.5 1
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Page 1012 and 1013:
9.2 SECTION 9 9.1 LINEAR FREE ENERG
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9.4 SECTION 9 TABLE 9.1 Hammett and
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9.6 SECTION 9 TABLE 9.1 Hammett and
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9.8 SECTION 9 TABLE 9.3 pK a and Rh
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10.2 SECTION 10 10.4.6 Polyacrylate
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10.4 SECTION 10 10.2 ADDITIVES TO P
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10.6 SECTION 10 injection molding.
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10.8 SECTION 10 10.3 FORMULAS AND K
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10.10 SECTION 10 Key properties of
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10.12 SECTION 10 10.3.8 Fluorocarbo
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10.14 SECTION 10 10.3.11 Phenolics
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10.16 SECTION 10 The resin has the
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10.18 SECTION 10 10.3.19 Polyuretha
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10.20 SECTION 10 10.3.22 Sulfones B
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TABLE 10.2 Properties of Commercial
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10.58 SECTION 10 10.4 FORMULAS AND
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10.60 SECTION 10 10.4.8 Polychlorop
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10.62 SECTION 10 Styrene-butadiene
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10.5 CHEMICAL RESISTANCE TABLE 10.4
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10.6 GAS PERMEABILITY TABLE 10.5 Ga
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TABLE 10.5 Gas Permeability Constan
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TABLE 10.7 Constants ofFats and Oil
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TABLE 10.8 Constants ofWaxes Wax Me
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SECTION 11 PRACTICAL LABORATORY INF
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11.4 SECTION 11 TABLE 11.2 Molecula
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11.6 SECTION 11 A saturated aqueous
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11.8 SECTION 11 TABLE 11.6 Relative
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11.10 SECTION 11 11.3 BOILING POINT
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11.12 SECTION 11 TABLE 11.8 Organic
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11.14 SECTION 11 TABLE 11.9 Molecul
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11.4 SEPARATION METHODS TABLE 11.11
Page 1109 and 1110:
11.18 SECTION 11 TABLE 11.12 Solven
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11.20 SECTION 11 TABLE 11.12 Solven
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TABLE 11.13 McReynolds’ Constants
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TABLE 11.13 McReynolds’ Constants
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11.26 SECTION 11 11.4.1 McReynolds
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11.28 SECTION 11 11.4.2.2 Partition
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11.30 SECTION 11 FIGURE 11.2 Band a
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11.32 SECTION 11 11.4.3 Ion-Exchang
Page 1125 and 1126:
11.34 SECTION 11 TABLE 11.16 Guide
Page 1127 and 1128:
11.36 SECTION 11 TABLE 11.16 Guide
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11.38 SECTION 11 TABLE 11.18 Relati
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11.40 SECTION 11 distribution coeff
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11.42 SECTION 11 TABLE 11.19 Gravim
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11.68 SECTION 11 TABLE 11.20 Elemen
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11.70 SECTION 11 TABLE 11.22 Common
Page 1163 and 1164:
11.72 SECTION 11 TABLE 11.25 Tolera
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11.74 SECTION 11 TABLE 11.26 Heatin
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11.76 SECTION 11 TABLE 11.28 Titrim
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11.84 SECTION 11 appears becomes le
Page 1177 and 1178:
11.86 SECTION 11 TABLE 11.29 Equati
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11.88 SECTION 11 TABLE 11.29 Equati
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11.90 SECTION 11 The more stable th
Page 1183 and 1184:
11.92 SECTION 11 11.6.6.2.5 Buffer
Page 1185 and 1186:
11.94 SECTION 11 TABLE 11.30 Standa
Page 1187 and 1188:
TABLE 11.32 Properties and Applicat
Page 1189 and 1190:
11.98 SECTION 11 TABLE 11.36 Maskin
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11.100 SECTION 11 TABLE 11.37 Anion
Page 1193 and 1194:
11.102 SECTION 11 TABLE 11.39 Amino
Page 1195 and 1196:
11.104 SECTION 11 TABLE 11.44 Facto
Page 1197 and 1198:
11.106 SECTION 11 11.7 LABORATORY S
Page 1199 and 1200:
11.108 SECTION 11 TABLE 11.48 Stand
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11.110 SECTION 11 Alizarin yellow G
Page 1203 and 1204:
11.112 SECTION 11 Bromchlorophenol
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11.114 SECTION 11 p-Ethoxychrysoidi
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11.116 SECTION 11 Mercurous nitrate
Page 1209 and 1210:
11.118 SECTION 11 Potassium carbona
Page 1211 and 1212:
11.120 SECTION 11 until the ammoniu
Page 1213 and 1214:
11.122 SECTION 11 TABLE 11.49 TLV C
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11.130 SECTION 11 TABLE 11.50 Chemi
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Page 1227 and 1228:
Page 1229 and 1230:
11.138 SECTION 11 of water which is
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TABLE 11.55 Thermoelectric Values i
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TABLE 11.56 Type B Thermocouples: P
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TABLE 11.58 Type J Thermocouples: I
Page 1237 and 1238:
TABLE 11.60 Type N Thermocouples: N
Page 1239 and 1240:
TABLE 11.62 Type S Thermocouples: P
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11.150 SECTION 11 11.11 CORRECTION
Page 1243 and 1244:
Index Terms Links 2 Acid-base indic
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Index Terms Links 4 Alkynes, nomenc
Page 1247 and 1248:
Index Terms Links 6 Aurintricarboxy
Page 1249 and 1250:
Index Terms Links 8 Boron-11 chemic
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Index Terms Links 10 Cellulose acet
Page 1253 and 1254:
Index Terms Links 12 Collective ino
Page 1255 and 1256:
Index Terms Links 14 Degree Fahrenh
Page 1257 and 1258:
Index Terms Links 16 Electrical res
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Index Terms Links 18 Equivalent wei
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Index Terms Links 20 Fluorocarbon p
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Index Terms Links 22 Halogenated hy
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Index Terms Links 24 Impact strengt
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Index Terms Links 26 Kα 1 lines, m
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Index Terms Links 28 Melmine phenol
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Index Terms Links 30 Neon-neon bond
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Index Terms Links 32 One-tailed tes
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Index Terms Links 34 Physical chemi
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Index Terms Links 36 Polyolefin the
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Index Terms Links 38 Pyridine: bina
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Index Terms Links 40 Rho values: fo
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Index Terms Links 42 Single-bond ra
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Index Terms Links 44 Stereoisomers
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Index Terms Links 46 Tension, aqueo
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Index Terms Links 48 Triethylenetet
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Index Terms Links 50 Water (Cont.)
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