preface to fifteenth edition

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ELECTROLYTES, EMF, AND CHEMICAL EQUILIBRIUM 8.15 TABLE 8.6 Solubility Product Constants (Continued) Compound Formula pK sp K sp iodide AgI 16.07 8.52 10 17 molybdate Ag 2 MoO 4 11.55 2.8 10 12 nitrite AgNO 2 3.22 6.0 10 4 oxalate Ag 2 C 2 O 4 11.27 5.40 10 12 phosphate Ag 3 PO 4 16.05 8.89 10 17 quinaldate AgL 16.89 1.3 10 17 perrhenate AgReO 4 4.10 8.0 10 5 selenate Ag 2 SeO 4 7.25 5.7 10 8 selenite Ag 2 SeO 3 15.00 1.0 10 15 selenocyanate AgSeCN 15.40 4.0 10 16 sulfate Ag 2 SO 4 4.92 1.20 10 5 sulfite Ag 2 SO 3 13.82 1.50 10 14 sulfide Ag 2 S 49.20 6.3 10 50 thiocyanate AgSCN 11.99 1.03 10 12 vanadate AgVO 3 6.3 5 10 7 tungstate Ag 2 WO 4 11.26 5.5 10 12 Sodium ammonium cobaltinitrite Na(NH 4 ) 2 [Co(NO 2 ) 6 ] 10.66 2.2 10 11 antimonate Na[Sb(OH) 6 ] 7.4 4 10 8 hexafluoroaluminate Na 2 [AlF 6 ] 9.39 4.0 10 10 uranyl arsenate NaUO 2 AsO 4 21.87 1.3 10 22 Strontium arsenate Sr 3 (AsO 4 ) 2 18.37 4.29 10 19 carbonate SrCO 3 9.25 5.60 10 10 chromate SrCrO 4 4.65 2.2 10 5 fluoride SrF 2 8.36 4.33 10 9 iodate Sr(IO 3 ) 2 6.94 1.14 10 7 iodate hydrate Sr(IO 3 ) 2·H 2 O 6.42 3.77 10 7 molybdate SrMoO 4 6.7 2 10 7 niobate Sr(NbO 3 ) 2 17.38 4.2 10 18 oxalate hydrate SrC 2 O 4·H 2 O 6.80 1.6 10 7 phosphate Sr 3 (PO 4 ) 2 27.39 4.0 10 28 8-quinolinolate SrL 2 9.3 5 10 10 selenate SrSeO 4 3.09 8.1 10 4 selenite SrSeO 3 5.74 1.8 10 6 sulfate SrSO 4 6.46 3.44 10 7 sulfite SrSO 3 7.4 4 10 8 tungstate SrWO 4 9.77 1.7 10 10 Terbium hydroxide Tb(OH) 3 21.70 2.0 10 22 Tellurium hydroxide Te(OH) 4 53.52 3.0 10 54 Thallium(I) azide TlN 3 3.66 2.2 10 4 bromate TlBrO 3 4.96 1.10 10 5 bromide TlBr 5.43 3.71 10 6 chloride TlCl 3.73 1.86 10 4 chromate Tl 2 CrO 4 12.06 8.67 10 13 ferrocyanide dihydrate Tl 4 [Fe(CN) 6 ]·2H 2 O 9.3 5 10 10 hexachloroplatinate Tl 2 [PtCl 6 ] 11.40 4.0 10 12 iodate TlIO 3 5.51 3.12 10 6 iodide TlI 7.26 5.54 10 8
8.16 SECTION 8 TABLE 8.6 Solubility Product Constants (Continued) Compound Formula pK sp K sp oxalate Tl 2 C 2 O 4 3.7 2 10 4 selenate Tl 2 SeO 4 4.00 1.0 10 4 selenite Tl 2 SeO 3 38.7 2 10 39 sulfide Tl 2 S 20.30 5.0 10 21 thiocyanate TlSCN 3.80 1.57 10 4 Thallium(III) hydroxide Tl(OH) 3 43.77 1.68 10 44 8-quinolinolate TlL 3 32.40 4.0 10 33 Thorium hydrogen phosphate Th(HPO 4 ) 2 20 1 10 20 hydroxide Th(OH) 4 44.40 4.0 10 45 iodate Th(IO 3 ) 4 14.60 2.5 10 15 oxalate Th(C 2 O 4 ) 2 22 1 10 22 phosphate Th 3 (PO 4 ) 4 78.60 2.5 10 79 Thullium hydroxide Tm(OH) 3 23.48 3.3 10 24 Tin (II) hydroxide Sn(OH) 2 27.26 5.45 10 28 (IV) hydroxide Sn(OH) 4 56 1 10 56 (II) sulfide SnS 25.00 1.0 10 25 Titanium (III) hydroxide Ti(OH) 3 40 1 10 40 (IV) oxide hydroxide TiO(OH) 2 29 1 10 29 Uranium(IV) fluoride 2.5-water UF 4·2.5H 2 O 21.24 5.7 10 22 Uranyl(VI)(2) carbonate UO 2 CO 3 11.73 1.8 10 12 ferrocyanide UO 2 [Fe(CN) 6 ] 13.15 7.1 10 14 hydrogen arsenate UO 2 HAsO 4 10.50 3.2 10 11 hydrogen phosphate UO 2 HPO 4 10.67 2.1 10 11 hydroxide UO 2 (OH) 2 21.95 1.1 10 22 iodate hydrate UO 2 (IO 3 ) 2·H 2 O 7.50 3.2 10 8 oxalate trihydrate UO 2 C 2 O 4·3H 2 O 3.7 2 10 4 phosphate (UO 2 ) 3 (PO 4 ) 2 46.7 2 10 47 sulfite UO 2 SO 3 8.58 2.6 10 9 thiocyanate (UO 2 )(SCN) 2 3.4 4 10 4 Vanadium (IV) hydroxide VO(OH) 2 22.13 5.9 10 23 (III) phosphate (VO 2 ) 3 PO 4 24.1 8 10 25 Ytterbium hydroxide Yt(OH) 3 23.60 2.5 10 24 Yttrium carbonate Y 2 (CO 3 ) 3 2.99 1.03 10 3 fluoride YF 3 20.06 8.62 10 21 hydroxide Y(OH) 3 22.00 1.00 10 22 iodate Y(IO 3 ) 3 9.95 1.12 10 10 oxalate Y 2 (C 2 O 4 ) 3 28.28 5.3 10 29 Zinc anthranilate ZnL 2 9.23 5.9 10 10 arsenate Zn 3 (AsO 4 ) 2 27.55 2.8 10 28 borate hydrate Zn(BO 2 ) 2·H 2 O 10.18 6.6 10 11 carbonate ZnCO 3 9.94 1.46 10 10 ferrocyanide Zn 2 [Fe(CN) 6 ] 15.40 4.0 10 15
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LANGE'S HANDBOOK OF CHEMISTRY John
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Grateful acknowledgment is hereby m
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PREFACE TO FIFTEENTH EDITION This n
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PREFACE TO FIFTEENTH EDITION ix inv
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xii PREFACE TO FOURTEENTH EDITION l
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PREFACE TO FIRST EDITION This book
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For the detailed contents of any se
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1.2 SECTION 1 is derived from the G
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1.4 SECTION 1 rather than methylide
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1.6 SECTION 1 Styrene Toluene Xylen
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1.8 SECTION 1 TABLE 1.2 Fused Polyc
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1.10 SECTION 1 1.1.1.6 Bridged Hydr
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1.12 SECTION 1 TABLE 1.4 Suffixes f
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1.14 SECTION 1 TABLE 1.5 Trivial Na
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1.16 SECTION 1 TABLE 1.6 Trivial Na
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1.18 SECTION 1 Selection of the pri
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1.20 SECTION 1 attached to one anot
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1.22 SECTION 1 When side chains of
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1.24 SECTION 1 heterocyclic structu
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1.26 SECTION 1 Bivalent radicals of
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1.28 SECTION 1 Complex linear polya
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1.30 SECTION 1 TABLE 1.11 Names of
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1.32 SECTION 1 hydroxyamino- to the
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1.34 SECTION 1 may be named (1) by
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1.36 SECTION 1 Examples are methyl
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1.38 SECTION 1 tuted acid, respecti
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1.40 SECTION 1 FIGURE 1.2 Newman pr
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1.42 SECTION 1 from the ring are kn
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1.44 SECTION 1 FIGURE 1.11 Two isom
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1.46 SECTION 1 Chiral Center. The c
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1.48 SECTION 1 FIGURE 1.15 Isomers
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1.50 SECTION 1 entries to bring tog
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1.52 SECTION 1 TABLE 1.13 Names and
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1.60 SECTION 1 TABLE 1.14 Empirical
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2.2 SECTION 2 2.3.6 Student’s Dis
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2.4 SECTION 2 TABLE 2.1 Fundamental
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2.6 SECTION 2 TABLE 2.1 Fundamental
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2.8 SECTION 2 TABLE 2.2 Physical an
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2.10 SECTION 2 TABLE 2.2 Physical a
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2.24 SECTION 2 TABLE 2.3 Mathematic
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2.26 SECTION 2 TABLE 2.6 Abbreviati
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2.36 SECTION 2 TABLE 2.7 Conversion
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2.54 SECTION 2 TABLE 2.8 Temperatur
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2.66 SECTION 2 2.1.1 Conversion of
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2.68 SECTION 2 Oleometer. A hydrome
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2.70 SECTION 2 Example 3. 25 1.2500
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2.72 SECTION 2 TABLE 2.9 Barometer
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2.74 SECTION 2 TABLE 2.9 Barometer
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2.76 SECTION 2 TABLE 2.10 Barometri
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2.78 SECTION 2 TABLE 2.12 Reduction
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2.80 SECTION 2 TABLE 2.12 Reduction
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2.82 SECTION 2 TABLE 2.13 Viscosity
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2.84 SECTION 2 TABLE 2.14 Conversio
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2.86 SECTION 2 TABLE 2.15 Hydromete
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2.88 SECTION 2 TABLE 2.17 Correctio
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2.90 SECTION 2 TABLE 2.18 Pressure
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2.96 SECTION 2 TABLE 2.20 Values of
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2.98 SECTION 2 TABLE 2.21 Transmitt
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2.100 SECTION 2 TABLE 2.21 Transmit
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2.102 SECTION 2 2.2 MATHEMATICAL TA
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2.104 SECTION 2 TABLE 2.23 Derivati
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2.106 SECTION 2 TABLE 2.24 Integral
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2.108 SECTION 2 TABLE 2.24 Integral
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2.110 SECTION 2 Regular Polygon of
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2.112 SECTION 2 A h[0.4(y y ) 1.
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2.114 SECTION 2 2.2.3.1 Signs of th
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2.116 SECTION 2 x2 x3 x4 x5 ln(1 x
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2.118 SECTION 2 2.3.2 Errors in Qua
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2.120 SECTION 2 The breadth or spre
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2.122 SECTION 2 TABLE 2.26b Areas U
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2.124 SECTION 2 The distribution of
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2.126 SECTION 2 Should there be mor
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2.128 SECTION 2 Example 10 Six samp
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2.130 SECTION 2 2.3.9 The F Statist
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TABLE 2.29 F Distribution (Continue
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2.134 SECTION 2 mathematical treatm
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2.136 SECTION 2 The confidence limi
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2.138 SECTION 2 situation where rel
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3.2 SECTION 3 The alphabetical orde
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3.4 SECTION 3 When it is required t
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3.6 SECTION 3 PO phosphoryl SeO sel
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3.8 SECTION 3 3.1.5 Acids 3.1.5.1 A
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3.10 SECTION 3 3.1.6.6 Multiplicati
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3.12 SECTION 3 3.2 PHYSICAL PROPERT
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TABLE 3.2 Physical Constants of Ino
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3.62 SECTION 3 TABLE 3.3 Synonyms a
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SECTION 4 PROPERTIES OF ATOMS, RADI
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4.3 Fermium Fm 100 [Rn] 5f 12 7s 2
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Silver (argentum) Ag 47 [Kr] 4d 10
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PROPERTIES OF ATOMS,RADICALS,AND BO
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PROPERTIES OF ATOMS, RADICALS, AND
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SECTION 5 PHYSICAL PROPERTIES 5.1 S
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PHYSICAL PROPERTIES 5.3 5.1 SOLUBIL
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TABLE 5.1 Solubility of Gases in Wa
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TABLE 5.1 Solubility of Gases in Wa
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TABLE 5.2 Solubilities of Inorganic
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formateBa(CHO 2 ) 2 26.2 28.0 29.9
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(III) sulfateCe 2 (SO 4 ) 3 ·9H 2
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iodidePbI 2 0.044 0.056 0.069 0.090
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Nickel sulfateNiSO 4 ·6H 2 O (pale
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Praseodymium bromatePr(BrO 3 ) 3 55
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formate NaCHO 2 43.9 62.5 81.2 102
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Uranyl nitrate UO 2 (NO 3 ) 2 98 10
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PHYSICAL PROPERTIES 5.25 TABLE 5.3
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PHYSICAL PROPERTIES 5.57 5.3 BOILIN
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TABLE 5.12 Ternary Azeotropic Mixtu
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TABLE 5.12 Ternary Azeotropic Mixtu
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PHYSICAL PROPERTIES 5.83 5.4 FREEZI
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PHYSICAL PROPERTIES 5.87 5.5 DENSIT
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PHYSICAL PROPERTIES 5.89 dt Dt P
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PHYSICAL PROPERTIES 5.135 5.6.1 Ref
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PHYSICAL PROPERTIES 5.137 where the
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PHYSICAL PROPERTIES 5.139 5.7 COMBU
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Temperature, C Substance 40 20 0 20
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PHYSICAL PROPERTIES 5.171 This equa
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SECTION 6 THERMODYNAMIC PROPERTIES
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THERMODYNAMICPROPERTIES 6.3 6.1.1.2
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THERMODYNAMICPROPERTIES 6.5 A gener
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THERMODYNAMICPROPERTIES 6.7 TABLE 6
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THERMODYNAMICPROPERTIES 6.9 TABLE 6
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THERMODYNAMICPROPERTIES 6.11 TABLE
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THERMODYNAMIC PROPERTIES 6.21 TABLE
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THERMODYNAMIC PROPERTIES 6.101 TABL
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THERMODYNAMIC PROPERTIES 6.143 The
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SECTION 7 SPECTROSCOPY 7.1 X-RAY ME
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SPECTROSCOPY 7.3 TABLE 7.1 Waveleng
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SPECTROSCOPY 7.9 TABLE 7.3 Critical
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SPECTROSCOPY 7.11 TABLE 7.4 X-Ray E
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SPECTROSCOPY 7.13 Emission line K 1
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SPECTROSCOPY 7.15 TABLE 7.7 Analyzi
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SPECTROSCOPY 7.17 TABLE 7.8 Mass Ab
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SPECTROSCOPY 7.19 TABLE 7.9 Electro
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SPECTROSCOPY 7.21 TABLE 7.11 Absorp
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SPECTROSCOPY 7.23 TABLE 7.13 Solven
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SPECTROSCOPY 7.25 7.3 FLUORESCENCE
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SPECTROSCOPY 7.27 TABLE 7.16 Fluore
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SPECTROSCOPY 7.29 TABLE 7.18 Detect
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SPECTROSCOPY 7.35 TABLE 7.19 Sensit
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SPECTROSCOPY 7.37 TABLE 7.19 Sensit
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SPECTROSCOPY 7.39 In terms of m ,
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SPECTROSCOPY 7.41 The ionization co
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SPECTROSCOPY 7.67 TABLE 7.28 Infrar
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7.69
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SPECTROSCOPY 7.71 7.6 RAMAN SPECTRO
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SPECTROSCOPY 7.73 TABLE 7.30 Raman
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SPECTROSCOPY 7.89 7.7 NUCLEAR MAGNE
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SPECTROSCOPY 7.91 TABLE 7.41 Nuclea
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SPECTROSCOPY 7.93 TABLE 7.42 Proton
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SPECTROSCOPY 7.95 TABLE 7.44 Estima
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SPECTROSCOPY 7.97 TABLE 7.46 Proton
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SPECTROSCOPY 7.99 TABLE 7.48 Solven
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SPECTROSCOPY 7.101 TABLE 7.49 Carbo
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Page 818 and 819: SPECTROSCOPY 7.115 TABLE 7.64 Nitro
Page 820 and 821: SPECTROSCOPY 7.117 TABLE 7.69 Fluor
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Page 828 and 829: SPECTROSCOPY 7.125 when z 3 and y
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Page 832 and 833: SPECTROSCOPY 7.129 TABLE 7.76 Conde
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ELECTROLYTES, EMF, AND CHEMICAL EQU
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TABLE 8.9 Selected Equilibrium Cons
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8.75 3-tert-Butylbenzoic acid (0) 4
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4-Hydroxyproline (1) 1.900 1C 1.850
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N-Propionylglycine (1) 3.728 3.723
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TABLE 8.14 National Bureau of Stand
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1 part 0.1% neutral red in alc. * V
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3,3-Dimethoxybenzidine dihydrochlor
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TABLE 8.35 Equivalent Conductivitie
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KCl 127.3 124.4 122.4 115.8 112.0 1
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NaIO 3 75.2 72.6 70.9 64.4 60.5 1
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9.2 SECTION 9 9.1 LINEAR FREE ENERG
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9.4 SECTION 9 TABLE 9.1 Hammett and
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9.6 SECTION 9 TABLE 9.1 Hammett and
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9.8 SECTION 9 TABLE 9.3 pK a and Rh
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10.2 SECTION 10 10.4.6 Polyacrylate
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10.4 SECTION 10 10.2 ADDITIVES TO P
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10.6 SECTION 10 injection molding.
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10.8 SECTION 10 10.3 FORMULAS AND K
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10.10 SECTION 10 Key properties of
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10.12 SECTION 10 10.3.8 Fluorocarbo
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10.14 SECTION 10 10.3.11 Phenolics
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10.16 SECTION 10 The resin has the
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10.18 SECTION 10 10.3.19 Polyuretha
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10.20 SECTION 10 10.3.22 Sulfones B
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TABLE 10.2 Properties of Commercial
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10.58 SECTION 10 10.4 FORMULAS AND
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10.60 SECTION 10 10.4.8 Polychlorop
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10.62 SECTION 10 Styrene-butadiene
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10.5 CHEMICAL RESISTANCE TABLE 10.4
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10.6 GAS PERMEABILITY TABLE 10.5 Ga
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TABLE 10.5 Gas Permeability Constan
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TABLE 10.7 Constants ofFats and Oil
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TABLE 10.8 Constants ofWaxes Wax Me
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SECTION 11 PRACTICAL LABORATORY INF
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11.4 SECTION 11 TABLE 11.2 Molecula
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11.6 SECTION 11 A saturated aqueous
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11.8 SECTION 11 TABLE 11.6 Relative
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11.10 SECTION 11 11.3 BOILING POINT
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11.12 SECTION 11 TABLE 11.8 Organic
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11.14 SECTION 11 TABLE 11.9 Molecul
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11.4 SEPARATION METHODS TABLE 11.11
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11.18 SECTION 11 TABLE 11.12 Solven
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11.20 SECTION 11 TABLE 11.12 Solven
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TABLE 11.13 McReynolds’ Constants
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TABLE 11.13 McReynolds’ Constants
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11.26 SECTION 11 11.4.1 McReynolds
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11.28 SECTION 11 11.4.2.2 Partition
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11.30 SECTION 11 FIGURE 11.2 Band a
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11.32 SECTION 11 11.4.3 Ion-Exchang
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11.34 SECTION 11 TABLE 11.16 Guide
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11.36 SECTION 11 TABLE 11.16 Guide
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11.38 SECTION 11 TABLE 11.18 Relati
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11.40 SECTION 11 distribution coeff
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11.42 SECTION 11 TABLE 11.19 Gravim
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11.68 SECTION 11 TABLE 11.20 Elemen
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11.70 SECTION 11 TABLE 11.22 Common
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11.72 SECTION 11 TABLE 11.25 Tolera
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11.74 SECTION 11 TABLE 11.26 Heatin
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11.76 SECTION 11 TABLE 11.28 Titrim
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11.84 SECTION 11 appears becomes le
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11.86 SECTION 11 TABLE 11.29 Equati
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11.88 SECTION 11 TABLE 11.29 Equati
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11.90 SECTION 11 The more stable th
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11.92 SECTION 11 11.6.6.2.5 Buffer
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11.94 SECTION 11 TABLE 11.30 Standa
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TABLE 11.32 Properties and Applicat
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11.98 SECTION 11 TABLE 11.36 Maskin
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11.100 SECTION 11 TABLE 11.37 Anion
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11.102 SECTION 11 TABLE 11.39 Amino
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11.104 SECTION 11 TABLE 11.44 Facto
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11.106 SECTION 11 11.7 LABORATORY S
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11.108 SECTION 11 TABLE 11.48 Stand
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11.110 SECTION 11 Alizarin yellow G
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11.112 SECTION 11 Bromchlorophenol
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11.114 SECTION 11 p-Ethoxychrysoidi
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11.116 SECTION 11 Mercurous nitrate
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11.118 SECTION 11 Potassium carbona
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11.120 SECTION 11 until the ammoniu
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11.122 SECTION 11 TABLE 11.49 TLV C
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11.130 SECTION 11 TABLE 11.50 Chemi
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11.138 SECTION 11 of water which is
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TABLE 11.55 Thermoelectric Values i
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TABLE 11.56 Type B Thermocouples: P
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TABLE 11.58 Type J Thermocouples: I
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TABLE 11.60 Type N Thermocouples: N
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TABLE 11.62 Type S Thermocouples: P
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11.150 SECTION 11 11.11 CORRECTION
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Index Terms Links 2 Acid-base indic
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Index Terms Links 4 Alkynes, nomenc
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Index Terms Links 6 Aurintricarboxy
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Index Terms Links 8 Boron-11 chemic
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Index Terms Links 10 Cellulose acet
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Index Terms Links 12 Collective ino
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Index Terms Links 14 Degree Fahrenh
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Index Terms Links 16 Electrical res
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Index Terms Links 18 Equivalent wei
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Index Terms Links 20 Fluorocarbon p
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Index Terms Links 22 Halogenated hy
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Index Terms Links 24 Impact strengt
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Index Terms Links 26 Kα 1 lines, m
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Index Terms Links 28 Melmine phenol
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Index Terms Links 30 Neon-neon bond
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Index Terms Links 32 One-tailed tes
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Index Terms Links 34 Physical chemi
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Index Terms Links 36 Polyolefin the
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Index Terms Links 38 Pyridine: bina
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Index Terms Links 40 Rho values: fo
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Index Terms Links 42 Single-bond ra
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Index Terms Links 44 Stereoisomers
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Index Terms Links 46 Tension, aqueo
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Index Terms Links 48 Triethylenetet
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Index Terms Links 50 Water (Cont.)
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