preface to fifteenth edition

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THERMODYNAMIC PROPERTIES 6.147 TABLE 6.5 Critical Properties (Continued) Substance T c , C P c , atm P c ,MPa V c ,cm 3 ·mol 1 c ,g·cm 3 trans-Difluorodiazine 13 55 5.57 1,1-Difluoroethane 113.6 44.4 4.50 181 0.365 1,1-Difluoroethylene 29.8 44.0 4.46 154 0.417 Dihexyl ether 384 18 1.82 720 0.259 Dihydrogen disulfide 299 58.3 5.91 Dihydrogen heptasulfide 742 33 3.34 Dihydrogen hexasulfide 707 36 3.65 Dihydrogen octasulfide 767 32 3.24 Dihydrogen pentasulfide 657 38.4 3.89 Dihydrogen tetrasulfide 582 43.1 4.37 Dihydrogen trisulfide 465 50.6 5.13 Diisopentyl sulfide 391 Diisopropyl ether 227.17 27.9 2.832 386 0.265 1,2-Dimethoxyethane 263 38.2 3.87 271 0.333 Dimethoxymethane 242.1 44.2 4.48 N,N-Dimethylacetamide 364 38.7 3.92 Dimethylamine 164.07 52.7 5.340 187 0.241 N,N-Dimethylaniline 414 35.8 3.63 2,2-Dimethylbutane 215.7 30.49 3.090 359 0.240 2,3-Dimethylbutane 499.9 30.90 3.131 358 0.241 3,3-Dimethyl-2-butanone 289.8 2,3-Dimethyl-1-butene 228 32.0 3.24 343 0.245 3,3-Dimethyl-1-butene 217 32.1 3.25 340 0.248 2,3-Dimethyl-2-butene 250.9 33.2 3.36 351 0.240 1,1-Dimethylcyclohexane 318 29.3 2.97 416 0.378 cis-1,2-Dimethylcyclohexane 333.0 29.0 2.94 460 0.244 trans-1,2-Dimethylcyclohexane 323.0 29.3 2.97 460 0.244 cis-1,3-Dimethylcyclohexane 317.9 29.3 2.97 450 0.249 trans-1,3-Dimethylcyclohexane 325 29.3 2.97 460 0.244 cis-1,4-Dimethylcyclohexane 325.0 29.0 2.94 460 0.244 trans-1,4-Dimethylcyclohexane 317.0 29.0 2.94 459 0.249 1,1-Dimethylcyclopentane 274 34.0 3.44 360 0.273 cis-1,2-Dimethylcyclopentane 291.7 34.0 3.44 368 0.267 trans-1,2-Dimethylcyclopentane 277.2 34.0 3.44 362 0.271 cis-1,3-Dimethylcyclopentane 318.9 Dimethyl disulfide 59.5 Dimethyl ether 126.9 53.0 5.37 190 0.242 N,N-Dimethylformamide 376.5 51.5 5.22 262 0.279 2,2-Dimethylheptane 303.7 23.19 2.350 519 0.247 2,2-Dimethylhexane 276.8 25.0 2.529 478 0.239 2,3-Dimethylhexane 290.4 25.94 2.628 468 0.244 2,4-Dimethylhexane 280.5 25.22 2.556 472 0.242 2,5-Dimethylhexane 277.0 24.54 2.487 482 0.237 3,3-Dimethylhexane 289.0 26.19 2.654 443 0.258 3,4-Dimethylhexane 295.8 26.57 2.692 466 0.245 1,1-Dimethylhydrazine 250 53.6 5.43 230 0.261 2,4-Dimethyl-3-isopentane 341.3 23.1 2.34 521 0.273 2,3-Dimethyloctane 340.1 21.6 2.19 567 0.251 2,4-Dimethyloctane 326.3 21.1 2.14 566 0.251 2,5-Dimethyloctane 330 21.2 2.15 569 0.250 2,6-Dimethyloctane 330 21.1 2.15 576 0.247 2,7-Dimethyloctane 329.8 20.7 2.10 590 0.241
6.148 SECTION 6 TABLE 6.5 Critical Properties (Continued) Substance T c , C P c , atm P c ,MPa V c ,cm 3 ·mol 1 c ,g·cm 3 3,3-Dimethyloctane 339 21.9 2.22 557 0.255 3,4-Dimethyloctane 341 22.1 2.24 551 0.258 3,5-Dimethyloctane 333.2 21.6 2.19 555 0.256 3,6-Dimethyloctane 335.2 21.6 2.19 562 0.253 4,5-Dimethyloctane 333.8 21.8 2.21 548 0.260 4,5-Dimethyloctane 339.1 22.1 2.24 546 0.261 Dimethyl oxalate 355 39.2 3.97 2,2-Dimethylpentane 247.4 27.4 2.773 416 0.241 2,3-Dimethylpentane 264.3 28.70 2.908 393 0.255 2,4-Dimethylpentane 246.7 27.01 2.737 418 0.240 3,3-Dimethylpentane 263.3 29.07 2.946 414 0.242 2,3-Dimethylphenol 449.7 48 4.86 470 0.26 2,4-Dimethylphenol 434.5 43 4.36 509 0.24 2,5-Dimethylphenol 433.8 48 4.86 470 0.26 2,6-Dimethylphenol 427.9 42 4.26 509 0.24 3,4-Dimethylphenol 456.7 49 4.96 552 0.27 3,5-Dimethylphenol 442.5 36 3.65 611 0.25 2,2-Dimethylpropane 160.7 31.55 3.197 307 0.238 2,2-Dimethyl-1-propanol 276 39 3.95 319 2,3-Dimethylpyridine 382.3 2,4-Dimethylpyridine 373.9 2,5-Dimethylpyridine 371 2,6-Dimethylpyridine 350.7 316 0.339 3,4-Dimethylpyridine 410.7 3,5-Dimethylpyridine 394.1 Dimethyl sulfide 229.9 54.6 5.53 201 0.309 N,N-Dimethyl-1,2-<strong>to</strong>luidine 395 30.8 3.12 1,4-Dioxane 314 51.5 5.21 238 0.370 Diphenyl ether 493.7 31 3.14 Diphenylmethane 494 29.4 2.98 Dipropylamine 282.7 35.8 3.63 407 0.249 Dipropyl ether 257.5 29.91 3.028 Docosafluorodecane 269 14.3 1.45 Dodecafluorocyclohexane 184.1 24 2.43 Dodecafluorocyclohexene 188.7 Dodecafluoro-1-hexene 181.3 Dodecafluoropentane 149 20.1 2.03 Dodecane 385 18.0 1.82 754 0.226 1-Dodecanol 405.9 19 1.92 718 0.260 1-Dodecene 384.5 18.3 1.85 Dodecylbenzene 501 15.6 1.58 1000 0.246 Dodecylcyclopentane 477 12.8 1.30 Ethane 32.3 48.2 4.90 148 0.203 1,2-Ethanediamine 319.8 62.1 6.29 206 0.292 1,2-Ethanediol 445 76 7.7 186 0.334 Ethanethiol 225.5 54.2 5.49 207 0.300 Ethanol 240.9 60.57 6.137 167 0.276 Ethoxybenzene 374.0 33.8 3.42 Ethyl acetate 250.2 38.31 3.882 286 0.308 Ethyl ace<strong>to</strong>acetate 400 Ethyl acrylate 279 37.0 3.75 320 0.313 Ethylamine 183 55.5 5.62 182 0.248 Ethylbenzene 344.00 35.61 3.609 374 0.284
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LANGE'S HANDBOOK OF CHEMISTRY John
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Grateful acknowledgment is hereby m
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PREFACE TO FIFTEENTH EDITION This n
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PREFACE TO FIFTEENTH EDITION ix inv
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xii PREFACE TO FOURTEENTH EDITION l
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PREFACE TO FIRST EDITION This book
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For the detailed contents of any se
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1.2 SECTION 1 is derived from the G
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1.4 SECTION 1 rather than methylide
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1.6 SECTION 1 Styrene Toluene Xylen
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1.8 SECTION 1 TABLE 1.2 Fused Polyc
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1.10 SECTION 1 1.1.1.6 Bridged Hydr
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1.12 SECTION 1 TABLE 1.4 Suffixes f
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1.14 SECTION 1 TABLE 1.5 Trivial Na
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1.16 SECTION 1 TABLE 1.6 Trivial Na
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1.18 SECTION 1 Selection of the pri
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1.20 SECTION 1 attached to one anot
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1.22 SECTION 1 When side chains of
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1.24 SECTION 1 heterocyclic structu
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1.26 SECTION 1 Bivalent radicals of
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1.28 SECTION 1 Complex linear polya
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1.30 SECTION 1 TABLE 1.11 Names of
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1.32 SECTION 1 hydroxyamino- to the
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1.34 SECTION 1 may be named (1) by
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1.36 SECTION 1 Examples are methyl
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1.38 SECTION 1 tuted acid, respecti
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1.40 SECTION 1 FIGURE 1.2 Newman pr
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1.42 SECTION 1 from the ring are kn
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1.44 SECTION 1 FIGURE 1.11 Two isom
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1.46 SECTION 1 Chiral Center. The c
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1.48 SECTION 1 FIGURE 1.15 Isomers
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1.50 SECTION 1 entries to bring tog
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1.52 SECTION 1 TABLE 1.13 Names and
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1.60 SECTION 1 TABLE 1.14 Empirical
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2.2 SECTION 2 2.3.6 Student’s Dis
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2.4 SECTION 2 TABLE 2.1 Fundamental
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2.6 SECTION 2 TABLE 2.1 Fundamental
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2.8 SECTION 2 TABLE 2.2 Physical an
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2.10 SECTION 2 TABLE 2.2 Physical a
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2.24 SECTION 2 TABLE 2.3 Mathematic
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2.26 SECTION 2 TABLE 2.6 Abbreviati
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2.36 SECTION 2 TABLE 2.7 Conversion
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2.54 SECTION 2 TABLE 2.8 Temperatur
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2.66 SECTION 2 2.1.1 Conversion of
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2.68 SECTION 2 Oleometer. A hydrome
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2.70 SECTION 2 Example 3. 25 1.2500
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2.72 SECTION 2 TABLE 2.9 Barometer
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2.74 SECTION 2 TABLE 2.9 Barometer
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2.76 SECTION 2 TABLE 2.10 Barometri
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2.78 SECTION 2 TABLE 2.12 Reduction
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2.80 SECTION 2 TABLE 2.12 Reduction
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2.82 SECTION 2 TABLE 2.13 Viscosity
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2.84 SECTION 2 TABLE 2.14 Conversio
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2.86 SECTION 2 TABLE 2.15 Hydromete
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2.88 SECTION 2 TABLE 2.17 Correctio
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2.90 SECTION 2 TABLE 2.18 Pressure
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2.96 SECTION 2 TABLE 2.20 Values of
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2.98 SECTION 2 TABLE 2.21 Transmitt
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2.100 SECTION 2 TABLE 2.21 Transmit
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2.102 SECTION 2 2.2 MATHEMATICAL TA
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2.104 SECTION 2 TABLE 2.23 Derivati
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2.106 SECTION 2 TABLE 2.24 Integral
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2.108 SECTION 2 TABLE 2.24 Integral
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2.110 SECTION 2 Regular Polygon of
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2.112 SECTION 2 A h[0.4(y y ) 1.
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2.114 SECTION 2 2.2.3.1 Signs of th
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2.116 SECTION 2 x2 x3 x4 x5 ln(1 x
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2.118 SECTION 2 2.3.2 Errors in Qua
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2.120 SECTION 2 The breadth or spre
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2.122 SECTION 2 TABLE 2.26b Areas U
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2.124 SECTION 2 The distribution of
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2.126 SECTION 2 Should there be mor
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2.128 SECTION 2 Example 10 Six samp
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2.130 SECTION 2 2.3.9 The F Statist
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TABLE 2.29 F Distribution (Continue
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2.134 SECTION 2 mathematical treatm
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2.136 SECTION 2 The confidence limi
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2.138 SECTION 2 situation where rel
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3.2 SECTION 3 The alphabetical orde
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3.4 SECTION 3 When it is required t
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3.6 SECTION 3 PO phosphoryl SeO sel
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3.8 SECTION 3 3.1.5 Acids 3.1.5.1 A
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3.10 SECTION 3 3.1.6.6 Multiplicati
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3.12 SECTION 3 3.2 PHYSICAL PROPERT
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TABLE 3.2 Physical Constants of Ino
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3.62 SECTION 3 TABLE 3.3 Synonyms a
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SECTION 4 PROPERTIES OF ATOMS, RADI
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4.3 Fermium Fm 100 [Rn] 5f 12 7s 2
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Silver (argentum) Ag 47 [Kr] 4d 10
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PROPERTIES OF ATOMS,RADICALS,AND BO
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PROPERTIES OF ATOMS, RADICALS, AND
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SECTION 5 PHYSICAL PROPERTIES 5.1 S
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PHYSICAL PROPERTIES 5.3 5.1 SOLUBIL
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TABLE 5.1 Solubility of Gases in Wa
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TABLE 5.1 Solubility of Gases in Wa
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TABLE 5.2 Solubilities of Inorganic
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formateBa(CHO 2 ) 2 26.2 28.0 29.9
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(III) sulfateCe 2 (SO 4 ) 3 ·9H 2
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iodidePbI 2 0.044 0.056 0.069 0.090
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Nickel sulfateNiSO 4 ·6H 2 O (pale
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Praseodymium bromatePr(BrO 3 ) 3 55
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formate NaCHO 2 43.9 62.5 81.2 102
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Uranyl nitrate UO 2 (NO 3 ) 2 98 10
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PHYSICAL PROPERTIES 5.25 TABLE 5.3
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PHYSICAL PROPERTIES 5.57 5.3 BOILIN
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TABLE 5.12 Ternary Azeotropic Mixtu
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TABLE 5.12 Ternary Azeotropic Mixtu
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PHYSICAL PROPERTIES 5.83 5.4 FREEZI
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PHYSICAL PROPERTIES 5.87 5.5 DENSIT
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PHYSICAL PROPERTIES 5.89 dt Dt P
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PHYSICAL PROPERTIES 5.135 5.6.1 Ref
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PHYSICAL PROPERTIES 5.137 where the
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PHYSICAL PROPERTIES 5.139 5.7 COMBU
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Temperature, C Substance 40 20 0 20
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PHYSICAL PROPERTIES 5.171 This equa
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SECTION 6 THERMODYNAMIC PROPERTIES
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THERMODYNAMICPROPERTIES 6.3 6.1.1.2
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THERMODYNAMICPROPERTIES 6.5 A gener
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THERMODYNAMICPROPERTIES 6.7 TABLE 6
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THERMODYNAMICPROPERTIES 6.9 TABLE 6
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THERMODYNAMICPROPERTIES 6.11 TABLE
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THERMODYNAMIC PROPERTIES 6.21 TABLE
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Page 642 and 643: THERMODYNAMIC PROPERTIES 6.97 TABLE
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Page 706 and 707: SPECTROSCOPY 7.3 TABLE 7.1 Waveleng
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Page 714 and 715: SPECTROSCOPY 7.11 TABLE 7.4 X-Ray E
Page 716 and 717: SPECTROSCOPY 7.13 Emission line K 1
Page 718 and 719: SPECTROSCOPY 7.15 TABLE 7.7 Analyzi
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Page 722 and 723: SPECTROSCOPY 7.19 TABLE 7.9 Electro
Page 724 and 725: SPECTROSCOPY 7.21 TABLE 7.11 Absorp
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Page 728 and 729: SPECTROSCOPY 7.25 7.3 FLUORESCENCE
Page 730 and 731: SPECTROSCOPY 7.27 TABLE 7.16 Fluore
Page 732 and 733: SPECTROSCOPY 7.29 TABLE 7.18 Detect
Page 738 and 739: SPECTROSCOPY 7.35 TABLE 7.19 Sensit
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SPECTROSCOPY 7.39 In terms of m ,
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SPECTROSCOPY 7.41 The ionization co
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SPECTROSCOPY 7.43 TABLE 7.20 Absorp
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SPECTROSCOPY 7.67 TABLE 7.28 Infrar
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7.69
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SPECTROSCOPY 7.71 7.6 RAMAN SPECTRO
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SPECTROSCOPY 7.73 TABLE 7.30 Raman
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SPECTROSCOPY 7.89 7.7 NUCLEAR MAGNE
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SPECTROSCOPY 7.91 TABLE 7.41 Nuclea
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SPECTROSCOPY 7.93 TABLE 7.42 Proton
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SPECTROSCOPY 7.95 TABLE 7.44 Estima
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SPECTROSCOPY 7.97 TABLE 7.46 Proton
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SPECTROSCOPY 7.99 TABLE 7.48 Solven
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SPECTROSCOPY 7.101 TABLE 7.49 Carbo
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SPECTROSCOPY 7.103 TABLE 7.51 Effec
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SPECTROSCOPY 7.107 TABLE 7.56 One-B
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SPECTROSCOPY 7.113 TABLE 7.63 Nitro
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SPECTROSCOPY 7.115 TABLE 7.64 Nitro
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SPECTROSCOPY 7.117 TABLE 7.69 Fluor
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SPECTROSCOPY 7.119 TABLE 7.72 Silic
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SPECTROSCOPY 7.121 TABLE 7.73 Phosp
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SPECTROSCOPY 7.123 TABLE 7.74 Phosp
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SPECTROSCOPY 7.125 when z 3 and y
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SPECTROSCOPY 7.127 Masses 19 and 31
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SPECTROSCOPY 7.129 TABLE 7.76 Conde
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SECTION 8 ELECTROLYTES, ELECTROMOTI
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ELECTROLYTES, EMF, AND CHEMICAL EQU
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TABLE 8.7 Proton Transfer Reactions
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TABLE 8.7 Proton Transfer Reactions
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TABLE 8.9 Selected Equilibrium Cons
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8.75 3-tert-Butylbenzoic acid (0) 4
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4-Hydroxyproline (1) 1.900 1C 1.850
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N-Propionylglycine (1) 3.728 3.723
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TABLE 8.14 National Bureau of Stand
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1 part 0.1% neutral red in alc. * V
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3,3-Dimethoxybenzidine dihydrochlor
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TABLE 8.35 Equivalent Conductivitie
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KCl 127.3 124.4 122.4 115.8 112.0 1
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NaIO 3 75.2 72.6 70.9 64.4 60.5 1
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9.2 SECTION 9 9.1 LINEAR FREE ENERG
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9.4 SECTION 9 TABLE 9.1 Hammett and
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9.6 SECTION 9 TABLE 9.1 Hammett and
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9.8 SECTION 9 TABLE 9.3 pK a and Rh
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10.2 SECTION 10 10.4.6 Polyacrylate
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10.4 SECTION 10 10.2 ADDITIVES TO P
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10.6 SECTION 10 injection molding.
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10.8 SECTION 10 10.3 FORMULAS AND K
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10.10 SECTION 10 Key properties of
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10.12 SECTION 10 10.3.8 Fluorocarbo
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10.14 SECTION 10 10.3.11 Phenolics
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10.16 SECTION 10 The resin has the
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10.18 SECTION 10 10.3.19 Polyuretha
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10.20 SECTION 10 10.3.22 Sulfones B
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TABLE 10.2 Properties of Commercial
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10.58 SECTION 10 10.4 FORMULAS AND
Page 1078 and 1079:
10.60 SECTION 10 10.4.8 Polychlorop
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10.62 SECTION 10 Styrene-butadiene
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10.5 CHEMICAL RESISTANCE TABLE 10.4
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10.6 GAS PERMEABILITY TABLE 10.5 Ga
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TABLE 10.5 Gas Permeability Constan
Page 1088 and 1089:
TABLE 10.7 Constants ofFats and Oil
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TABLE 10.8 Constants ofWaxes Wax Me
Page 1092:
SECTION 11 PRACTICAL LABORATORY INF
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11.4 SECTION 11 TABLE 11.2 Molecula
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11.6 SECTION 11 A saturated aqueous
Page 1099 and 1100:
11.8 SECTION 11 TABLE 11.6 Relative
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11.10 SECTION 11 11.3 BOILING POINT
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11.12 SECTION 11 TABLE 11.8 Organic
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11.14 SECTION 11 TABLE 11.9 Molecul
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11.4 SEPARATION METHODS TABLE 11.11
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11.18 SECTION 11 TABLE 11.12 Solven
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11.20 SECTION 11 TABLE 11.12 Solven
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TABLE 11.13 McReynolds’ Constants
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TABLE 11.13 McReynolds’ Constants
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11.26 SECTION 11 11.4.1 McReynolds
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11.28 SECTION 11 11.4.2.2 Partition
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11.30 SECTION 11 FIGURE 11.2 Band a
Page 1123 and 1124:
11.32 SECTION 11 11.4.3 Ion-Exchang
Page 1125 and 1126:
11.34 SECTION 11 TABLE 11.16 Guide
Page 1127 and 1128:
11.36 SECTION 11 TABLE 11.16 Guide
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11.38 SECTION 11 TABLE 11.18 Relati
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11.40 SECTION 11 distribution coeff
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11.42 SECTION 11 TABLE 11.19 Gravim
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11.68 SECTION 11 TABLE 11.20 Elemen
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11.70 SECTION 11 TABLE 11.22 Common
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11.72 SECTION 11 TABLE 11.25 Tolera
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11.74 SECTION 11 TABLE 11.26 Heatin
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11.76 SECTION 11 TABLE 11.28 Titrim
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11.84 SECTION 11 appears becomes le
Page 1177 and 1178:
11.86 SECTION 11 TABLE 11.29 Equati
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11.88 SECTION 11 TABLE 11.29 Equati
Page 1181 and 1182:
11.90 SECTION 11 The more stable th
Page 1183 and 1184:
11.92 SECTION 11 11.6.6.2.5 Buffer
Page 1185 and 1186:
11.94 SECTION 11 TABLE 11.30 Standa
Page 1187 and 1188:
TABLE 11.32 Properties and Applicat
Page 1189 and 1190:
11.98 SECTION 11 TABLE 11.36 Maskin
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11.100 SECTION 11 TABLE 11.37 Anion
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11.102 SECTION 11 TABLE 11.39 Amino
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11.104 SECTION 11 TABLE 11.44 Facto
Page 1197 and 1198:
11.106 SECTION 11 11.7 LABORATORY S
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11.108 SECTION 11 TABLE 11.48 Stand
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11.110 SECTION 11 Alizarin yellow G
Page 1203 and 1204:
11.112 SECTION 11 Bromchlorophenol
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11.114 SECTION 11 p-Ethoxychrysoidi
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11.116 SECTION 11 Mercurous nitrate
Page 1209 and 1210:
11.118 SECTION 11 Potassium carbona
Page 1211 and 1212:
11.120 SECTION 11 until the ammoniu
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11.122 SECTION 11 TABLE 11.49 TLV C
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Page 1221 and 1222:
11.130 SECTION 11 TABLE 11.50 Chemi
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Page 1227 and 1228:
Page 1229 and 1230:
11.138 SECTION 11 of water which is
Page 1231 and 1232:
TABLE 11.55 Thermoelectric Values i
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TABLE 11.56 Type B Thermocouples: P
Page 1235 and 1236:
TABLE 11.58 Type J Thermocouples: I
Page 1237 and 1238:
TABLE 11.60 Type N Thermocouples: N
Page 1239 and 1240:
TABLE 11.62 Type S Thermocouples: P
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11.150 SECTION 11 11.11 CORRECTION
Page 1243 and 1244:
Index Terms Links 2 Acid-base indic
Page 1245 and 1246:
Index Terms Links 4 Alkynes, nomenc
Page 1247 and 1248:
Index Terms Links 6 Aurintricarboxy
Page 1249 and 1250:
Index Terms Links 8 Boron-11 chemic
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Index Terms Links 10 Cellulose acet
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Index Terms Links 12 Collective ino
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Index Terms Links 14 Degree Fahrenh
Page 1257 and 1258:
Index Terms Links 16 Electrical res
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Index Terms Links 18 Equivalent wei
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Index Terms Links 20 Fluorocarbon p
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Index Terms Links 22 Halogenated hy
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Index Terms Links 24 Impact strengt
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Index Terms Links 26 Kα 1 lines, m
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Index Terms Links 28 Melmine phenol
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Index Terms Links 30 Neon-neon bond
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Index Terms Links 32 One-tailed tes
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Index Terms Links 34 Physical chemi
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Index Terms Links 36 Polyolefin the
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Index Terms Links 38 Pyridine: bina
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Index Terms Links 40 Rho values: fo
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Index Terms Links 42 Single-bond ra
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Index Terms Links 44 Stereoisomers
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Index Terms Links 46 Tension, aqueo
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Index Terms Links 48 Triethylenetet
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Index Terms Links 50 Water (Cont.)
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