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preface to fifteenth edition

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5.66 SECTION 5<br />

TABLE 5.11<br />

Binary Azeotropic (Constant-Boiling) Mixtures (Continued)<br />

C. Binary azeotropes containing alcohol<br />

Composition, wt %<br />

System<br />

BP of azeotrope,<br />

C<br />

Alcohol<br />

Other<br />

component<br />

Methanol<br />

Pentane 30.9 7 93<br />

Cyclopentane 38.8 14 86<br />

Cyclohexane 53.9 36.4 63.6<br />

Methylcyclohexane 59.2 54 46<br />

Heptane 59.1 51.5 48.5<br />

Octane 62.8 67.5 32.5<br />

Nonane 64.1 83.4 16.6<br />

Benzene 57.5 39.1 60.9<br />

Fluorobenzene 59.7 32 68<br />

Toluene 63.5 72.5 27.5<br />

Bromomethane 3.55 99.55 0.45<br />

Iodomethane 37.8 95.5 4.5<br />

Bromodichloromethane 63.8 60 40<br />

Chloroform 53.4 87.4 12.6<br />

Carbon tetrachloride 55.7 79.44 20.56<br />

Bromoethane 34.9 5.3 94.7<br />

1,2-Dichloroethane 61.0 32 68<br />

Trichloroethylene 59.3 38 62<br />

1-Bromopropane 54.5 21 79<br />

2-Bromopropane 48.6 15.0 85.0<br />

1-Chloropropane 40.5 9.5 90.5<br />

2-Chloropropane 33.4 6 94<br />

2-Iodopropane 61.0 38 62<br />

1-Chlorobutane 57.0 27 73<br />

Isobutyl formate 64.6 95 5<br />

Methyl acetate 53.5 19 81<br />

Methyl acrylate 62.5 54 46<br />

Methyl nitrate 52.5 73 27<br />

Ace<strong>to</strong>ne 55.5 12.1 87.9<br />

1,4-Dioxane<br />

zeotrope<br />

Dipropyl ether 63.8 72 28<br />

Methyl tert-butyl ether 51.3 14.3 85.7<br />

Diethyl sulfide 61.2 62 38<br />

Carbon disulfide 39.8 71 29<br />

Thiophene 59.7 16.4 83.6<br />

Nitromethane 64.4 9.1 90.9<br />

Ethanol<br />

Pentane 34.3 5 95<br />

Cyclopentane 44.7 7.5 92.5<br />

Hexane 58.7 21 79<br />

Cyclohexane 64.8 29.2 70.8<br />

Heptane 70.9 49 51

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