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THERMODYNAMIC PROPERTIES 6.155 TABLE 6.5 Critical Properties (Continued) Substance T c , C P c , atm P c ,MPa V c ,cm 3 ·mol 1 c ,g·cm 3 3-Pentanol 286.5 2-Pentanone 287.93 36.46 3.694 301 0.286 3-Pentanone 288.31 36.9 3.729 336 0.256 1-Pentene 191.63 34.81 3.527 293 0.239 cis-2-Pentene 202 36.4 3.69 trans-2-Pentene 198 34.7 3.52 304 0.231 Pentyl acetate 332 Pentylbenzene 406.8 25.7 2.60 550 0.269 Pentyl formate 303 1-Pentyne 220.3 40 4.05 278 0.245 Perchloryl fluoride 95.3 53.0 5.37 161 0.637 Phenanthrene 596 554 0.322 Phenol 421.1 60.5 6.13 229 0.41 1-Phenylhexadecane 535 12.7 1.29 1200 0.252 1-Phenylpentadecane 526.9 13.3 1.35 1140 0.253 1-Phenyltetradecane 519 14.0 1.42 1110 0.247 Phosgene 182 56 5.67 190 0.52 Phosphine 51.3 64.5 6.54 Phosphine-d 3 50.4 Phosphonium chloride 49.1 72.7 7.37 Phosphorus 721 Phosphorus bromide difluoride 113 Phosphorus chloride difluoride 89.2 44.6 4.52 Phosphorus dibromide fluoride 254 Phosphorus dichloride fluoride 189.9 49.3 5.00 Phosphorus pentachloride 372 Phosphorus trichloride 290 260 0.528 Phosphorus trifluoride 1.9 42.7 4.33 Phosphoryl chloride difluoride 150.7 43.4 4.40 Phosphoryl trichloride 329 Phosphoryl trifluoride 73.4 41.8 4.24 Phthalicanhydride 537 47 4.76 368 0.402 Piperidine 321.0 48.8 4.94 288 0.296 Propadiene 120 54.0 5.47 162 0.247 Propanal 231.3 52.0 5.27 204 0.285 Propane 96.68 41.92 4.248 200 0.217 1,2-Propanediol 352 60 6.08 237 0.321 1,3-Propanediol 385 59 5.98 241 0.316 Propanenitrile 288.2 42.0 4.26 230 0.240 1-Propanethiol 262.5 2-Propanethiol 244.2 Propanoicacid 331 44.7 4.53 222 0.32 1-Propanol 263.7 51.01 5.169 218.5 0.275 2-Propanol 235.2 47.02 4.764 220 0.273 2-Propenal 233 51 5.17 197 0.285 Propene 91.9 45.6 4.62 181 0.233 2-Propen-1-ol 272.0 208 0.279 Propyl acetate 276.6 33.2 3.36 345 0.296 Propylamine 223.9 46.6 4.72 233 0.254 Propylbenzene 365.20 31.58 3.200 440 0.273 Propyl butanoate 327 Propylcyclopentane 358.7 29.6 3.00 425 0.264 Propylcyclohexane 336.7 27.7 2.81 Propylene oxide 209.1 48.6 4.92 186 0.312
6.156 SECTION 6 TABLE 6.5 Critical Properties (Continued) Substance T c , C P c , atm P c ,MPa V c ,cm 3 ·mol 1 c ,g·cm 3 Propyl formate 264.9 40.1 4.06 285 0.309 Propyl 2-methylpropanoate 316 Propyl 3-methylpropanoate 336 Propyl propanoate 305 Propyne 129.3 55.5 5.62 164 0.245 Pyridine 346.9 55.96 5.67 243 0.325 Pyrrole 366.6 62.6 6.34 200 0.335 Pyrrolidine 295.1 55.2 5.59 238 0.300 Quinoline 509 48.0 4.86 437 0.300 Radon 104 62 6.28 139 1.6 Rhenium(VII) oxide 669 334 Rhenium(VI) oxide tetrachloride 508 161 0.95 Rubidium 1832 250 0.34 Selenium 1493 Silane 3.5 47.8 4.84 Silicon chloride trifluoride 34.5 34.2 3.47 Silicon tetrabromide 390 Silicon tetrachloride 234 37 3.75 326 0.521 Silicon tetrafluoride 14.0 36.7 3.72 Silicon trichloride fluoride 165.4 35.3 3.57 Spiro[2.2]pentane 233.3 Styrene 363.8 36.3 3.68 347 0.300 Sulfur 1041 116 11.7 Sulfur dioxide 157.7 77.8 7.88 122 0.5240 Sulfur hexafluoride 45.6 37.1 3.76 198 0.734 Sulfur tetrafluoride 91.7 Sulfur trioxide 217.9 81 8.2 130 0.633 Tantalum pentabromide 701 461 1.26 Tantalum pentachloride 494 400 0.89 1,2-Terphenyl 617.9 38.5 3.90 755 0.305 1,3-Terphenyl 651.7 34.6 3.51 768 0.300 1,4-Terphenyl 652.9 32.8 3.32 762 0.302 1,1,2,2-Tetrachlorodifluoroethane 278 34 3.44 371 0.549 1,1,2,2-Tetrachloroethane 388.00 Tetrachloroethylene 347.1 44.3 4.49 290 0.572 Tetrachloromethane 283.5 44.57 4.516 276 0.557 Tetradecafluoro-1-heptene 205.1 Tetradecafluorohexane 174.5 18.8 1.90 Tetradecafluoromethylcyclohexane 213.7 23 2.33 Tetradecane 420.9 16 1.62 830 0.239 1-Tetradecene 416 15.4 1.56 Tetradecylcyclopentane 499 11.1 1.12 Tetraethylsilane 330.6 25.68 2.602 Tetrafluoroethylene 33.4 38.9 3.91 175 0.58 Tetrafluorohydrazine 33.3 37 3.75 Tetrafluoromethane 45.5 36.9 3.74 140 0.629 Tetrahydrofuran 267.0 51.22 5.19 224 0.322 1,2,3,4-Tetrahydronaphthalene 447 36.0 3.65 408 0.324 Tetrahydropyran 299.1 47.1 4.77 263 0.328 Tetrahydrothiophene 358.9 1,2,4,5-Tetramethylbenzene 402 29 2.94 480 0.280 2,2,3,3-Tetramethylbutane 294.7 28.3 2.87 461 0.248 2,2,3,3-Tetramethylhexane 350.0 24.8 2.51 573 0.248
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LANGE'S HANDBOOK OF CHEMISTRY John
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Grateful acknowledgment is hereby m
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PREFACE TO FIFTEENTH EDITION This n
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PREFACE TO FIFTEENTH EDITION ix inv
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xii PREFACE TO FOURTEENTH EDITION l
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PREFACE TO FIRST EDITION This book
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For the detailed contents of any se
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1.2 SECTION 1 is derived from the G
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1.4 SECTION 1 rather than methylide
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1.6 SECTION 1 Styrene Toluene Xylen
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1.8 SECTION 1 TABLE 1.2 Fused Polyc
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1.10 SECTION 1 1.1.1.6 Bridged Hydr
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1.12 SECTION 1 TABLE 1.4 Suffixes f
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1.14 SECTION 1 TABLE 1.5 Trivial Na
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1.16 SECTION 1 TABLE 1.6 Trivial Na
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1.18 SECTION 1 Selection of the pri
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1.20 SECTION 1 attached to one anot
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1.22 SECTION 1 When side chains of
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1.24 SECTION 1 heterocyclic structu
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1.26 SECTION 1 Bivalent radicals of
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1.28 SECTION 1 Complex linear polya
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1.30 SECTION 1 TABLE 1.11 Names of
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1.32 SECTION 1 hydroxyamino- to the
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1.34 SECTION 1 may be named (1) by
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1.36 SECTION 1 Examples are methyl
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1.38 SECTION 1 tuted acid, respecti
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1.40 SECTION 1 FIGURE 1.2 Newman pr
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1.42 SECTION 1 from the ring are kn
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1.44 SECTION 1 FIGURE 1.11 Two isom
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1.46 SECTION 1 Chiral Center. The c
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1.48 SECTION 1 FIGURE 1.15 Isomers
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1.50 SECTION 1 entries to bring tog
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1.52 SECTION 1 TABLE 1.13 Names and
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1.60 SECTION 1 TABLE 1.14 Empirical
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2.2 SECTION 2 2.3.6 Student’s Dis
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2.4 SECTION 2 TABLE 2.1 Fundamental
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2.6 SECTION 2 TABLE 2.1 Fundamental
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2.8 SECTION 2 TABLE 2.2 Physical an
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2.10 SECTION 2 TABLE 2.2 Physical a
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2.24 SECTION 2 TABLE 2.3 Mathematic
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2.26 SECTION 2 TABLE 2.6 Abbreviati
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2.36 SECTION 2 TABLE 2.7 Conversion
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2.54 SECTION 2 TABLE 2.8 Temperatur
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2.66 SECTION 2 2.1.1 Conversion of
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2.68 SECTION 2 Oleometer. A hydrome
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2.70 SECTION 2 Example 3. 25 1.2500
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2.72 SECTION 2 TABLE 2.9 Barometer
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2.74 SECTION 2 TABLE 2.9 Barometer
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2.76 SECTION 2 TABLE 2.10 Barometri
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2.78 SECTION 2 TABLE 2.12 Reduction
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2.80 SECTION 2 TABLE 2.12 Reduction
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2.82 SECTION 2 TABLE 2.13 Viscosity
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2.84 SECTION 2 TABLE 2.14 Conversio
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2.86 SECTION 2 TABLE 2.15 Hydromete
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2.88 SECTION 2 TABLE 2.17 Correctio
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2.90 SECTION 2 TABLE 2.18 Pressure
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2.96 SECTION 2 TABLE 2.20 Values of
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2.98 SECTION 2 TABLE 2.21 Transmitt
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2.100 SECTION 2 TABLE 2.21 Transmit
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2.102 SECTION 2 2.2 MATHEMATICAL TA
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2.104 SECTION 2 TABLE 2.23 Derivati
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2.106 SECTION 2 TABLE 2.24 Integral
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2.108 SECTION 2 TABLE 2.24 Integral
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2.110 SECTION 2 Regular Polygon of
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2.112 SECTION 2 A h[0.4(y y ) 1.
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2.114 SECTION 2 2.2.3.1 Signs of th
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2.116 SECTION 2 x2 x3 x4 x5 ln(1 x
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2.118 SECTION 2 2.3.2 Errors in Qua
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2.120 SECTION 2 The breadth or spre
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2.122 SECTION 2 TABLE 2.26b Areas U
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2.124 SECTION 2 The distribution of
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2.126 SECTION 2 Should there be mor
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2.128 SECTION 2 Example 10 Six samp
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2.130 SECTION 2 2.3.9 The F Statist
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TABLE 2.29 F Distribution (Continue
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2.134 SECTION 2 mathematical treatm
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2.136 SECTION 2 The confidence limi
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2.138 SECTION 2 situation where rel
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3.2 SECTION 3 The alphabetical orde
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3.4 SECTION 3 When it is required t
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3.6 SECTION 3 PO phosphoryl SeO sel
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3.8 SECTION 3 3.1.5 Acids 3.1.5.1 A
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3.10 SECTION 3 3.1.6.6 Multiplicati
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3.12 SECTION 3 3.2 PHYSICAL PROPERT
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TABLE 3.2 Physical Constants of Ino
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3.62 SECTION 3 TABLE 3.3 Synonyms a
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SECTION 4 PROPERTIES OF ATOMS, RADI
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4.3 Fermium Fm 100 [Rn] 5f 12 7s 2
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Silver (argentum) Ag 47 [Kr] 4d 10
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PROPERTIES OF ATOMS,RADICALS,AND BO
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PROPERTIES OF ATOMS, RADICALS, AND
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SECTION 5 PHYSICAL PROPERTIES 5.1 S
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PHYSICAL PROPERTIES 5.3 5.1 SOLUBIL
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TABLE 5.1 Solubility of Gases in Wa
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TABLE 5.1 Solubility of Gases in Wa
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TABLE 5.2 Solubilities of Inorganic
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formateBa(CHO 2 ) 2 26.2 28.0 29.9
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(III) sulfateCe 2 (SO 4 ) 3 ·9H 2
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iodidePbI 2 0.044 0.056 0.069 0.090
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Nickel sulfateNiSO 4 ·6H 2 O (pale
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Praseodymium bromatePr(BrO 3 ) 3 55
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formate NaCHO 2 43.9 62.5 81.2 102
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Uranyl nitrate UO 2 (NO 3 ) 2 98 10
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PHYSICAL PROPERTIES 5.25 TABLE 5.3
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PHYSICAL PROPERTIES 5.57 5.3 BOILIN
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TABLE 5.12 Ternary Azeotropic Mixtu
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TABLE 5.12 Ternary Azeotropic Mixtu
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PHYSICAL PROPERTIES 5.83 5.4 FREEZI
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PHYSICAL PROPERTIES 5.87 5.5 DENSIT
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PHYSICAL PROPERTIES 5.89 dt Dt P
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PHYSICAL PROPERTIES 5.135 5.6.1 Ref
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PHYSICAL PROPERTIES 5.137 where the
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PHYSICAL PROPERTIES 5.139 5.7 COMBU
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Temperature, C Substance 40 20 0 20
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PHYSICAL PROPERTIES 5.171 This equa
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SECTION 6 THERMODYNAMIC PROPERTIES
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THERMODYNAMICPROPERTIES 6.3 6.1.1.2
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THERMODYNAMICPROPERTIES 6.5 A gener
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THERMODYNAMICPROPERTIES 6.7 TABLE 6
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THERMODYNAMICPROPERTIES 6.9 TABLE 6
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THERMODYNAMICPROPERTIES 6.11 TABLE
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THERMODYNAMIC PROPERTIES 6.21 TABLE
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THERMODYNAMIC PROPERTIES 6.101 TABL
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THERMODYNAMIC PROPERTIES 6.103 TABL
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Page 704 and 705: SECTION 7 SPECTROSCOPY 7.1 X-RAY ME
Page 706 and 707: SPECTROSCOPY 7.3 TABLE 7.1 Waveleng
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Page 714 and 715: SPECTROSCOPY 7.11 TABLE 7.4 X-Ray E
Page 716 and 717: SPECTROSCOPY 7.13 Emission line K 1
Page 718 and 719: SPECTROSCOPY 7.15 TABLE 7.7 Analyzi
Page 720 and 721: SPECTROSCOPY 7.17 TABLE 7.8 Mass Ab
Page 722 and 723: SPECTROSCOPY 7.19 TABLE 7.9 Electro
Page 724 and 725: SPECTROSCOPY 7.21 TABLE 7.11 Absorp
Page 726 and 727: SPECTROSCOPY 7.23 TABLE 7.13 Solven
Page 728 and 729: SPECTROSCOPY 7.25 7.3 FLUORESCENCE
Page 730 and 731: SPECTROSCOPY 7.27 TABLE 7.16 Fluore
Page 732 and 733: SPECTROSCOPY 7.29 TABLE 7.18 Detect
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Page 742 and 743: SPECTROSCOPY 7.39 In terms of m ,
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SPECTROSCOPY 7.47 TABLE 7.20 Absorp
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SPECTROSCOPY 7.67 TABLE 7.28 Infrar
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7.69
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SPECTROSCOPY 7.71 7.6 RAMAN SPECTRO
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SPECTROSCOPY 7.73 TABLE 7.30 Raman
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SPECTROSCOPY 7.89 7.7 NUCLEAR MAGNE
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SPECTROSCOPY 7.91 TABLE 7.41 Nuclea
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SPECTROSCOPY 7.93 TABLE 7.42 Proton
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SPECTROSCOPY 7.95 TABLE 7.44 Estima
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SPECTROSCOPY 7.97 TABLE 7.46 Proton
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SPECTROSCOPY 7.99 TABLE 7.48 Solven
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SPECTROSCOPY 7.101 TABLE 7.49 Carbo
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SPECTROSCOPY 7.103 TABLE 7.51 Effec
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SPECTROSCOPY 7.107 TABLE 7.56 One-B
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SPECTROSCOPY 7.113 TABLE 7.63 Nitro
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SPECTROSCOPY 7.115 TABLE 7.64 Nitro
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SPECTROSCOPY 7.117 TABLE 7.69 Fluor
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SPECTROSCOPY 7.119 TABLE 7.72 Silic
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SPECTROSCOPY 7.121 TABLE 7.73 Phosp
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SPECTROSCOPY 7.123 TABLE 7.74 Phosp
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SPECTROSCOPY 7.125 when z 3 and y
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SPECTROSCOPY 7.127 Masses 19 and 31
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SPECTROSCOPY 7.129 TABLE 7.76 Conde
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SECTION 8 ELECTROLYTES, ELECTROMOTI
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ELECTROLYTES, EMF, AND CHEMICAL EQU
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TABLE 8.7 Proton Transfer Reactions
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TABLE 8.7 Proton Transfer Reactions
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TABLE 8.9 Selected Equilibrium Cons
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8.75 3-tert-Butylbenzoic acid (0) 4
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4-Hydroxyproline (1) 1.900 1C 1.850
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N-Propionylglycine (1) 3.728 3.723
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TABLE 8.14 National Bureau of Stand
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1 part 0.1% neutral red in alc. * V
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3,3-Dimethoxybenzidine dihydrochlor
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TABLE 8.35 Equivalent Conductivitie
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KCl 127.3 124.4 122.4 115.8 112.0 1
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NaIO 3 75.2 72.6 70.9 64.4 60.5 1
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9.2 SECTION 9 9.1 LINEAR FREE ENERG
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9.4 SECTION 9 TABLE 9.1 Hammett and
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9.6 SECTION 9 TABLE 9.1 Hammett and
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9.8 SECTION 9 TABLE 9.3 pK a and Rh
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10.2 SECTION 10 10.4.6 Polyacrylate
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10.4 SECTION 10 10.2 ADDITIVES TO P
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10.6 SECTION 10 injection molding.
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10.8 SECTION 10 10.3 FORMULAS AND K
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10.10 SECTION 10 Key properties of
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10.12 SECTION 10 10.3.8 Fluorocarbo
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10.14 SECTION 10 10.3.11 Phenolics
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10.16 SECTION 10 The resin has the
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10.18 SECTION 10 10.3.19 Polyuretha
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10.20 SECTION 10 10.3.22 Sulfones B
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TABLE 10.2 Properties of Commercial
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10.58 SECTION 10 10.4 FORMULAS AND
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10.60 SECTION 10 10.4.8 Polychlorop
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10.62 SECTION 10 Styrene-butadiene
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10.5 CHEMICAL RESISTANCE TABLE 10.4
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10.6 GAS PERMEABILITY TABLE 10.5 Ga
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TABLE 10.5 Gas Permeability Constan
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TABLE 10.7 Constants ofFats and Oil
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TABLE 10.8 Constants ofWaxes Wax Me
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SECTION 11 PRACTICAL LABORATORY INF
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11.4 SECTION 11 TABLE 11.2 Molecula
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11.6 SECTION 11 A saturated aqueous
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11.8 SECTION 11 TABLE 11.6 Relative
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11.10 SECTION 11 11.3 BOILING POINT
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11.12 SECTION 11 TABLE 11.8 Organic
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11.14 SECTION 11 TABLE 11.9 Molecul
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11.4 SEPARATION METHODS TABLE 11.11
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11.18 SECTION 11 TABLE 11.12 Solven
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11.20 SECTION 11 TABLE 11.12 Solven
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TABLE 11.13 McReynolds’ Constants
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TABLE 11.13 McReynolds’ Constants
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11.26 SECTION 11 11.4.1 McReynolds
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11.28 SECTION 11 11.4.2.2 Partition
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11.30 SECTION 11 FIGURE 11.2 Band a
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11.32 SECTION 11 11.4.3 Ion-Exchang
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11.34 SECTION 11 TABLE 11.16 Guide
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11.36 SECTION 11 TABLE 11.16 Guide
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11.38 SECTION 11 TABLE 11.18 Relati
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11.40 SECTION 11 distribution coeff
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11.42 SECTION 11 TABLE 11.19 Gravim
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11.68 SECTION 11 TABLE 11.20 Elemen
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11.70 SECTION 11 TABLE 11.22 Common
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11.72 SECTION 11 TABLE 11.25 Tolera
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11.74 SECTION 11 TABLE 11.26 Heatin
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11.76 SECTION 11 TABLE 11.28 Titrim
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11.84 SECTION 11 appears becomes le
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11.86 SECTION 11 TABLE 11.29 Equati
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11.88 SECTION 11 TABLE 11.29 Equati
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11.90 SECTION 11 The more stable th
Page 1183 and 1184:
11.92 SECTION 11 11.6.6.2.5 Buffer
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11.94 SECTION 11 TABLE 11.30 Standa
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TABLE 11.32 Properties and Applicat
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11.98 SECTION 11 TABLE 11.36 Maskin
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11.100 SECTION 11 TABLE 11.37 Anion
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11.102 SECTION 11 TABLE 11.39 Amino
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11.104 SECTION 11 TABLE 11.44 Facto
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11.106 SECTION 11 11.7 LABORATORY S
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11.108 SECTION 11 TABLE 11.48 Stand
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11.110 SECTION 11 Alizarin yellow G
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11.112 SECTION 11 Bromchlorophenol
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11.114 SECTION 11 p-Ethoxychrysoidi
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11.116 SECTION 11 Mercurous nitrate
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11.118 SECTION 11 Potassium carbona
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11.120 SECTION 11 until the ammoniu
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11.122 SECTION 11 TABLE 11.49 TLV C
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11.130 SECTION 11 TABLE 11.50 Chemi
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Page 1229 and 1230:
11.138 SECTION 11 of water which is
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TABLE 11.55 Thermoelectric Values i
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TABLE 11.56 Type B Thermocouples: P
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TABLE 11.58 Type J Thermocouples: I
Page 1237 and 1238:
TABLE 11.60 Type N Thermocouples: N
Page 1239 and 1240:
TABLE 11.62 Type S Thermocouples: P
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11.150 SECTION 11 11.11 CORRECTION
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Index Terms Links 2 Acid-base indic
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Index Terms Links 4 Alkynes, nomenc
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Index Terms Links 6 Aurintricarboxy
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Index Terms Links 8 Boron-11 chemic
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Index Terms Links 10 Cellulose acet
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Index Terms Links 12 Collective ino
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Index Terms Links 14 Degree Fahrenh
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Index Terms Links 16 Electrical res
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Index Terms Links 18 Equivalent wei
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Index Terms Links 20 Fluorocarbon p
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Index Terms Links 22 Halogenated hy
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Index Terms Links 24 Impact strengt
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Index Terms Links 26 Kα 1 lines, m
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Index Terms Links 28 Melmine phenol
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Index Terms Links 30 Neon-neon bond
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Index Terms Links 32 One-tailed tes
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Index Terms Links 34 Physical chemi
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Index Terms Links 36 Polyolefin the
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Index Terms Links 38 Pyridine: bina
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Index Terms Links 40 Rho values: fo
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Index Terms Links 42 Single-bond ra
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Index Terms Links 44 Stereoisomers
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Index Terms Links 46 Tension, aqueo
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Index Terms Links 48 Triethylenetet
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Index Terms Links 50 Water (Cont.)
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