preface to fifteenth edition

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ELECTROLYTES, EMF, AND CHEMICAL EQUILIBRIUM 8.11 TABLE 8.6 Solubility Product Constants (Continued) Compound Formula pK sp K sp hydroxide La(OH) 3 18.70 2.0 10 19 iodate La(IO 3 ) 3 11.12 7.50 10 12 molybdate La 2 (MoO 4 ) 3 20.4 4 10 21 oxalate 9-water La 2 (C 2 O 4 ) 3 26.60 2.5 10 27 phosphate LaPO 4 22.43 3.7 10 23 sulfide La 2 S 3 12.70 2.0 10 13 tungstate trihydrate La 2 (WO 4 ) 3·3H 2 O 3.90 1.3 10 4 Lead acetate Pb(OAc) 2 2.75 1.8 10 3 anthranilate PbL 2 9.81 1.6 10 10 arsenate Pb 3 (AsO 4 ) 3 35.39 4.0 10 36 azide Pb(N 3 ) 2 8.59 2.5 10 9 borate, meta Pb(BO 2 ) 3 10.78 1.6 10 11 bromate Pb(BrO 3 ) 2 1.70 2.0 10 2 bromide PbBr 2 6.82 6.60 10 6 carbonate PbCO 3 13.13 7.4 10 14 chloride PbCl 2 4.77 1.70 10 5 chloride fluoride PbClF8.62 2.4 10 9 chlorite Pb(ClO 2 ) 2 8.4 4 10 9 chromate PbCrO 4 12.55 2.8 10 13 ferrocyanide Pb 2 [Fe(CN) 6 ] 14.46 3.5 10 15 fluoride PbF 2 7.48 3.3 10 8 fluoride iodide PbFI 8.07 8.5 10 9 hydrogen phosphate PbHPO 4 9.90 1.3 10 10 hydrogen phosphite PbHPO 3 6.24 5.8 10 7 hydroxide Pb(OH) 2 14.84 1.43 10 15 hydroxide bromide PbOHBr 14.70 2.0 10 15 hydroxide chloride PbOHCl 13.7 2 10 14 hydroxide nitrate PbOHNO 3 3.55 2.8 10 4 iodate Pb(IO 3 ) 2 12.43 3.69 10 13 iodide PbI 2 8.01 9.8 10 9 molybdate PbMoO 4 13.00 1.0 10 13 niobate Pb(NbO 3 ) 2 16.62 2.4 10 17 oxalate PbC 2 O 4 9.32 4.8 10 10 phosphate Pb 3 (PO 4 ) 2 42.10 8.0 10 43 quinaldate PbL 2 10.60 2.5 10 11 selenate PbSeO 4 6.84 1.37 10 7 selenite PbSeO 3 11.50 3.2 10 12 sulfate PbSO 4 7.60 2.53 10 8 sulfide PbS 27.10 8.0 10 28 thiocyanate Pb(SCN) 2 4.70 2.0 10 5 thiosulfate PbS 2 O 3 6.40 4.0 10 7 tungstate PbWO 4 6.35 4.5 10 7 Lead(IV) hydroxide Pb(OH) 4 65.50 3.2 10 66 Lithium carbonate Li 2 CO 3 1.60 2.5 10 2 fluoride LiF2.74 1.84 10 3 phosphate Li 3 PO 4 10.63 2.37 10 11 uranylarsenate LiUO 2 AsO 4 18.82 1.5 10 19 Lutetium hydroxide Lu(OH) 3 23.72 1.9 10 24
8.12 SECTION 8 TABLE 8.6 Solubility Product Constants (Continued) Compound Formula pK sp K sp Magnesium ammonium phosphate MgNH 4 PO 4 12.60 2.5 10 13 arsenate Mg 3 (AsO 4 ) 2 19.68 2.1 10 20 carbonate MgCO 3 5.17 6.82 10 6 carbonate trihydrate MgCO 3·3H 2 O 5.62 2.38 10 6 fluoride MgF 2 10.29 5.16 10 11 hydroxide Mg(OH) 2 11.25 5.61 10 12 iodate 4-water Mg(IO 3 ) 2·4H 2 O 2.50 3.2 10 3 niobate Mg(NbO 3 ) 2 16.64 2.3 10 17 oxalate dihydrate MgC 2 O 4·2H 2 O 5.32 4.83 10 6 phosphate Mg 3 (PO 4 ) 2 23.98 1.04 10 24 8-quinolinolate MgL 2 15.40 4.0 10 16 selenite MgSeO 3 4.89 1.3 10 5 sulfite MgSO 3 2.50 3.2 10 3 Manganese anthranilate MnL 2 6.75 1.8 10 3 arsenate Mn 3 (AsO 4 ) 2 28.72 1.9 10 29 carbonate MnCO 3 10.63 2.34 10 11 ferrocyanide Mn 2 [Fe(CN) 6 ] 12.10 8.0 10 13 iodate Mn(IO 3 ) 2 6.36 4.37 10 7 hydroxide Mn(OH) 2 12.72 1.9 10 13 oxalate dihydrate MnC 2 O 4·2H 2 O 6.77 1.70 10 7 8-quinolinolate MnL 2 21.70 2.0 10 22 selenite MnSeO 3 6.90 1.3 10 7 sulfide MnS amorphous 9.60 2.5 10 10 MnS crystalline 12.60 2.5 10 13 Mercury(I) azide Hg 2 (N 3 ) 2 9.15 7.1 10 10 bromide Hg 2 Br 2 22.19 6.40 10 23 carbonate Hg 2 CO 3 16.44 3.6 10 17 chloride Hg 2 Cl 2 17.84 1.43 10 18 cyanide Hg 2 (CN) 2 39.3 5 10 40 chromate Hg 2 CrO 4 8.70 2.0 10 9 ferricyanide (Hg 2 ) 3 [Fe(CN) 6 ] 2 20.07 8.5 10 21 fluoride Hg 2 F 2 5.51 3.10 10 6 hydrogen phosphate Hg 2 HPO 4 12.40 4.0 10 13 hydroxide Hg 2 (OH) 2 23.70 2.0 10 24 iodate Hg 2 (IO 3 ) 2 13.71 2.0 10 14 iodide Hg 2 I 2 28.72 5.2 10 29 oxalate Hg 2 C 2 O 4 12.76 1.75 10 13 quinaldate Hg 2 L 2 17.90 1.3 10 18 selenite Hg 2 SeO 3 14.20 8.4 10 15 sulfate Hg 2 SO 4 6.19 6.5 10 7 sulfite Hg 2 SO 3 27.0 1.0 10 27 sulfide Hg 2 S 47.0 1.0 10 47 thiocyanate Hg 2 (SCN) 2 19.49 3.2 10 20 tungstate Hg 2 WO 4 16.96 1.1 10 17 Mercury(II) bromide HgBr 2 19.21 6.2 10 20 hydroxide Hg(OH) 2 25.52 3.2 10 26 iodate Hg(IO 3 ) 2 12.49 3.2 10 13 iodide HgI 2 28.54 2.9 10 29 1,10-phenanthroline HgL 2 24.70 2.0 10 25
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LANGE'S HANDBOOK OF CHEMISTRY John
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Grateful acknowledgment is hereby m
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PREFACE TO FIFTEENTH EDITION This n
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PREFACE TO FIFTEENTH EDITION ix inv
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xii PREFACE TO FOURTEENTH EDITION l
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PREFACE TO FIRST EDITION This book
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For the detailed contents of any se
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1.2 SECTION 1 is derived from the G
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1.4 SECTION 1 rather than methylide
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1.6 SECTION 1 Styrene Toluene Xylen
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1.8 SECTION 1 TABLE 1.2 Fused Polyc
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1.10 SECTION 1 1.1.1.6 Bridged Hydr
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1.12 SECTION 1 TABLE 1.4 Suffixes f
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1.14 SECTION 1 TABLE 1.5 Trivial Na
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1.16 SECTION 1 TABLE 1.6 Trivial Na
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1.18 SECTION 1 Selection of the pri
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1.20 SECTION 1 attached to one anot
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1.22 SECTION 1 When side chains of
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1.24 SECTION 1 heterocyclic structu
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1.26 SECTION 1 Bivalent radicals of
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1.28 SECTION 1 Complex linear polya
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1.30 SECTION 1 TABLE 1.11 Names of
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1.32 SECTION 1 hydroxyamino- to the
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1.34 SECTION 1 may be named (1) by
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1.36 SECTION 1 Examples are methyl
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1.38 SECTION 1 tuted acid, respecti
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1.40 SECTION 1 FIGURE 1.2 Newman pr
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1.42 SECTION 1 from the ring are kn
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1.44 SECTION 1 FIGURE 1.11 Two isom
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1.46 SECTION 1 Chiral Center. The c
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1.48 SECTION 1 FIGURE 1.15 Isomers
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1.50 SECTION 1 entries to bring tog
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1.52 SECTION 1 TABLE 1.13 Names and
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1.60 SECTION 1 TABLE 1.14 Empirical
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2.2 SECTION 2 2.3.6 Student’s Dis
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2.4 SECTION 2 TABLE 2.1 Fundamental
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2.6 SECTION 2 TABLE 2.1 Fundamental
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2.8 SECTION 2 TABLE 2.2 Physical an
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2.10 SECTION 2 TABLE 2.2 Physical a
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2.24 SECTION 2 TABLE 2.3 Mathematic
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2.26 SECTION 2 TABLE 2.6 Abbreviati
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2.36 SECTION 2 TABLE 2.7 Conversion
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2.54 SECTION 2 TABLE 2.8 Temperatur
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2.66 SECTION 2 2.1.1 Conversion of
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2.68 SECTION 2 Oleometer. A hydrome
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2.70 SECTION 2 Example 3. 25 1.2500
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2.72 SECTION 2 TABLE 2.9 Barometer
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2.74 SECTION 2 TABLE 2.9 Barometer
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2.76 SECTION 2 TABLE 2.10 Barometri
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2.78 SECTION 2 TABLE 2.12 Reduction
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2.80 SECTION 2 TABLE 2.12 Reduction
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2.82 SECTION 2 TABLE 2.13 Viscosity
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2.84 SECTION 2 TABLE 2.14 Conversio
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2.86 SECTION 2 TABLE 2.15 Hydromete
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2.88 SECTION 2 TABLE 2.17 Correctio
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2.90 SECTION 2 TABLE 2.18 Pressure
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2.96 SECTION 2 TABLE 2.20 Values of
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2.98 SECTION 2 TABLE 2.21 Transmitt
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2.100 SECTION 2 TABLE 2.21 Transmit
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2.102 SECTION 2 2.2 MATHEMATICAL TA
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2.104 SECTION 2 TABLE 2.23 Derivati
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2.106 SECTION 2 TABLE 2.24 Integral
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2.108 SECTION 2 TABLE 2.24 Integral
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2.110 SECTION 2 Regular Polygon of
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2.112 SECTION 2 A h[0.4(y y ) 1.
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2.114 SECTION 2 2.2.3.1 Signs of th
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2.116 SECTION 2 x2 x3 x4 x5 ln(1 x
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2.118 SECTION 2 2.3.2 Errors in Qua
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2.120 SECTION 2 The breadth or spre
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2.122 SECTION 2 TABLE 2.26b Areas U
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2.124 SECTION 2 The distribution of
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2.126 SECTION 2 Should there be mor
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2.128 SECTION 2 Example 10 Six samp
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2.130 SECTION 2 2.3.9 The F Statist
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TABLE 2.29 F Distribution (Continue
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2.134 SECTION 2 mathematical treatm
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2.136 SECTION 2 The confidence limi
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2.138 SECTION 2 situation where rel
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3.2 SECTION 3 The alphabetical orde
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3.4 SECTION 3 When it is required t
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3.6 SECTION 3 PO phosphoryl SeO sel
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3.8 SECTION 3 3.1.5 Acids 3.1.5.1 A
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3.10 SECTION 3 3.1.6.6 Multiplicati
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3.12 SECTION 3 3.2 PHYSICAL PROPERT
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TABLE 3.2 Physical Constants of Ino
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3.62 SECTION 3 TABLE 3.3 Synonyms a
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SECTION 4 PROPERTIES OF ATOMS, RADI
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4.3 Fermium Fm 100 [Rn] 5f 12 7s 2
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Silver (argentum) Ag 47 [Kr] 4d 10
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PROPERTIES OF ATOMS,RADICALS,AND BO
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PROPERTIES OF ATOMS, RADICALS, AND
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SECTION 5 PHYSICAL PROPERTIES 5.1 S
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PHYSICAL PROPERTIES 5.3 5.1 SOLUBIL
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TABLE 5.1 Solubility of Gases in Wa
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TABLE 5.1 Solubility of Gases in Wa
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TABLE 5.2 Solubilities of Inorganic
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formateBa(CHO 2 ) 2 26.2 28.0 29.9
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(III) sulfateCe 2 (SO 4 ) 3 ·9H 2
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iodidePbI 2 0.044 0.056 0.069 0.090
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Nickel sulfateNiSO 4 ·6H 2 O (pale
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Praseodymium bromatePr(BrO 3 ) 3 55
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formate NaCHO 2 43.9 62.5 81.2 102
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Uranyl nitrate UO 2 (NO 3 ) 2 98 10
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PHYSICAL PROPERTIES 5.25 TABLE 5.3
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PHYSICAL PROPERTIES 5.57 5.3 BOILIN
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TABLE 5.12 Ternary Azeotropic Mixtu
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TABLE 5.12 Ternary Azeotropic Mixtu
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PHYSICAL PROPERTIES 5.83 5.4 FREEZI
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PHYSICAL PROPERTIES 5.87 5.5 DENSIT
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PHYSICAL PROPERTIES 5.89 dt Dt P
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PHYSICAL PROPERTIES 5.135 5.6.1 Ref
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PHYSICAL PROPERTIES 5.137 where the
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PHYSICAL PROPERTIES 5.139 5.7 COMBU
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Temperature, C Substance 40 20 0 20
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PHYSICAL PROPERTIES 5.171 This equa
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SECTION 6 THERMODYNAMIC PROPERTIES
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THERMODYNAMICPROPERTIES 6.3 6.1.1.2
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THERMODYNAMICPROPERTIES 6.5 A gener
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THERMODYNAMICPROPERTIES 6.7 TABLE 6
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THERMODYNAMICPROPERTIES 6.9 TABLE 6
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THERMODYNAMICPROPERTIES 6.11 TABLE
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THERMODYNAMIC PROPERTIES 6.21 TABLE
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THERMODYNAMIC PROPERTIES 6.101 TABL
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THERMODYNAMIC PROPERTIES 6.143 The
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SECTION 7 SPECTROSCOPY 7.1 X-RAY ME
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SPECTROSCOPY 7.3 TABLE 7.1 Waveleng
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SPECTROSCOPY 7.9 TABLE 7.3 Critical
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SPECTROSCOPY 7.11 TABLE 7.4 X-Ray E
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SPECTROSCOPY 7.13 Emission line K 1
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SPECTROSCOPY 7.15 TABLE 7.7 Analyzi
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SPECTROSCOPY 7.17 TABLE 7.8 Mass Ab
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SPECTROSCOPY 7.19 TABLE 7.9 Electro
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SPECTROSCOPY 7.21 TABLE 7.11 Absorp
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SPECTROSCOPY 7.23 TABLE 7.13 Solven
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SPECTROSCOPY 7.25 7.3 FLUORESCENCE
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SPECTROSCOPY 7.27 TABLE 7.16 Fluore
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SPECTROSCOPY 7.29 TABLE 7.18 Detect
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SPECTROSCOPY 7.35 TABLE 7.19 Sensit
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SPECTROSCOPY 7.37 TABLE 7.19 Sensit
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SPECTROSCOPY 7.39 In terms of m ,
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SPECTROSCOPY 7.41 The ionization co
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SPECTROSCOPY 7.67 TABLE 7.28 Infrar
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7.69
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SPECTROSCOPY 7.71 7.6 RAMAN SPECTRO
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SPECTROSCOPY 7.73 TABLE 7.30 Raman
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SPECTROSCOPY 7.89 7.7 NUCLEAR MAGNE
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SPECTROSCOPY 7.91 TABLE 7.41 Nuclea
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SPECTROSCOPY 7.93 TABLE 7.42 Proton
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SPECTROSCOPY 7.95 TABLE 7.44 Estima
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SPECTROSCOPY 7.97 TABLE 7.46 Proton
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Page 844 and 845: ELECTROLYTES, EMF, AND CHEMICAL EQU
Page 860 and 861: TABLE 8.7 Proton Transfer Reactions
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ELECTROLYTES, EMF, AND CHEMICAL EQU
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TABLE 8.9 Selected Equilibrium Cons
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8.75 3-tert-Butylbenzoic acid (0) 4
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4-Hydroxyproline (1) 1.900 1C 1.850
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N-Propionylglycine (1) 3.728 3.723
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TABLE 8.14 National Bureau of Stand
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1 part 0.1% neutral red in alc. * V
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3,3-Dimethoxybenzidine dihydrochlor
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TABLE 8.35 Equivalent Conductivitie
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KCl 127.3 124.4 122.4 115.8 112.0 1
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NaIO 3 75.2 72.6 70.9 64.4 60.5 1
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9.2 SECTION 9 9.1 LINEAR FREE ENERG
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9.4 SECTION 9 TABLE 9.1 Hammett and
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9.6 SECTION 9 TABLE 9.1 Hammett and
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9.8 SECTION 9 TABLE 9.3 pK a and Rh
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10.2 SECTION 10 10.4.6 Polyacrylate
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10.4 SECTION 10 10.2 ADDITIVES TO P
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10.6 SECTION 10 injection molding.
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10.8 SECTION 10 10.3 FORMULAS AND K
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10.10 SECTION 10 Key properties of
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10.12 SECTION 10 10.3.8 Fluorocarbo
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10.14 SECTION 10 10.3.11 Phenolics
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10.16 SECTION 10 The resin has the
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10.18 SECTION 10 10.3.19 Polyuretha
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10.20 SECTION 10 10.3.22 Sulfones B
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TABLE 10.2 Properties of Commercial
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10.58 SECTION 10 10.4 FORMULAS AND
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10.60 SECTION 10 10.4.8 Polychlorop
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10.62 SECTION 10 Styrene-butadiene
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10.5 CHEMICAL RESISTANCE TABLE 10.4
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10.6 GAS PERMEABILITY TABLE 10.5 Ga
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TABLE 10.5 Gas Permeability Constan
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TABLE 10.7 Constants ofFats and Oil
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TABLE 10.8 Constants ofWaxes Wax Me
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SECTION 11 PRACTICAL LABORATORY INF
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11.4 SECTION 11 TABLE 11.2 Molecula
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11.6 SECTION 11 A saturated aqueous
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11.8 SECTION 11 TABLE 11.6 Relative
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11.10 SECTION 11 11.3 BOILING POINT
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11.12 SECTION 11 TABLE 11.8 Organic
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11.14 SECTION 11 TABLE 11.9 Molecul
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11.4 SEPARATION METHODS TABLE 11.11
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11.18 SECTION 11 TABLE 11.12 Solven
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11.20 SECTION 11 TABLE 11.12 Solven
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TABLE 11.13 McReynolds’ Constants
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TABLE 11.13 McReynolds’ Constants
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11.26 SECTION 11 11.4.1 McReynolds
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11.28 SECTION 11 11.4.2.2 Partition
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11.30 SECTION 11 FIGURE 11.2 Band a
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11.32 SECTION 11 11.4.3 Ion-Exchang
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11.34 SECTION 11 TABLE 11.16 Guide
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11.36 SECTION 11 TABLE 11.16 Guide
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11.38 SECTION 11 TABLE 11.18 Relati
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11.40 SECTION 11 distribution coeff
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11.42 SECTION 11 TABLE 11.19 Gravim
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11.68 SECTION 11 TABLE 11.20 Elemen
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11.70 SECTION 11 TABLE 11.22 Common
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11.72 SECTION 11 TABLE 11.25 Tolera
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11.74 SECTION 11 TABLE 11.26 Heatin
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11.76 SECTION 11 TABLE 11.28 Titrim
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11.84 SECTION 11 appears becomes le
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11.86 SECTION 11 TABLE 11.29 Equati
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11.88 SECTION 11 TABLE 11.29 Equati
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11.90 SECTION 11 The more stable th
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11.92 SECTION 11 11.6.6.2.5 Buffer
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11.94 SECTION 11 TABLE 11.30 Standa
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TABLE 11.32 Properties and Applicat
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11.98 SECTION 11 TABLE 11.36 Maskin
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11.100 SECTION 11 TABLE 11.37 Anion
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11.102 SECTION 11 TABLE 11.39 Amino
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11.104 SECTION 11 TABLE 11.44 Facto
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11.106 SECTION 11 11.7 LABORATORY S
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11.108 SECTION 11 TABLE 11.48 Stand
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11.110 SECTION 11 Alizarin yellow G
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11.112 SECTION 11 Bromchlorophenol
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11.114 SECTION 11 p-Ethoxychrysoidi
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11.116 SECTION 11 Mercurous nitrate
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11.118 SECTION 11 Potassium carbona
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11.120 SECTION 11 until the ammoniu
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11.122 SECTION 11 TABLE 11.49 TLV C
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11.130 SECTION 11 TABLE 11.50 Chemi
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11.138 SECTION 11 of water which is
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TABLE 11.55 Thermoelectric Values i
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TABLE 11.56 Type B Thermocouples: P
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TABLE 11.58 Type J Thermocouples: I
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TABLE 11.60 Type N Thermocouples: N
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TABLE 11.62 Type S Thermocouples: P
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11.150 SECTION 11 11.11 CORRECTION
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Index Terms Links 2 Acid-base indic
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Index Terms Links 4 Alkynes, nomenc
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Index Terms Links 6 Aurintricarboxy
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Index Terms Links 8 Boron-11 chemic
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Index Terms Links 10 Cellulose acet
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Index Terms Links 12 Collective ino
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Index Terms Links 14 Degree Fahrenh
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Index Terms Links 16 Electrical res
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Index Terms Links 18 Equivalent wei
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Index Terms Links 20 Fluorocarbon p
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Index Terms Links 22 Halogenated hy
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Index Terms Links 24 Impact strengt
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Index Terms Links 26 Kα 1 lines, m
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Index Terms Links 28 Melmine phenol
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Index Terms Links 30 Neon-neon bond
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Index Terms Links 32 One-tailed tes
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Index Terms Links 34 Physical chemi
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Index Terms Links 36 Polyolefin the
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Index Terms Links 38 Pyridine: bina
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Index Terms Links 40 Rho values: fo
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Index Terms Links 42 Single-bond ra
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Index Terms Links 44 Stereoisomers
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Index Terms Links 46 Tension, aqueo
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Index Terms Links 48 Triethylenetet
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Index Terms Links 50 Water (Cont.)
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