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TABLE 3.2 Physical Constants of Inorganic Compounds (Continued) Name Formula Formula weight Density Melting point, C Boiling point, C Solubility in 100 parts solvent 3.42 Phosphine PH 3 34.00 1.529 g/L 133.81 87.78 mL/100 mL 17 : 1025 CS 2 , 726 bz, 319 HOAc, 26 aq; s alc, eth Phosphonium iodide PH 4 I 161.91 2.86 18.5 subl 62.5 d aq Phosphoryl chloride difluoride POClF 2 120.43 1.656 0 96.4 3.1 dichloride fluoride POCl 2 F 136.89 1.5497 20 80.1 52.90 tribromide POBr 3 286.72 2.822 56 191.7 d s bz, CS 2 , eth trichloride POCl 3 153.35 1.645 25 1.25 105 d aq, alc Platinum Pt 195.08 21.09 20 1769 3824 s aqua regia, fused alkali (II) chloride PtCl 2 266.00 5.87 d 581 i aq, alc; s HCl, NH 4 OH (IV) chloride PtCl 4 336.90 4.303 25 d 370 143 g/100 mL 25 aq (VI) fluoride PtF 6 309.08 3.826 (lq) 61.3 69.14 (II) oxide PtO 211.09 14.9 15 d550 iaq;sHCl (IV) oxide PtO 2 227.09 10.2 450 i aqua regia (IV) sulfide PtS 2 259.22 7.66 d 225 s HCl, HNO 3 Plutonium Pu 239.052 19.81620 4 639.5 3230 i aq; s acids (III) bromide PuBr 3 478.79 6.69 681 d 1300 s aq (III) chloride PuCl 3 345.42 5.70 760 1767 i aq; v s acids (III) fluoride PuF 3 296.06 9.32 1425 d 2000 hyd aq (IV) fluoride PuF 4 315.05 7.00 1037 d i aq (VI) fluoride PuF 6 353.05 4.86 51.59 62.16 (II) hydride PuH 2 241.08 10.40 ca. 727 (III) hydride PuH 3 242.08 9.61 ca. 327 (II) oxide PuO 255.05 13.9 1900 (III) oxide Pu 2 O 3 526.12 10.2 2085 (in He) (IV) oxide PuO 2 271.05 11.46 2390 (in He) d 2800 (III) sulfide Pu 2 S 3 574.30 9.95 1727 Polonium Po 208.9824 9.196 alpha 254 962 sl s aq; s acids 9.398 beta (IV) chloride PoCl 4 350.79 300 (in Cl 2 ) 390 (in Cl 2 ) sl hyd aq; v s HCl; s alc, acet (IV) oxide PoO 240.98 d 550 v s dilute HCl
3.43 Potassium K 39.0983 0.89 63.38 759 d aq to KOH; s acids acetate KC 2 H 3 O 2 98.14 1.57 292 g/100 mL: 200 aq, 34 alc arsenate K 3 AsO 4 256.21 2.8 1310 19 g/100 mL aq; slowly s glyc; s alc borate(1) KBO 2 81.91 947 1401 71 g/100 mL 30 aq bromate KBrO 3 167.00 3.27 350 d 370 6.9 g/100 mL 20 aq bromide KBr 119.00 2.75 734 1435 g/100 mL: 65 20 aq, 22 glyc, 0.4 alc carbonate K 2 CO 3 138.21 2.29 901 d to K 2 O 90 g/100 mL 20 aq; i alc chlorate KClO 3 122.55 2.32 368 d 400 g/100 mL: 7.3 20 aq, 2 glyc chloride KCl 74.55 1.988 771 1437 g/100 mL: 34 20 aq, 7 glyc, 0.4 alc chromate(VI) K 2 CrO 4 194.19 2.732 975 64 g/100 mL 20 aq; i alc citrate hydrate K 3 C 6 H 5 O 7 ·H 2 O 324.42 1.98 anhyd 180 d 230 g/100 mL: 154 aq; 40 glyc cyanate KOCN 81.11 2.05 d 700 s aq; sl s alc cyanide KCN 65.12 1.55 634 1625 g/100 mL: 50 aq, 50 glyc, 4 MeOH dichromate(VI) K 2 Cr 2 O 7 294.19 25 2.676 4 398 d 500 11.7 g/100 mL 20 aq dicyanoargentate(I) K[Ag(CN) 2 ] 199.01 2.36 25 g/100 mL 30 aq dihydrogen arsenate KH 2 AsO 4 180.03 2.867 288 g/100 mL: 19 6 aq, 63 glyc; i alc dihydrogen phosphate KH 2 PO 4 136.09 2.338 d 400 (KPO 3 ) 22.6 g/100 mL 20 aq; i alc dioxide KO 2 71.10 2.14 509 d v s aq with decomposition diphosphate(V) 3-water K 4 P 2 O 7 ·3H 2 O 384.38 2.33 anhyd 300 mp: 1090 s aq; i alc disulfate(IV) K 2 S 2 O 5 222.32 s aq; flammable if ground disulfate(VI) (pyrosulfate) K 2 S 2 O 7 254.32 2.28 325 s aq ethyldithiocarbonate KOCSSC 2 H 5 160.30 1.558 d 200 v s aq fluoride KF 58.10 2.48 859.9 1505 95 g/100 mL 20 aq formate KCHO 84.12 1.91 167.5 d mp 250 g/100 mL aq gluconate KC 6 H 11 O 7 234.25 d 180 v s aq; i alc, bz, chl heptaiodobismuthate(III)(4) K 4 [BiI 7 ] 1253.82 d aq; s alkali iodide solutions hexachloroplatinate(IV) K 2 [PtCl 6 ] 485.99 3.50 d 250 0.48 20 aq hexacyanoferrate(II) K 4 [Fe(CN) 6 ]·3H 2 O 422.39 1.85 anhyd 100 d 28 g/100 mL 20 aq 3-water hexacyanoferrate(III) K 3 [Fe(CN) 6 ] 329.25 1.89 d 40 g/100 mL 20 aq (slow); sl s alc hexafluorosilicate K 2 [SiF 6 ] 220.27 2.27 d sl s aq; i alc hexafluorozirconate K 2 [ZrF 6 ] 283.41 3.58 2.7 g/100 mL 20 aq hexanitritocobaltate(III) K 3 [Co(NO 2 ) 6 ] · 1.5H 2 O 479.30 d 200 0.089 18 aq; s HOAc; v sl s alc 1.5-water hydride KH 40.11 1.43 417 d d aq hydrogen carbonate KHCO 3 100.11 2.17 d 100 34 g/100 mL 20 aq; i alc
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LANGE'S HANDBOOK OF CHEMISTRY John
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Grateful acknowledgment is hereby m
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PREFACE TO FIFTEENTH EDITION This n
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PREFACE TO FIFTEENTH EDITION ix inv
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xii PREFACE TO FOURTEENTH EDITION l
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PREFACE TO FIRST EDITION This book
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For the detailed contents of any se
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1.2 SECTION 1 is derived from the G
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1.4 SECTION 1 rather than methylide
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1.6 SECTION 1 Styrene Toluene Xylen
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1.8 SECTION 1 TABLE 1.2 Fused Polyc
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1.10 SECTION 1 1.1.1.6 Bridged Hydr
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1.12 SECTION 1 TABLE 1.4 Suffixes f
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1.14 SECTION 1 TABLE 1.5 Trivial Na
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1.16 SECTION 1 TABLE 1.6 Trivial Na
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1.18 SECTION 1 Selection of the pri
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1.20 SECTION 1 attached to one anot
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1.22 SECTION 1 When side chains of
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1.24 SECTION 1 heterocyclic structu
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1.26 SECTION 1 Bivalent radicals of
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1.28 SECTION 1 Complex linear polya
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1.30 SECTION 1 TABLE 1.11 Names of
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1.32 SECTION 1 hydroxyamino- to the
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1.34 SECTION 1 may be named (1) by
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1.36 SECTION 1 Examples are methyl
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1.38 SECTION 1 tuted acid, respecti
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1.40 SECTION 1 FIGURE 1.2 Newman pr
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1.42 SECTION 1 from the ring are kn
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1.44 SECTION 1 FIGURE 1.11 Two isom
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1.46 SECTION 1 Chiral Center. The c
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1.48 SECTION 1 FIGURE 1.15 Isomers
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1.50 SECTION 1 entries to bring tog
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1.52 SECTION 1 TABLE 1.13 Names and
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1.60 SECTION 1 TABLE 1.14 Empirical
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2.2 SECTION 2 2.3.6 Student’s Dis
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2.4 SECTION 2 TABLE 2.1 Fundamental
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2.6 SECTION 2 TABLE 2.1 Fundamental
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2.8 SECTION 2 TABLE 2.2 Physical an
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2.10 SECTION 2 TABLE 2.2 Physical a
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2.24 SECTION 2 TABLE 2.3 Mathematic
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2.26 SECTION 2 TABLE 2.6 Abbreviati
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2.36 SECTION 2 TABLE 2.7 Conversion
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2.54 SECTION 2 TABLE 2.8 Temperatur
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2.66 SECTION 2 2.1.1 Conversion of
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2.68 SECTION 2 Oleometer. A hydrome
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2.70 SECTION 2 Example 3. 25 1.2500
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2.72 SECTION 2 TABLE 2.9 Barometer
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2.74 SECTION 2 TABLE 2.9 Barometer
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2.76 SECTION 2 TABLE 2.10 Barometri
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2.78 SECTION 2 TABLE 2.12 Reduction
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2.80 SECTION 2 TABLE 2.12 Reduction
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2.82 SECTION 2 TABLE 2.13 Viscosity
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2.84 SECTION 2 TABLE 2.14 Conversio
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2.86 SECTION 2 TABLE 2.15 Hydromete
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2.88 SECTION 2 TABLE 2.17 Correctio
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2.90 SECTION 2 TABLE 2.18 Pressure
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2.96 SECTION 2 TABLE 2.20 Values of
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2.98 SECTION 2 TABLE 2.21 Transmitt
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2.100 SECTION 2 TABLE 2.21 Transmit
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2.102 SECTION 2 2.2 MATHEMATICAL TA
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2.104 SECTION 2 TABLE 2.23 Derivati
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2.106 SECTION 2 TABLE 2.24 Integral
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2.108 SECTION 2 TABLE 2.24 Integral
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2.110 SECTION 2 Regular Polygon of
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2.112 SECTION 2 A h[0.4(y y ) 1.
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2.114 SECTION 2 2.2.3.1 Signs of th
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2.116 SECTION 2 x2 x3 x4 x5 ln(1 x
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2.118 SECTION 2 2.3.2 Errors in Qua
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2.120 SECTION 2 The breadth or spre
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2.122 SECTION 2 TABLE 2.26b Areas U
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2.124 SECTION 2 The distribution of
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2.126 SECTION 2 Should there be mor
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2.128 SECTION 2 Example 10 Six samp
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PROPERTIES OF ATOMS, RADICALS, AND
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SECTION 5 PHYSICAL PROPERTIES 5.1 S
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PHYSICAL PROPERTIES 5.3 5.1 SOLUBIL
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TABLE 5.1 Solubility of Gases in Wa
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TABLE 5.1 Solubility of Gases in Wa
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TABLE 5.2 Solubilities of Inorganic
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formateBa(CHO 2 ) 2 26.2 28.0 29.9
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(III) sulfateCe 2 (SO 4 ) 3 ·9H 2
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iodidePbI 2 0.044 0.056 0.069 0.090
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Nickel sulfateNiSO 4 ·6H 2 O (pale
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Praseodymium bromatePr(BrO 3 ) 3 55
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formate NaCHO 2 43.9 62.5 81.2 102
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Uranyl nitrate UO 2 (NO 3 ) 2 98 10
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PHYSICAL PROPERTIES 5.25 TABLE 5.3
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PHYSICAL PROPERTIES 5.57 5.3 BOILIN
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TABLE 5.12 Ternary Azeotropic Mixtu
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TABLE 5.12 Ternary Azeotropic Mixtu
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PHYSICAL PROPERTIES 5.83 5.4 FREEZI
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PHYSICAL PROPERTIES 5.87 5.5 DENSIT
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PHYSICAL PROPERTIES 5.89 dt Dt P
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PHYSICAL PROPERTIES 5.135 5.6.1 Ref
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PHYSICAL PROPERTIES 5.137 where the
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PHYSICAL PROPERTIES 5.139 5.7 COMBU
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Temperature, C Substance 40 20 0 20
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PHYSICAL PROPERTIES 5.171 This equa
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SECTION 6 THERMODYNAMIC PROPERTIES
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THERMODYNAMICPROPERTIES 6.3 6.1.1.2
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THERMODYNAMICPROPERTIES 6.5 A gener
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THERMODYNAMICPROPERTIES 6.7 TABLE 6
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THERMODYNAMICPROPERTIES 6.9 TABLE 6
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THERMODYNAMICPROPERTIES 6.11 TABLE
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THERMODYNAMIC PROPERTIES 6.21 TABLE
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THERMODYNAMIC PROPERTIES 6.101 TABL
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THERMODYNAMIC PROPERTIES 6.143 The
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SECTION 7 SPECTROSCOPY 7.1 X-RAY ME
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SPECTROSCOPY 7.3 TABLE 7.1 Waveleng
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SPECTROSCOPY 7.9 TABLE 7.3 Critical
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SPECTROSCOPY 7.11 TABLE 7.4 X-Ray E
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SPECTROSCOPY 7.13 Emission line K 1
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SPECTROSCOPY 7.15 TABLE 7.7 Analyzi
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SPECTROSCOPY 7.17 TABLE 7.8 Mass Ab
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SPECTROSCOPY 7.19 TABLE 7.9 Electro
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SPECTROSCOPY 7.21 TABLE 7.11 Absorp
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SPECTROSCOPY 7.23 TABLE 7.13 Solven
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SPECTROSCOPY 7.25 7.3 FLUORESCENCE
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SPECTROSCOPY 7.27 TABLE 7.16 Fluore
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SPECTROSCOPY 7.29 TABLE 7.18 Detect
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SPECTROSCOPY 7.35 TABLE 7.19 Sensit
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SPECTROSCOPY 7.37 TABLE 7.19 Sensit
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SPECTROSCOPY 7.39 In terms of m ,
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SPECTROSCOPY 7.41 The ionization co
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SPECTROSCOPY 7.67 TABLE 7.28 Infrar
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7.69
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SPECTROSCOPY 7.71 7.6 RAMAN SPECTRO
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SPECTROSCOPY 7.73 TABLE 7.30 Raman
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SPECTROSCOPY 7.89 7.7 NUCLEAR MAGNE
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SPECTROSCOPY 7.91 TABLE 7.41 Nuclea
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SPECTROSCOPY 7.93 TABLE 7.42 Proton
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SPECTROSCOPY 7.95 TABLE 7.44 Estima
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SPECTROSCOPY 7.97 TABLE 7.46 Proton
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SPECTROSCOPY 7.99 TABLE 7.48 Solven
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SPECTROSCOPY 7.101 TABLE 7.49 Carbo
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SPECTROSCOPY 7.103 TABLE 7.51 Effec
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SPECTROSCOPY 7.107 TABLE 7.56 One-B
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SPECTROSCOPY 7.113 TABLE 7.63 Nitro
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SPECTROSCOPY 7.115 TABLE 7.64 Nitro
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SPECTROSCOPY 7.117 TABLE 7.69 Fluor
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SPECTROSCOPY 7.119 TABLE 7.72 Silic
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SPECTROSCOPY 7.121 TABLE 7.73 Phosp
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SPECTROSCOPY 7.123 TABLE 7.74 Phosp
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SPECTROSCOPY 7.125 when z 3 and y
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SPECTROSCOPY 7.127 Masses 19 and 31
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SPECTROSCOPY 7.129 TABLE 7.76 Conde
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SECTION 8 ELECTROLYTES, ELECTROMOTI
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ELECTROLYTES, EMF, AND CHEMICAL EQU
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TABLE 8.7 Proton Transfer Reactions
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TABLE 8.7 Proton Transfer Reactions
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TABLE 8.9 Selected Equilibrium Cons
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8.75 3-tert-Butylbenzoic acid (0) 4
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4-Hydroxyproline (1) 1.900 1C 1.850
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N-Propionylglycine (1) 3.728 3.723
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TABLE 8.14 National Bureau of Stand
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1 part 0.1% neutral red in alc. * V
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3,3-Dimethoxybenzidine dihydrochlor
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TABLE 8.35 Equivalent Conductivitie
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KCl 127.3 124.4 122.4 115.8 112.0 1
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NaIO 3 75.2 72.6 70.9 64.4 60.5 1
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9.2 SECTION 9 9.1 LINEAR FREE ENERG
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9.4 SECTION 9 TABLE 9.1 Hammett and
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9.6 SECTION 9 TABLE 9.1 Hammett and
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9.8 SECTION 9 TABLE 9.3 pK a and Rh
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10.2 SECTION 10 10.4.6 Polyacrylate
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10.4 SECTION 10 10.2 ADDITIVES TO P
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10.6 SECTION 10 injection molding.
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10.8 SECTION 10 10.3 FORMULAS AND K
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10.10 SECTION 10 Key properties of
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10.12 SECTION 10 10.3.8 Fluorocarbo
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10.14 SECTION 10 10.3.11 Phenolics
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10.16 SECTION 10 The resin has the
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10.18 SECTION 10 10.3.19 Polyuretha
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10.20 SECTION 10 10.3.22 Sulfones B
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TABLE 10.2 Properties of Commercial
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10.58 SECTION 10 10.4 FORMULAS AND
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10.60 SECTION 10 10.4.8 Polychlorop
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10.62 SECTION 10 Styrene-butadiene
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10.5 CHEMICAL RESISTANCE TABLE 10.4
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10.6 GAS PERMEABILITY TABLE 10.5 Ga
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TABLE 10.5 Gas Permeability Constan
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TABLE 10.7 Constants ofFats and Oil
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TABLE 10.8 Constants ofWaxes Wax Me
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SECTION 11 PRACTICAL LABORATORY INF
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11.4 SECTION 11 TABLE 11.2 Molecula
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11.6 SECTION 11 A saturated aqueous
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11.8 SECTION 11 TABLE 11.6 Relative
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11.10 SECTION 11 11.3 BOILING POINT
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11.12 SECTION 11 TABLE 11.8 Organic
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11.14 SECTION 11 TABLE 11.9 Molecul
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11.4 SEPARATION METHODS TABLE 11.11
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11.18 SECTION 11 TABLE 11.12 Solven
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11.20 SECTION 11 TABLE 11.12 Solven
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TABLE 11.13 McReynolds’ Constants
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TABLE 11.13 McReynolds’ Constants
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11.26 SECTION 11 11.4.1 McReynolds
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11.28 SECTION 11 11.4.2.2 Partition
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11.30 SECTION 11 FIGURE 11.2 Band a
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11.32 SECTION 11 11.4.3 Ion-Exchang
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11.34 SECTION 11 TABLE 11.16 Guide
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11.36 SECTION 11 TABLE 11.16 Guide
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11.38 SECTION 11 TABLE 11.18 Relati
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11.40 SECTION 11 distribution coeff
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11.42 SECTION 11 TABLE 11.19 Gravim
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11.68 SECTION 11 TABLE 11.20 Elemen
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11.70 SECTION 11 TABLE 11.22 Common
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11.72 SECTION 11 TABLE 11.25 Tolera
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11.74 SECTION 11 TABLE 11.26 Heatin
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11.76 SECTION 11 TABLE 11.28 Titrim
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11.84 SECTION 11 appears becomes le
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11.86 SECTION 11 TABLE 11.29 Equati
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11.88 SECTION 11 TABLE 11.29 Equati
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11.90 SECTION 11 The more stable th
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11.92 SECTION 11 11.6.6.2.5 Buffer
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11.94 SECTION 11 TABLE 11.30 Standa
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TABLE 11.32 Properties and Applicat
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11.98 SECTION 11 TABLE 11.36 Maskin
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11.100 SECTION 11 TABLE 11.37 Anion
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11.102 SECTION 11 TABLE 11.39 Amino
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11.104 SECTION 11 TABLE 11.44 Facto
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11.106 SECTION 11 11.7 LABORATORY S
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11.108 SECTION 11 TABLE 11.48 Stand
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11.110 SECTION 11 Alizarin yellow G
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11.112 SECTION 11 Bromchlorophenol
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11.114 SECTION 11 p-Ethoxychrysoidi
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11.116 SECTION 11 Mercurous nitrate
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11.118 SECTION 11 Potassium carbona
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11.120 SECTION 11 until the ammoniu
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11.122 SECTION 11 TABLE 11.49 TLV C
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11.130 SECTION 11 TABLE 11.50 Chemi
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11.138 SECTION 11 of water which is
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TABLE 11.55 Thermoelectric Values i
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TABLE 11.56 Type B Thermocouples: P
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TABLE 11.58 Type J Thermocouples: I
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TABLE 11.60 Type N Thermocouples: N
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TABLE 11.62 Type S Thermocouples: P
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11.150 SECTION 11 11.11 CORRECTION
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Index Terms Links 2 Acid-base indic
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Index Terms Links 4 Alkynes, nomenc
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Index Terms Links 6 Aurintricarboxy
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Index Terms Links 8 Boron-11 chemic
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Index Terms Links 10 Cellulose acet
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Index Terms Links 12 Collective ino
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Index Terms Links 14 Degree Fahrenh
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Index Terms Links 16 Electrical res
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Index Terms Links 18 Equivalent wei
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Index Terms Links 20 Fluorocarbon p
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Index Terms Links 22 Halogenated hy
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Index Terms Links 24 Impact strengt
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Index Terms Links 26 Kα 1 lines, m
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Index Terms Links 28 Melmine phenol
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Index Terms Links 30 Neon-neon bond
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Index Terms Links 32 One-tailed tes
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Index Terms Links 34 Physical chemi
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Index Terms Links 36 Polyolefin the
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Index Terms Links 38 Pyridine: bina
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Index Terms Links 40 Rho values: fo
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Index Terms Links 42 Single-bond ra
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Index Terms Links 44 Stereoisomers
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Index Terms Links 46 Tension, aqueo
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Index Terms Links 48 Triethylenetet
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Index Terms Links 50 Water (Cont.)
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