preface to fifteenth edition

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TABLE 3.2 Physical Constants of Inorganic Compounds (Continued) Name Formula Formula weight Density Melting point, C Boiling point, C Solubility in 100 parts solvent 3.18 Arsenic (continued) (III)oxide (claudetite) As 2 O 3 197.84 3.74 313 460 sl s aq; s dil acid, alk (V)oxide As 2 O 5 229.84 4.32 315 d 800 66 g/100 mL 20 aq; s alc (III)selenide As 2 Se 3 386.72 4.75 260 s alkali, HNO 3 (III)sulfide As 2 S 3 246.04 3.460 310 707 i aq; s alk, slowly s hot HCl (V)sulfide As 2 S 5 310.17 subl 500 0.0003 aq; s alkali, HNO 3 (III)telluride As 2 Te 3 532.64 6.50 621 Astatine At 210 302 Barium Ba 137.33 3.51 20 726.9 1845 d aq to Ba(OH) acetate hydrate Ba(C 2 H 3 O 2 ) 2 ·H 2 O 273.43 2.19 anhyd 110 d 150 58.8 g/100 mL 0 aq; 0.014 alc benzenesulfonate Ba(O 3 SC 6 H 5 ) 2 451.70 s aq; sl s alc bromate hydrate Ba(BrO 3 ) 2 ·H 2 O 411.14 3.99 18 d 260 0.96 30 aq; s acet; i alc bromide BaBr 2 297.14 4.781 856 1835 92 g/100 mL 0 aq; s MeOH, acet carbonate BaCO 3 197.34 4.2865 d 1300 to BaO 0.0024 aq; s acids CO 2 chlorate hydrate Ba(ClO 3 ) 2 ·H 2 O 322.24 3.179 anhyd 120 O 2 , 250 34 g/100 mL 20 aq; sl s alc, acet chloride BaCl 2 208.24 3.856 24 962 1560 36 g/100 mL 20 aq; s MeOH; i acet, EtAc chloride dihydrate BaCl 2 ·2H 2 O 244.26 3.097 anhyd 113 31.7 g/100 mL 0 aq chromate(VI)BaCrO 4 253.33 4.498 20 d 0.001 20 aq; s mineral acids cyanide Ba(CN) 2 189.36 80 g/100 mL 14 aq; s alc fluoride BaF 2 175.32 4.89 1368 2260 0.161 20 aq; s acids hexafluorosilicate Ba[SiF 6 ] 279.40 4.29 21 4 d 300 0.0235 25 aq;sNH 4 Cl soln; i alc hydrogen phosphate BaHPO 4 233.31 4.165 15 d 410 0.01 aq; s HCl, HNO 3 hydroxide 8-water Ba(OH) 2 ·8H 2 O 315.48 2.18 16 78 3.9 20 aq iodate Ba(IO 3 ) 2 487.13 5.23 20 d 476 0.033 20 aq; s HCl iodide BaI 2 391.14 5.15 711 2027 169 g/100 mL 20 aq; s alc, acet manganate(VI)(2)BaMnO 4 256.26 4.85 disprop to Ba(MnO 4 ) 2 MnO 2 molybdate BaMoO 4 297.27 4.975 1450 0.0058 25 aq niobate Ba(NbO 3 ) 2 419.14 5.44 1455 i aq nitrate Ba(NO 3 ) 2 261.34 3.24 23 592 d 5.0 aq; v sl s alc, acet nitrite hydrate Ba(NO 2 ) 2 ·H 2 O 247.35 3.173 30 d 115 54.8 g/100 mL 0 aq; i alc
3.19 oxalate BaC 2 O 4 225.35 2.658 400 d i aq oxide BaO 153.33 5.72 1973 3088 3.5 20 aq; s acids, EtOH perchlorate Ba(ClO 4 ) 2 336.23 3.20 505 g/100 mL 25 : 129 aq, 78 EtOH, 42 BuOH, 81 EtOAc; i eth perchlorate 3-water Ba(ClO 4 ) 2 ·3H 2 O 390.27 2.74 d 400 198 g/100 mL 25 aq; s MeOH; sl s acet permanganate Ba(MnO 4 ) 2 375.20 3.77 d 200 v s aq peroxide BaO 2 169.33 4.96 450 d O 2 , 800 1.5 0 aq selenide BaSe 216.29 5.02 1780 d aq stearate Ba(C 18 H 35 O 2 ) 2 704.28 1.145 160 i aq sulfate BaSO 4 233.39 4.50 15 1580 d 1600 0.00285 aq sulfide BaS 169.39 4.25 15 2230 7.9 20 aq; dec in acids sulfite BaSO 3 217.39 4.44 d 0.02 0 aq; i alc tetracyanoplatinate(II)- Ba[Pt(CN) 4 ]·4H 2 O 508.54 2.076 2.86 aq; i alc 4-water thiocyanate 2-water Ba(SCN) 2 ·2H 2 O 289.53 2.286 18 d 160 170 g/100 mL 20 aq; s alc, acet thiosulfate hydrate BaS 2 O 3 ·H 2 O 267.47 3.5 18 d 220 0.21 20 aq; i alc, acet, eth, CS titanate(IV)(2)BaTiO 3 233.19 6.02 1625 i aq vanadate Ba 3 (VO 4 ) 2 641.86 5.14 707 zirconate BaZrO 3 276.55 5.52 2500 i aq, alk; sl s acids Berkelium ( form)Bk 247 14.78 1050 ( form)Bk 247 13.25 986 Beryllium Be 9.012 1.8477 20 1287 2467 i aq; s acid, alk bromide BeBr 2 168.82 3.465 25 508 521 v s aq; s alc; 18.6 pyr carbide Be 2 C 30.04 1.90 15 d 2127 d aq; s acids, alkali giving CH 4 chloride BeCl 2 79.92 1.899 25 415 (alpha)482.3 42 g/100 mL aq; s alc, eth, pyr, CS 2 fluoride BeF 2 47.01 1.986 555 subl 1036 1mm v s aq (slowly) hydride BeH 2 11.03 0.65 H 2 , 220 d aq (slowly), acids (rapidly) hydroxide Be(OH) 2 43.03 1.909 93 s hot conc acids and alkali (viol) iodide BeI 2 262.82 4.32 480 487 hyd aq violently; s alc, eth, CS 2 nitrate 3-water Be(NO 3 ) 2 ·3H 2 O 187.07 1.557 60.5 d 125 166 g/100 mL 20 aq nitride Be 3 N 2 55.05 2.71 2200 d hot aq, alkali oxide BeO 25.01 3.025 2578 (alpha)3787 s conc H 2 SO 4 selenate 4-water BeSeO 4 ·4H 2 O 224.03 2.03 anhyd 300 d 560 49 g/100 mL 25 aq silicate Be 2 SiO 4 110.11 3.0 1560 i aq sulfate 4-water BeSO 4 ·4H 2 O 177.14 1.713 anhyd 270 d 580 39 g/100 mL 20 aq; i alc sulfide BeS 41.08 2.36 d i aq; s HNO 3
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LANGE'S HANDBOOK OF CHEMISTRY John
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Grateful acknowledgment is hereby m
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PREFACE TO FIFTEENTH EDITION This n
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PREFACE TO FIFTEENTH EDITION ix inv
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xii PREFACE TO FOURTEENTH EDITION l
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PREFACE TO FIRST EDITION This book
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For the detailed contents of any se
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1.2 SECTION 1 is derived from the G
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1.4 SECTION 1 rather than methylide
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1.6 SECTION 1 Styrene Toluene Xylen
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1.8 SECTION 1 TABLE 1.2 Fused Polyc
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1.10 SECTION 1 1.1.1.6 Bridged Hydr
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1.12 SECTION 1 TABLE 1.4 Suffixes f
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1.14 SECTION 1 TABLE 1.5 Trivial Na
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1.16 SECTION 1 TABLE 1.6 Trivial Na
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1.18 SECTION 1 Selection of the pri
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1.20 SECTION 1 attached to one anot
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1.22 SECTION 1 When side chains of
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1.24 SECTION 1 heterocyclic structu
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1.26 SECTION 1 Bivalent radicals of
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1.28 SECTION 1 Complex linear polya
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1.30 SECTION 1 TABLE 1.11 Names of
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1.32 SECTION 1 hydroxyamino- to the
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1.34 SECTION 1 may be named (1) by
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1.36 SECTION 1 Examples are methyl
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1.38 SECTION 1 tuted acid, respecti
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1.40 SECTION 1 FIGURE 1.2 Newman pr
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1.42 SECTION 1 from the ring are kn
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1.44 SECTION 1 FIGURE 1.11 Two isom
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1.46 SECTION 1 Chiral Center. The c
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1.48 SECTION 1 FIGURE 1.15 Isomers
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1.50 SECTION 1 entries to bring tog
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1.52 SECTION 1 TABLE 1.13 Names and
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1.60 SECTION 1 TABLE 1.14 Empirical
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2.2 SECTION 2 2.3.6 Student’s Dis
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2.4 SECTION 2 TABLE 2.1 Fundamental
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2.6 SECTION 2 TABLE 2.1 Fundamental
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2.8 SECTION 2 TABLE 2.2 Physical an
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2.10 SECTION 2 TABLE 2.2 Physical a
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2.24 SECTION 2 TABLE 2.3 Mathematic
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2.26 SECTION 2 TABLE 2.6 Abbreviati
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2.36 SECTION 2 TABLE 2.7 Conversion
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2.54 SECTION 2 TABLE 2.8 Temperatur
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2.66 SECTION 2 2.1.1 Conversion of
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2.68 SECTION 2 Oleometer. A hydrome
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2.70 SECTION 2 Example 3. 25 1.2500
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2.72 SECTION 2 TABLE 2.9 Barometer
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2.74 SECTION 2 TABLE 2.9 Barometer
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2.76 SECTION 2 TABLE 2.10 Barometri
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2.78 SECTION 2 TABLE 2.12 Reduction
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2.80 SECTION 2 TABLE 2.12 Reduction
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2.82 SECTION 2 TABLE 2.13 Viscosity
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2.84 SECTION 2 TABLE 2.14 Conversio
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2.86 SECTION 2 TABLE 2.15 Hydromete
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2.88 SECTION 2 TABLE 2.17 Correctio
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2.90 SECTION 2 TABLE 2.18 Pressure
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2.96 SECTION 2 TABLE 2.20 Values of
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2.98 SECTION 2 TABLE 2.21 Transmitt
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2.100 SECTION 2 TABLE 2.21 Transmit
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2.102 SECTION 2 2.2 MATHEMATICAL TA
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2.104 SECTION 2 TABLE 2.23 Derivati
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Silver (argentum) Ag 47 [Kr] 4d 10
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PROPERTIES OF ATOMS,RADICALS,AND BO
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PROPERTIES OF ATOMS, RADICALS, AND
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SECTION 5 PHYSICAL PROPERTIES 5.1 S
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PHYSICAL PROPERTIES 5.3 5.1 SOLUBIL
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TABLE 5.1 Solubility of Gases in Wa
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TABLE 5.1 Solubility of Gases in Wa
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TABLE 5.2 Solubilities of Inorganic
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formateBa(CHO 2 ) 2 26.2 28.0 29.9
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(III) sulfateCe 2 (SO 4 ) 3 ·9H 2
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iodidePbI 2 0.044 0.056 0.069 0.090
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Nickel sulfateNiSO 4 ·6H 2 O (pale
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Praseodymium bromatePr(BrO 3 ) 3 55
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formate NaCHO 2 43.9 62.5 81.2 102
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Uranyl nitrate UO 2 (NO 3 ) 2 98 10
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PHYSICAL PROPERTIES 5.25 TABLE 5.3
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PHYSICAL PROPERTIES 5.57 5.3 BOILIN
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TABLE 5.12 Ternary Azeotropic Mixtu
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TABLE 5.12 Ternary Azeotropic Mixtu
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PHYSICAL PROPERTIES 5.83 5.4 FREEZI
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PHYSICAL PROPERTIES 5.87 5.5 DENSIT
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PHYSICAL PROPERTIES 5.89 dt Dt P
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PHYSICAL PROPERTIES 5.135 5.6.1 Ref
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PHYSICAL PROPERTIES 5.137 where the
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PHYSICAL PROPERTIES 5.139 5.7 COMBU
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Temperature, C Substance 40 20 0 20
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PHYSICAL PROPERTIES 5.171 This equa
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SECTION 6 THERMODYNAMIC PROPERTIES
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THERMODYNAMICPROPERTIES 6.3 6.1.1.2
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THERMODYNAMICPROPERTIES 6.5 A gener
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THERMODYNAMICPROPERTIES 6.7 TABLE 6
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THERMODYNAMICPROPERTIES 6.9 TABLE 6
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THERMODYNAMICPROPERTIES 6.11 TABLE
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THERMODYNAMIC PROPERTIES 6.21 TABLE
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THERMODYNAMIC PROPERTIES 6.101 TABL
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THERMODYNAMIC PROPERTIES 6.143 The
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SECTION 7 SPECTROSCOPY 7.1 X-RAY ME
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SPECTROSCOPY 7.3 TABLE 7.1 Waveleng
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SPECTROSCOPY 7.9 TABLE 7.3 Critical
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SPECTROSCOPY 7.11 TABLE 7.4 X-Ray E
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SPECTROSCOPY 7.13 Emission line K 1
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SPECTROSCOPY 7.15 TABLE 7.7 Analyzi
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SPECTROSCOPY 7.17 TABLE 7.8 Mass Ab
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SPECTROSCOPY 7.19 TABLE 7.9 Electro
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SPECTROSCOPY 7.21 TABLE 7.11 Absorp
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SPECTROSCOPY 7.23 TABLE 7.13 Solven
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SPECTROSCOPY 7.25 7.3 FLUORESCENCE
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SPECTROSCOPY 7.27 TABLE 7.16 Fluore
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SPECTROSCOPY 7.29 TABLE 7.18 Detect
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SPECTROSCOPY 7.35 TABLE 7.19 Sensit
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SPECTROSCOPY 7.37 TABLE 7.19 Sensit
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SPECTROSCOPY 7.39 In terms of m ,
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SPECTROSCOPY 7.41 The ionization co
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SPECTROSCOPY 7.67 TABLE 7.28 Infrar
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7.69
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SPECTROSCOPY 7.71 7.6 RAMAN SPECTRO
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SPECTROSCOPY 7.73 TABLE 7.30 Raman
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SPECTROSCOPY 7.89 7.7 NUCLEAR MAGNE
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SPECTROSCOPY 7.91 TABLE 7.41 Nuclea
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SPECTROSCOPY 7.93 TABLE 7.42 Proton
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SPECTROSCOPY 7.95 TABLE 7.44 Estima
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SPECTROSCOPY 7.97 TABLE 7.46 Proton
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SPECTROSCOPY 7.99 TABLE 7.48 Solven
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SPECTROSCOPY 7.101 TABLE 7.49 Carbo
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SPECTROSCOPY 7.103 TABLE 7.51 Effec
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SPECTROSCOPY 7.107 TABLE 7.56 One-B
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SPECTROSCOPY 7.113 TABLE 7.63 Nitro
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SPECTROSCOPY 7.115 TABLE 7.64 Nitro
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SPECTROSCOPY 7.117 TABLE 7.69 Fluor
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SPECTROSCOPY 7.119 TABLE 7.72 Silic
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SPECTROSCOPY 7.121 TABLE 7.73 Phosp
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SPECTROSCOPY 7.123 TABLE 7.74 Phosp
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SPECTROSCOPY 7.125 when z 3 and y
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SPECTROSCOPY 7.127 Masses 19 and 31
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SPECTROSCOPY 7.129 TABLE 7.76 Conde
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SECTION 8 ELECTROLYTES, ELECTROMOTI
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ELECTROLYTES, EMF, AND CHEMICAL EQU
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TABLE 8.7 Proton Transfer Reactions
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TABLE 8.7 Proton Transfer Reactions
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TABLE 8.9 Selected Equilibrium Cons
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8.75 3-tert-Butylbenzoic acid (0) 4
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4-Hydroxyproline (1) 1.900 1C 1.850
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N-Propionylglycine (1) 3.728 3.723
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TABLE 8.14 National Bureau of Stand
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1 part 0.1% neutral red in alc. * V
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3,3-Dimethoxybenzidine dihydrochlor
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TABLE 8.35 Equivalent Conductivitie
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KCl 127.3 124.4 122.4 115.8 112.0 1
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NaIO 3 75.2 72.6 70.9 64.4 60.5 1
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9.2 SECTION 9 9.1 LINEAR FREE ENERG
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9.4 SECTION 9 TABLE 9.1 Hammett and
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9.6 SECTION 9 TABLE 9.1 Hammett and
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9.8 SECTION 9 TABLE 9.3 pK a and Rh
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10.2 SECTION 10 10.4.6 Polyacrylate
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10.4 SECTION 10 10.2 ADDITIVES TO P
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10.6 SECTION 10 injection molding.
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10.8 SECTION 10 10.3 FORMULAS AND K
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10.10 SECTION 10 Key properties of
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10.12 SECTION 10 10.3.8 Fluorocarbo
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10.14 SECTION 10 10.3.11 Phenolics
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10.16 SECTION 10 The resin has the
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10.18 SECTION 10 10.3.19 Polyuretha
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10.20 SECTION 10 10.3.22 Sulfones B
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TABLE 10.2 Properties of Commercial
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10.58 SECTION 10 10.4 FORMULAS AND
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10.60 SECTION 10 10.4.8 Polychlorop
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10.62 SECTION 10 Styrene-butadiene
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10.5 CHEMICAL RESISTANCE TABLE 10.4
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10.6 GAS PERMEABILITY TABLE 10.5 Ga
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TABLE 10.5 Gas Permeability Constan
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TABLE 10.7 Constants ofFats and Oil
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TABLE 10.8 Constants ofWaxes Wax Me
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SECTION 11 PRACTICAL LABORATORY INF
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11.4 SECTION 11 TABLE 11.2 Molecula
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11.6 SECTION 11 A saturated aqueous
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11.8 SECTION 11 TABLE 11.6 Relative
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11.10 SECTION 11 11.3 BOILING POINT
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11.12 SECTION 11 TABLE 11.8 Organic
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11.14 SECTION 11 TABLE 11.9 Molecul
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11.4 SEPARATION METHODS TABLE 11.11
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11.18 SECTION 11 TABLE 11.12 Solven
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11.20 SECTION 11 TABLE 11.12 Solven
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TABLE 11.13 McReynolds’ Constants
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TABLE 11.13 McReynolds’ Constants
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11.26 SECTION 11 11.4.1 McReynolds
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11.28 SECTION 11 11.4.2.2 Partition
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11.30 SECTION 11 FIGURE 11.2 Band a
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11.32 SECTION 11 11.4.3 Ion-Exchang
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11.34 SECTION 11 TABLE 11.16 Guide
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11.36 SECTION 11 TABLE 11.16 Guide
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11.38 SECTION 11 TABLE 11.18 Relati
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11.40 SECTION 11 distribution coeff
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11.42 SECTION 11 TABLE 11.19 Gravim
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11.68 SECTION 11 TABLE 11.20 Elemen
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11.70 SECTION 11 TABLE 11.22 Common
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11.72 SECTION 11 TABLE 11.25 Tolera
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11.74 SECTION 11 TABLE 11.26 Heatin
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11.76 SECTION 11 TABLE 11.28 Titrim
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11.84 SECTION 11 appears becomes le
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11.86 SECTION 11 TABLE 11.29 Equati
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11.88 SECTION 11 TABLE 11.29 Equati
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11.90 SECTION 11 The more stable th
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11.92 SECTION 11 11.6.6.2.5 Buffer
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11.94 SECTION 11 TABLE 11.30 Standa
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TABLE 11.32 Properties and Applicat
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11.98 SECTION 11 TABLE 11.36 Maskin
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11.100 SECTION 11 TABLE 11.37 Anion
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11.102 SECTION 11 TABLE 11.39 Amino
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11.104 SECTION 11 TABLE 11.44 Facto
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11.106 SECTION 11 11.7 LABORATORY S
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11.108 SECTION 11 TABLE 11.48 Stand
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11.110 SECTION 11 Alizarin yellow G
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11.112 SECTION 11 Bromchlorophenol
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11.114 SECTION 11 p-Ethoxychrysoidi
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11.116 SECTION 11 Mercurous nitrate
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11.118 SECTION 11 Potassium carbona
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11.120 SECTION 11 until the ammoniu
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11.122 SECTION 11 TABLE 11.49 TLV C
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11.130 SECTION 11 TABLE 11.50 Chemi
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11.138 SECTION 11 of water which is
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TABLE 11.55 Thermoelectric Values i
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TABLE 11.56 Type B Thermocouples: P
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TABLE 11.58 Type J Thermocouples: I
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TABLE 11.60 Type N Thermocouples: N
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TABLE 11.62 Type S Thermocouples: P
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11.150 SECTION 11 11.11 CORRECTION
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Index Terms Links 2 Acid-base indic
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Index Terms Links 4 Alkynes, nomenc
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Index Terms Links 6 Aurintricarboxy
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Index Terms Links 8 Boron-11 chemic
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Index Terms Links 10 Cellulose acet
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Index Terms Links 12 Collective ino
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Index Terms Links 14 Degree Fahrenh
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Index Terms Links 16 Electrical res
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Index Terms Links 18 Equivalent wei
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Index Terms Links 20 Fluorocarbon p
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Index Terms Links 22 Halogenated hy
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Index Terms Links 24 Impact strengt
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Index Terms Links 26 Kα 1 lines, m
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Index Terms Links 28 Melmine phenol
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Index Terms Links 30 Neon-neon bond
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Index Terms Links 32 One-tailed tes
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Index Terms Links 34 Physical chemi
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Index Terms Links 36 Polyolefin the
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Index Terms Links 38 Pyridine: bina
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Index Terms Links 40 Rho values: fo
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Index Terms Links 42 Single-bond ra
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Index Terms Links 44 Stereoisomers
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Index Terms Links 46 Tension, aqueo
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Index Terms Links 48 Triethylenetet
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Index Terms Links 50 Water (Cont.)
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