preface to fifteenth edition

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TABLE 3.2 Physical Constants of Inorganic Compounds (Continued) Name Formula Formula weight Density Melting point, C Boiling point, C Solubility in 100 parts solvent 3.26 Chromium (continued) (III) phosphate CrPO 4 146.97 4.6 1800 i aq, acids, aq reg potassium bissulfate CrK(SO 4 ) 2 · 12H 2 O 499.41 1.826 25 89 anhyd 400 22 g/100 mL 25 aq; i alc 12-water (II) sulfate 7-water CrSO 4 ·7H 2 O 274.17 22.9 g/100 mL 0 aq; sl s alc (III) sulfate 18-water Cr 2 (SO 4 ) 3 · 18H 2 O 716.45 1.7 d 100 220 g/100 mL 20 aq Chromyl chloride CrO 2 Cl 2 154.90 25 1.9145 4 96.5 117 d aq; s bz, chl, eth, CCl 4 fluoride CrO 2 F 2 121.99 31.6 885mm subl 29.6 Cobalt Co 58.9332 8.90 1494 2927 i aq; s dil HNO 3 (II) acetate 4-water Co(C 2 H 3 O 2 ) 2 ·4H 2 O 249.08 1.705 19 anhyd 140 s aq; 2.1 g/100 mL 15 MeOH (III) acetate Co(C 2 H 3 O 2 ) 3 236.07 d 100 s aq, HOAc, alc (II) bromide CoBr 2 218.74 25 4.909 4 678 (in N 2 ) 112 g/100 mL 20 aq; s alc, acet (II) carbonate CoCO 3 118.94 4.13 d 0.18 15 aq; s hot acids (II) chloride CoCl 2 129.84 25 3.367 4 735 1049 53 g/100 mL 20 aq; s alc, acet, eth, glyc, pyr (II) chloride 6-water CoCl 2·6H 2 O 237.93 1.924 anhyd 110 97 g/100 mL 20 aq (II) chromate CoCrO 4 174.93 4.0 d i aq; s acids (II) cyanide Co(CN) 2 110.97 25 1.872 4 d 300 0.0042 18 aq; s KCN (II) fluoride CoF 3 96.93 4.46 1127 1400 1.36 20 aq; s warm mineral acids (III) fluoride CoF 3 115.93 3.88 926 d aq (II) formate 2-water Co(CHO 2 ) 2 ·2H 2 O 185.00 22 2.129 4 anhyd 140 d 175 5.03 g/100 mL 30 aq; i alc (II) hydroxide Co(OH) 2 92.95 3.37 168 (vacuo) 0.00018 aq; v s acids (III) hydroxide Co(OH) 3 109.96 4.46 H 2 O, 100 d 0.00032 aq; s acids (II) iodide (alpha, black) CoI 2 312.74 25 5.584 4 515 (vacuo) 570 (vacuo) 203 aq (II) nitrate 6-water Co(NO 3 ) 3 ·6H 2 O 291.03 1.88 55 d 74 155 g/100 mL 30 aq; v s alc (II) oxalate CoC 2 O 4 146.95 3.021 d 250 0.002 18 aq (II) oxide CoO 74.93 6.44 s1935 i aq; s acids, alkalis (II,III) oxide Co 3 O 4 240.80 6.07 d 900 i aq; s acids, alkalis (II) phosphate 8-water Co 3 (PO 4 ) 2 ·8H 2 O 510.87 2.769 anhyd 200 v sl s aq; s mineral acids (II) sulfate 7-water CoSO 4 ·7H 2 O 281.10 2.03 anhyd 420 d 1140 65 g/100 mL 20 aq; sl s alc (II) sulfide CoS 91.00 5.45 18 1180 i aq; s acids (II) thiocyanate 3-water Co(SCN) 2 ·3H 2 O 229.14 anhyd 105 7.8 18 aq; s alc, eth
3.27 Copper Cu 63.546 8.96 20 1084.62 2561.5 i; s HNO 3 , hot H 2 SO 4 (II) acetate 1-water Cu(C 2 H 3 O 2 )·H 2 O 199.65 1.882 115 d 240 8 g/100 mL aq; 0.48 MeOH; sl s eth acetate meta-arsenate (1/3) Cu(C 2 H 3 O 2 ) 2 · 3Cu(AsO 2 ) 2 1013.80 unstable in acids, bases; s NH 4 OH (II) borate(1) Cu(BO 2 ) 2 149.17 3.859 s a; i aq (I) bromide CuBr 143.45 4.98 497 1345 v sl s aq; s HCl, HBr, NH 4 OH (II) bromide CuBr 2 223.35 4.71 498 900 126 g/100 mL aq; s alc, acet, pyr; i bz (II) carbonate hydroxide CuCO 3 · Cu(OH) 2 221.12 4.0 d 200 i aq; s acids (1/1) (malachite) (II) chlorate 6-water Cu(ClO 3 ) 2 ·6H 2 O 338.54 65 d 100 242 g/100 mL 18 aq; v s alc; s acet (I) chloride CuCl 99.00 4.14 430 1400 0.024 aq; s conc HCl, conc NH 4 OH (II) chloride CuCl 2 134.45 3.386 300 d 73 g/100 mL 20 aq; s alc, acet (II) chloride 2-water CuCl 2 ·2H 2 O 170.48 2.51 anhyd 200 d 300 76.4 g/100 mL 25 aq; v s alc; s acet (I) chromium(III) Cr 2 O 3 ·Cu 2 O 295.07 5.24 20 d 900 i aq; s HNO 3 oxide (1/1) (II) citrate 2.5-water Cu 2 C 6 H 4 O 7 · 2.5H 2 O 360.22 anhyd 100 0.17 aq; s acids (I) cyanide CuCN 89.56 2.92 473 (in N 2 ) d iaq;sNH 4 OH, KCN; d hot dil HCl (II) fluoride CuF 2 101.54 4.23 836 1676 4.75 g/100 mL 20 aq; s acids (II) formate Cu(CHO 2 ) 2 153.58 1.831 12.5 aq (II) hexafluorosilicate Cu[SiF 6 ]·4H 2 O 277.60 2.56 d 124 g/100 mL 20 aq 4-water (II) hydroxide Cu(OH) 2 97.56 3.368 d 160 i aq; s acids (I) iodide CuI 190.45 5.67 606 1290 i aq; s KCN, NH 4 OH, KI (II) nitrate 3-water Cu(NO 3 ) 2 ·3H 2 O 241.60 2.32 114.5 170 d 138 g/100 mL 0 aq; v s alc (II) oleate Cu(OOCC 17 H 33 ) 2 626.46 i aq; sl s alc; s eth (II) oxalate hemihydrate CuC 2 O 4 · 0.5H 2 O 160.57 anhydr 200 d 310 0.002 aq; s NH 4 OH (I) oxide Cu 2 O 143.09 25 6.0 4 1235 O 2 , 1800 i aq; s HCl (II) oxide CuO 79.54 14 6.315 4 1450 i aq, alc; s acids, KCN (II) perchlorate Cu(ClO 4 ) 2 262.45 2.225 23 d 130 146 g/100 mL 30 aq; s eth, EtAc; i bz (II) phosphate 3-water Cu 3 (PO 4 ) 2 ·3H 2 O 434.63 d i aq; s acids (II) salicylate 4-water Cu(C 7 H 5 O 3 ) 2 ·4H 2 O 409.83 dehyd in air v s aq; s alc (II) selenate 5-water CuSeO 4 ·5H 2 O 296.58 2.559 anhyd 265 d ca. 480 25 g/100 mL 20 aq; v sl s acet (I) selenide Cu 2 Se 206.05 21 6.84 4 1113 d HCl (II) selenide CuSe 142.51 6.0 d 550 s acids (II) stearate Cu(OOCC 17 H 35 ) 2 630.50 250 i aq, alc, eth; s hot bz, pyr (II) sulfate CuSO 4 159.61 3.603 d 560 14.3 g/100 mL 0 aq; i alc (II) sulfate 5-water CuSO 4 ·5H 2 O 249.69 16 2.284 4 anhyd 200 32 g/100 mL 20 aq; s MeOH, glyc
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LANGE'S HANDBOOK OF CHEMISTRY John
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Grateful acknowledgment is hereby m
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PREFACE TO FIFTEENTH EDITION This n
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PREFACE TO FIFTEENTH EDITION ix inv
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xii PREFACE TO FOURTEENTH EDITION l
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PREFACE TO FIRST EDITION This book
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For the detailed contents of any se
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1.2 SECTION 1 is derived from the G
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1.4 SECTION 1 rather than methylide
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1.6 SECTION 1 Styrene Toluene Xylen
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1.8 SECTION 1 TABLE 1.2 Fused Polyc
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1.10 SECTION 1 1.1.1.6 Bridged Hydr
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1.12 SECTION 1 TABLE 1.4 Suffixes f
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1.14 SECTION 1 TABLE 1.5 Trivial Na
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1.16 SECTION 1 TABLE 1.6 Trivial Na
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1.18 SECTION 1 Selection of the pri
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1.20 SECTION 1 attached to one anot
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1.22 SECTION 1 When side chains of
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1.24 SECTION 1 heterocyclic structu
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1.26 SECTION 1 Bivalent radicals of
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1.28 SECTION 1 Complex linear polya
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1.30 SECTION 1 TABLE 1.11 Names of
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1.32 SECTION 1 hydroxyamino- to the
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1.34 SECTION 1 may be named (1) by
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1.36 SECTION 1 Examples are methyl
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1.38 SECTION 1 tuted acid, respecti
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1.40 SECTION 1 FIGURE 1.2 Newman pr
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1.42 SECTION 1 from the ring are kn
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1.44 SECTION 1 FIGURE 1.11 Two isom
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1.46 SECTION 1 Chiral Center. The c
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1.48 SECTION 1 FIGURE 1.15 Isomers
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1.50 SECTION 1 entries to bring tog
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1.52 SECTION 1 TABLE 1.13 Names and
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1.60 SECTION 1 TABLE 1.14 Empirical
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2.2 SECTION 2 2.3.6 Student’s Dis
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2.4 SECTION 2 TABLE 2.1 Fundamental
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2.6 SECTION 2 TABLE 2.1 Fundamental
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2.8 SECTION 2 TABLE 2.2 Physical an
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2.10 SECTION 2 TABLE 2.2 Physical a
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2.24 SECTION 2 TABLE 2.3 Mathematic
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2.26 SECTION 2 TABLE 2.6 Abbreviati
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2.36 SECTION 2 TABLE 2.7 Conversion
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2.54 SECTION 2 TABLE 2.8 Temperatur
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2.66 SECTION 2 2.1.1 Conversion of
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2.68 SECTION 2 Oleometer. A hydrome
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2.70 SECTION 2 Example 3. 25 1.2500
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2.72 SECTION 2 TABLE 2.9 Barometer
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2.74 SECTION 2 TABLE 2.9 Barometer
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2.76 SECTION 2 TABLE 2.10 Barometri
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2.78 SECTION 2 TABLE 2.12 Reduction
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2.80 SECTION 2 TABLE 2.12 Reduction
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2.82 SECTION 2 TABLE 2.13 Viscosity
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2.84 SECTION 2 TABLE 2.14 Conversio
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2.86 SECTION 2 TABLE 2.15 Hydromete
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2.88 SECTION 2 TABLE 2.17 Correctio
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2.90 SECTION 2 TABLE 2.18 Pressure
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2.96 SECTION 2 TABLE 2.20 Values of
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2.98 SECTION 2 TABLE 2.21 Transmitt
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2.100 SECTION 2 TABLE 2.21 Transmit
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2.102 SECTION 2 2.2 MATHEMATICAL TA
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2.104 SECTION 2 TABLE 2.23 Derivati
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2.106 SECTION 2 TABLE 2.24 Integral
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2.108 SECTION 2 TABLE 2.24 Integral
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2.110 SECTION 2 Regular Polygon of
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2.112 SECTION 2 A h[0.4(y y ) 1.
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PROPERTIES OF ATOMS,RADICALS,AND BO
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PROPERTIES OF ATOMS, RADICALS, AND
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SECTION 5 PHYSICAL PROPERTIES 5.1 S
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PHYSICAL PROPERTIES 5.3 5.1 SOLUBIL
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TABLE 5.1 Solubility of Gases in Wa
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TABLE 5.1 Solubility of Gases in Wa
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TABLE 5.2 Solubilities of Inorganic
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formateBa(CHO 2 ) 2 26.2 28.0 29.9
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(III) sulfateCe 2 (SO 4 ) 3 ·9H 2
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iodidePbI 2 0.044 0.056 0.069 0.090
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Nickel sulfateNiSO 4 ·6H 2 O (pale
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Praseodymium bromatePr(BrO 3 ) 3 55
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formate NaCHO 2 43.9 62.5 81.2 102
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Uranyl nitrate UO 2 (NO 3 ) 2 98 10
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PHYSICAL PROPERTIES 5.25 TABLE 5.3
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PHYSICAL PROPERTIES 5.57 5.3 BOILIN
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TABLE 5.12 Ternary Azeotropic Mixtu
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TABLE 5.12 Ternary Azeotropic Mixtu
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PHYSICAL PROPERTIES 5.83 5.4 FREEZI
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PHYSICAL PROPERTIES 5.87 5.5 DENSIT
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PHYSICAL PROPERTIES 5.89 dt Dt P
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PHYSICAL PROPERTIES 5.135 5.6.1 Ref
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PHYSICAL PROPERTIES 5.137 where the
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PHYSICAL PROPERTIES 5.139 5.7 COMBU
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Temperature, C Substance 40 20 0 20
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PHYSICAL PROPERTIES 5.171 This equa
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SECTION 6 THERMODYNAMIC PROPERTIES
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THERMODYNAMICPROPERTIES 6.3 6.1.1.2
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THERMODYNAMICPROPERTIES 6.5 A gener
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THERMODYNAMICPROPERTIES 6.7 TABLE 6
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THERMODYNAMICPROPERTIES 6.9 TABLE 6
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THERMODYNAMICPROPERTIES 6.11 TABLE
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THERMODYNAMIC PROPERTIES 6.21 TABLE
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THERMODYNAMIC PROPERTIES 6.101 TABL
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THERMODYNAMIC PROPERTIES 6.143 The
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SECTION 7 SPECTROSCOPY 7.1 X-RAY ME
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SPECTROSCOPY 7.3 TABLE 7.1 Waveleng
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SPECTROSCOPY 7.9 TABLE 7.3 Critical
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SPECTROSCOPY 7.11 TABLE 7.4 X-Ray E
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SPECTROSCOPY 7.13 Emission line K 1
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SPECTROSCOPY 7.15 TABLE 7.7 Analyzi
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SPECTROSCOPY 7.17 TABLE 7.8 Mass Ab
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SPECTROSCOPY 7.19 TABLE 7.9 Electro
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SPECTROSCOPY 7.21 TABLE 7.11 Absorp
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SPECTROSCOPY 7.23 TABLE 7.13 Solven
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SPECTROSCOPY 7.25 7.3 FLUORESCENCE
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SPECTROSCOPY 7.27 TABLE 7.16 Fluore
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SPECTROSCOPY 7.29 TABLE 7.18 Detect
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SPECTROSCOPY 7.35 TABLE 7.19 Sensit
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SPECTROSCOPY 7.37 TABLE 7.19 Sensit
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SPECTROSCOPY 7.39 In terms of m ,
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SPECTROSCOPY 7.41 The ionization co
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SPECTROSCOPY 7.67 TABLE 7.28 Infrar
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7.69
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SPECTROSCOPY 7.71 7.6 RAMAN SPECTRO
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SPECTROSCOPY 7.73 TABLE 7.30 Raman
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SPECTROSCOPY 7.89 7.7 NUCLEAR MAGNE
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SPECTROSCOPY 7.91 TABLE 7.41 Nuclea
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SPECTROSCOPY 7.93 TABLE 7.42 Proton
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SPECTROSCOPY 7.95 TABLE 7.44 Estima
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SPECTROSCOPY 7.97 TABLE 7.46 Proton
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SPECTROSCOPY 7.99 TABLE 7.48 Solven
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SPECTROSCOPY 7.101 TABLE 7.49 Carbo
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SPECTROSCOPY 7.103 TABLE 7.51 Effec
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SPECTROSCOPY 7.107 TABLE 7.56 One-B
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SPECTROSCOPY 7.113 TABLE 7.63 Nitro
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SPECTROSCOPY 7.115 TABLE 7.64 Nitro
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SPECTROSCOPY 7.117 TABLE 7.69 Fluor
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SPECTROSCOPY 7.119 TABLE 7.72 Silic
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SPECTROSCOPY 7.121 TABLE 7.73 Phosp
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SPECTROSCOPY 7.123 TABLE 7.74 Phosp
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SPECTROSCOPY 7.125 when z 3 and y
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SPECTROSCOPY 7.127 Masses 19 and 31
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SPECTROSCOPY 7.129 TABLE 7.76 Conde
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SECTION 8 ELECTROLYTES, ELECTROMOTI
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ELECTROLYTES, EMF, AND CHEMICAL EQU
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TABLE 8.7 Proton Transfer Reactions
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TABLE 8.7 Proton Transfer Reactions
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TABLE 8.9 Selected Equilibrium Cons
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8.75 3-tert-Butylbenzoic acid (0) 4
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4-Hydroxyproline (1) 1.900 1C 1.850
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N-Propionylglycine (1) 3.728 3.723
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TABLE 8.14 National Bureau of Stand
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1 part 0.1% neutral red in alc. * V
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3,3-Dimethoxybenzidine dihydrochlor
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TABLE 8.35 Equivalent Conductivitie
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KCl 127.3 124.4 122.4 115.8 112.0 1
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NaIO 3 75.2 72.6 70.9 64.4 60.5 1
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9.2 SECTION 9 9.1 LINEAR FREE ENERG
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9.4 SECTION 9 TABLE 9.1 Hammett and
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9.6 SECTION 9 TABLE 9.1 Hammett and
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9.8 SECTION 9 TABLE 9.3 pK a and Rh
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10.2 SECTION 10 10.4.6 Polyacrylate
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10.4 SECTION 10 10.2 ADDITIVES TO P
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10.6 SECTION 10 injection molding.
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10.8 SECTION 10 10.3 FORMULAS AND K
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10.10 SECTION 10 Key properties of
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10.12 SECTION 10 10.3.8 Fluorocarbo
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10.14 SECTION 10 10.3.11 Phenolics
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10.16 SECTION 10 The resin has the
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10.18 SECTION 10 10.3.19 Polyuretha
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10.20 SECTION 10 10.3.22 Sulfones B
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TABLE 10.2 Properties of Commercial
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10.58 SECTION 10 10.4 FORMULAS AND
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10.60 SECTION 10 10.4.8 Polychlorop
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10.62 SECTION 10 Styrene-butadiene
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10.5 CHEMICAL RESISTANCE TABLE 10.4
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10.6 GAS PERMEABILITY TABLE 10.5 Ga
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TABLE 10.5 Gas Permeability Constan
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TABLE 10.7 Constants ofFats and Oil
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TABLE 10.8 Constants ofWaxes Wax Me
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SECTION 11 PRACTICAL LABORATORY INF
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11.4 SECTION 11 TABLE 11.2 Molecula
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11.6 SECTION 11 A saturated aqueous
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11.8 SECTION 11 TABLE 11.6 Relative
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11.10 SECTION 11 11.3 BOILING POINT
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11.12 SECTION 11 TABLE 11.8 Organic
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11.14 SECTION 11 TABLE 11.9 Molecul
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11.4 SEPARATION METHODS TABLE 11.11
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11.18 SECTION 11 TABLE 11.12 Solven
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11.20 SECTION 11 TABLE 11.12 Solven
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TABLE 11.13 McReynolds’ Constants
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TABLE 11.13 McReynolds’ Constants
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11.26 SECTION 11 11.4.1 McReynolds
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11.28 SECTION 11 11.4.2.2 Partition
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11.30 SECTION 11 FIGURE 11.2 Band a
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11.32 SECTION 11 11.4.3 Ion-Exchang
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11.34 SECTION 11 TABLE 11.16 Guide
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11.36 SECTION 11 TABLE 11.16 Guide
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11.38 SECTION 11 TABLE 11.18 Relati
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11.40 SECTION 11 distribution coeff
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11.42 SECTION 11 TABLE 11.19 Gravim
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11.68 SECTION 11 TABLE 11.20 Elemen
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11.70 SECTION 11 TABLE 11.22 Common
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11.72 SECTION 11 TABLE 11.25 Tolera
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11.74 SECTION 11 TABLE 11.26 Heatin
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11.76 SECTION 11 TABLE 11.28 Titrim
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11.84 SECTION 11 appears becomes le
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11.86 SECTION 11 TABLE 11.29 Equati
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11.88 SECTION 11 TABLE 11.29 Equati
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11.90 SECTION 11 The more stable th
Page 1183 and 1184:
11.92 SECTION 11 11.6.6.2.5 Buffer
Page 1185 and 1186:
11.94 SECTION 11 TABLE 11.30 Standa
Page 1187 and 1188:
TABLE 11.32 Properties and Applicat
Page 1189 and 1190:
11.98 SECTION 11 TABLE 11.36 Maskin
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11.100 SECTION 11 TABLE 11.37 Anion
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11.102 SECTION 11 TABLE 11.39 Amino
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11.104 SECTION 11 TABLE 11.44 Facto
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11.106 SECTION 11 11.7 LABORATORY S
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11.108 SECTION 11 TABLE 11.48 Stand
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11.110 SECTION 11 Alizarin yellow G
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11.112 SECTION 11 Bromchlorophenol
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11.114 SECTION 11 p-Ethoxychrysoidi
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11.116 SECTION 11 Mercurous nitrate
Page 1209 and 1210:
11.118 SECTION 11 Potassium carbona
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11.120 SECTION 11 until the ammoniu
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11.122 SECTION 11 TABLE 11.49 TLV C
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11.130 SECTION 11 TABLE 11.50 Chemi
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Page 1229 and 1230:
11.138 SECTION 11 of water which is
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TABLE 11.55 Thermoelectric Values i
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TABLE 11.56 Type B Thermocouples: P
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TABLE 11.58 Type J Thermocouples: I
Page 1237 and 1238:
TABLE 11.60 Type N Thermocouples: N
Page 1239 and 1240:
TABLE 11.62 Type S Thermocouples: P
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11.150 SECTION 11 11.11 CORRECTION
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Index Terms Links 2 Acid-base indic
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Index Terms Links 4 Alkynes, nomenc
Page 1247 and 1248:
Index Terms Links 6 Aurintricarboxy
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Index Terms Links 8 Boron-11 chemic
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Index Terms Links 10 Cellulose acet
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Index Terms Links 12 Collective ino
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Index Terms Links 14 Degree Fahrenh
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Index Terms Links 16 Electrical res
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Index Terms Links 18 Equivalent wei
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Index Terms Links 20 Fluorocarbon p
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Index Terms Links 22 Halogenated hy
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Index Terms Links 24 Impact strengt
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Index Terms Links 26 Kα 1 lines, m
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Index Terms Links 28 Melmine phenol
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Index Terms Links 30 Neon-neon bond
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Index Terms Links 32 One-tailed tes
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Index Terms Links 34 Physical chemi
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Index Terms Links 36 Polyolefin the
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Index Terms Links 38 Pyridine: bina
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Index Terms Links 40 Rho values: fo
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Index Terms Links 42 Single-bond ra
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Index Terms Links 44 Stereoisomers
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Index Terms Links 46 Tension, aqueo
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Index Terms Links 48 Triethylenetet
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Index Terms Links 50 Water (Cont.)
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