preface to fifteenth edition

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SPECTROSCOPY 7.91 TABLE 7.41 Nuclear Properties of the Elements (Continued) Nuclide Natural abundance, % Spin I Sensitivityat constant field relative to 1 H NMR frequency for a 1-kG field, MHz Magnetic moment / N , J·T 1 Electric quadrupole moment Q, 10 28 m 2 139 La 99.9098 7 ⁄2 0.060 58 0.606 10 2.783 045 0.20 137 Ce * 3 ⁄2 0.006 41 0.462 0.91 139 Ce * 3⁄2 0.006 41 0.462 0.91 141 Ce * 7 ⁄2 0.003 64 0.237 1.09 141 Pr 100 5 ⁄2 0.334 83 1.303 55 4.275 4 0.059 143 Nd 12.18 7 ⁄2 0.003 39 0.231 9 1.065 0.63 145 Nd 8.30 7 ⁄2 0.000 79 0.142 9 0.656 0.33 143 Pm * 5⁄2 0.235 10 1.16 3.8 147 Pm * 7⁄2 0.049 40 0.57 2.6 0.70 147 Sm 15.0 7 ⁄2 0.001 52 0.177 47 0.814 9 0.26 149 Sm 13.8 7⁄2 0.000 85 0.146 31 0.671 8 0.094 151 Eu 47.8 5 ⁄2 0.179 29 1.058 54 3.471 8 0.903 153 Eu 52.2 5 ⁄2 0.015 44 0.467 44 1.533 1 2.41 155 Gd 14.80 3 ⁄2 0.000 15 0.131 7 0.259 1 1.27 157 Gd 15.65 3 ⁄2 0.000 33 0.1727 0.339 9 1.35 159 Tb 100 3 ⁄2 0.069 45 1.023 2.014 1.432 161 Dy18.9 5 ⁄2 0.000 48 1.465 3 0.480 6 2.47 163 Dy24.9 5 ⁄2 0.001 30 0.205 07 0.672 6 2.65 165 Ho 100 7 ⁄2 0.204 23 0.908 81 4.173 3.58 167 Er 22.95 7 ⁄2 0.000 507 0.122 81 0.563 9 3.57 169 Tm 100 1 ⁄2 0.000 566 3.531 0.231 6 171 Yb 14.3 1⁄2 0.005 52 0.752 59 0.493 67 173 Yb 16.12 5 ⁄2 0.001 35 0.207 301 0.679 89 2.80 175 Lu 97.41 7 ⁄2 0.031 28 0.486 24 2.232 7 3.49 176 Lu * 2.59 7 0.039 75 0.345 1 3.169 4.97 177 Hf 18.606 7 ⁄2 0.001 40 0.172 81 0.793 5 3.36 179 Hf 13.629 9⁄2 0.000 55 0.108 56 0.640 9 3.79 180 Ta 0.012 9 0.102 51 0.404 4.77 181 Ta 99.988 7⁄2 0.037 44 0.516 25 2.3705 3.17 183 W 14.3 1⁄2 0.000 08 0.179 56 0.117 785 185 Re 37.40 5 ⁄2 0.138 70 0.971 7 3.1871 2.18 187 Re * 62.60 5⁄2 0.143 00 0.981 7 3.219 7 2.07 187 Os 1.6 1 ⁄2 0.000 01 0.098 56 0.064 652 189 Os 16.1 3 ⁄2 0.002 44 0.335 35 0.659 933 0.856 191 Ir 37.3 3 ⁄2 0.000 03 0.076 6 0.150 7 0.816 193 Ir 62.7 3 ⁄2 0.000 04 0.0832 0.163 7 0.751 195 Pt 33.8 1 ⁄2 0.010 39 0.929 20 0.609 52 197 Au 100 3 ⁄2 0.000 03 0.074 06 0.145 746 0.547 199 Hg 16.87 1 ⁄2 0.005 94 0.771 21 0.505 885 201 Hg 13.18 3 ⁄2 0.001 49 0.284 68 0.560 226 0.386 203 Tl 29.524 1 ⁄2 0.195 981 2.473 10 1.622 258 205 Tl 70.476 1 ⁄2 0.201 82 2.497 42 1.638 215 207 Pb 22.1 1 ⁄2 0.009 55 0.903 38 0.592 58 209 Bi 100 9 ⁄2 0.144 33 0.696 28 4.110 6 0.50 229 Th * 5 ⁄2 0.000 42 0.140 0.46 4.30 231 Pa * 3⁄2 0.069 03 1.02 2.01 1.72 235 U * 0.7200 7 ⁄2 0.000 15 0.083 0.38 4.936 237 Np * 5 ⁄2 0.132 64 0.957 3.14 3.886 239 Pu * 1 ⁄2 0.000 38 0.309 0.203 243 Am * 5 ⁄2 0.017 88 0.491 1.61 4.21
7.92 SECTION 7 TABLE 7.42 Proton Chemical Shifts Values are given on the officially approved scale; 10.00 . Abbreviations Used in the Table R, alkyl group Ar, aryl group Substituent group Methyl protons Methylene protons Methine proton HC9C9CH 2 0.95 1.20 1.55 HC9C9NR 2 1.05 1.45 1.70 HC9C9C"C 1.00 1.35 1.70 HC9C9C"O 1.05 1.55 1.95 HC9C9NRAr 1.10 1.50 1.80 HC9C9H(C"O)R 1.10 1.50 1.90 HC9C9(C"O)NR 2 1.10 1.50 1.80 HC9C9(C"O)Ar 1.15 1.55 1.90 HC9C9(C"O)OR 1.15 1.70 1.90 HC9C9Ar 1.15 1.55 1.80 HC9C9OH 1.20 1.50 1.75 HC9C9OR 1.20 1.50 1.75 HC9C9C#CR 1.20 1.50 1.80 HC9C9C#N 1.25 1.65 2.00 HC9C9SR 1.25 1.60 1.90 HC9C9OAr 1.30 1.55 2.00 HC9C9O(C"O)R 1.30 1.60 1.80 HC9C9SH 1.30 1.60 1.65 HC9C9(S"O)R 1.35 1.70 and HC9C9SO 2 R HC9C9NR 3 1.40 1.75 2.05 HC9C9O9N"O 1.40 HC9C9O(C"O)CF 3 1.40 1.65 HC9C9CL 1.55 1.80 1.95 HC9C9F 1.55 1.85 2.15 HC9C9NO 2 1.60 2.05 2.50 HC9C9O(C"O)Ar 1.65 1.75 1.85 HC9C9I 1.75 1.80 2.10 HC9C9Br 1.80 1.85 1.90 HC9CH 2 0.90 1.30 1.50 HC9C"C 1.60 2.05 HC9C#C 1.70 2.20 2.80 HC9(C"O)OR 2.00 2.25 2.50 HC9(C"O)NR 2 2.00 2.25 2.40 HC9SR 2.05 2.55 3.00 HC9O9O 2.10 2.30 2.55 HC9(C"O)R 2.10 2.35 2.65 HC9C#N 2.15 2.45 2.90 HC9I 2.15 3.15 4.25 HC9CHO 2.20 2.40 HC9Ar 2.25 2.45 2.85 HC9NR 2 2.25 2.40 2.80 HC9SSR 2.35 2.70 HC9(C"O)Ar 2.40 2.70 3.40 HC9SAr 2.40 HC9NRAr 2.60 3.10 3.60 HC9SO 2 R and HC9(SO)R 2.60 3.05 HC9Br 2.70 3.40 4.10 HC9NR 3 2.95 3.10 3.60
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LANGE'S HANDBOOK OF CHEMISTRY John
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Grateful acknowledgment is hereby m
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PREFACE TO FIFTEENTH EDITION This n
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PREFACE TO FIFTEENTH EDITION ix inv
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xii PREFACE TO FOURTEENTH EDITION l
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PREFACE TO FIRST EDITION This book
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For the detailed contents of any se
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1.2 SECTION 1 is derived from the G
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1.4 SECTION 1 rather than methylide
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1.6 SECTION 1 Styrene Toluene Xylen
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1.8 SECTION 1 TABLE 1.2 Fused Polyc
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1.10 SECTION 1 1.1.1.6 Bridged Hydr
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1.12 SECTION 1 TABLE 1.4 Suffixes f
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1.14 SECTION 1 TABLE 1.5 Trivial Na
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1.16 SECTION 1 TABLE 1.6 Trivial Na
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1.18 SECTION 1 Selection of the pri
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1.20 SECTION 1 attached to one anot
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1.22 SECTION 1 When side chains of
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1.24 SECTION 1 heterocyclic structu
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1.26 SECTION 1 Bivalent radicals of
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1.28 SECTION 1 Complex linear polya
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1.30 SECTION 1 TABLE 1.11 Names of
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1.32 SECTION 1 hydroxyamino- to the
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1.34 SECTION 1 may be named (1) by
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1.36 SECTION 1 Examples are methyl
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1.38 SECTION 1 tuted acid, respecti
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1.40 SECTION 1 FIGURE 1.2 Newman pr
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1.42 SECTION 1 from the ring are kn
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1.44 SECTION 1 FIGURE 1.11 Two isom
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1.46 SECTION 1 Chiral Center. The c
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1.48 SECTION 1 FIGURE 1.15 Isomers
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1.50 SECTION 1 entries to bring tog
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1.52 SECTION 1 TABLE 1.13 Names and
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1.60 SECTION 1 TABLE 1.14 Empirical
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2.2 SECTION 2 2.3.6 Student’s Dis
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2.4 SECTION 2 TABLE 2.1 Fundamental
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2.6 SECTION 2 TABLE 2.1 Fundamental
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2.8 SECTION 2 TABLE 2.2 Physical an
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2.10 SECTION 2 TABLE 2.2 Physical a
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2.24 SECTION 2 TABLE 2.3 Mathematic
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2.26 SECTION 2 TABLE 2.6 Abbreviati
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2.36 SECTION 2 TABLE 2.7 Conversion
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2.54 SECTION 2 TABLE 2.8 Temperatur
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2.66 SECTION 2 2.1.1 Conversion of
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2.68 SECTION 2 Oleometer. A hydrome
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2.70 SECTION 2 Example 3. 25 1.2500
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2.72 SECTION 2 TABLE 2.9 Barometer
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2.74 SECTION 2 TABLE 2.9 Barometer
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2.76 SECTION 2 TABLE 2.10 Barometri
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2.78 SECTION 2 TABLE 2.12 Reduction
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2.80 SECTION 2 TABLE 2.12 Reduction
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2.82 SECTION 2 TABLE 2.13 Viscosity
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2.84 SECTION 2 TABLE 2.14 Conversio
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2.86 SECTION 2 TABLE 2.15 Hydromete
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2.88 SECTION 2 TABLE 2.17 Correctio
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2.90 SECTION 2 TABLE 2.18 Pressure
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2.96 SECTION 2 TABLE 2.20 Values of
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2.98 SECTION 2 TABLE 2.21 Transmitt
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2.100 SECTION 2 TABLE 2.21 Transmit
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2.102 SECTION 2 2.2 MATHEMATICAL TA
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2.104 SECTION 2 TABLE 2.23 Derivati
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2.106 SECTION 2 TABLE 2.24 Integral
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2.108 SECTION 2 TABLE 2.24 Integral
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2.110 SECTION 2 Regular Polygon of
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2.112 SECTION 2 A h[0.4(y y ) 1.
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2.114 SECTION 2 2.2.3.1 Signs of th
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2.116 SECTION 2 x2 x3 x4 x5 ln(1 x
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2.118 SECTION 2 2.3.2 Errors in Qua
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2.120 SECTION 2 The breadth or spre
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2.122 SECTION 2 TABLE 2.26b Areas U
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2.124 SECTION 2 The distribution of
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2.126 SECTION 2 Should there be mor
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2.128 SECTION 2 Example 10 Six samp
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2.130 SECTION 2 2.3.9 The F Statist
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TABLE 2.29 F Distribution (Continue
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2.134 SECTION 2 mathematical treatm
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2.136 SECTION 2 The confidence limi
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2.138 SECTION 2 situation where rel
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3.2 SECTION 3 The alphabetical orde
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3.4 SECTION 3 When it is required t
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3.6 SECTION 3 PO phosphoryl SeO sel
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3.8 SECTION 3 3.1.5 Acids 3.1.5.1 A
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3.10 SECTION 3 3.1.6.6 Multiplicati
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3.12 SECTION 3 3.2 PHYSICAL PROPERT
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TABLE 3.2 Physical Constants of Ino
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3.62 SECTION 3 TABLE 3.3 Synonyms a
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SECTION 4 PROPERTIES OF ATOMS, RADI
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4.3 Fermium Fm 100 [Rn] 5f 12 7s 2
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Silver (argentum) Ag 47 [Kr] 4d 10
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PROPERTIES OF ATOMS,RADICALS,AND BO
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PROPERTIES OF ATOMS, RADICALS, AND
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SECTION 5 PHYSICAL PROPERTIES 5.1 S
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PHYSICAL PROPERTIES 5.3 5.1 SOLUBIL
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TABLE 5.1 Solubility of Gases in Wa
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TABLE 5.1 Solubility of Gases in Wa
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TABLE 5.2 Solubilities of Inorganic
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formateBa(CHO 2 ) 2 26.2 28.0 29.9
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(III) sulfateCe 2 (SO 4 ) 3 ·9H 2
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iodidePbI 2 0.044 0.056 0.069 0.090
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Nickel sulfateNiSO 4 ·6H 2 O (pale
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Praseodymium bromatePr(BrO 3 ) 3 55
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formate NaCHO 2 43.9 62.5 81.2 102
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Uranyl nitrate UO 2 (NO 3 ) 2 98 10
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PHYSICAL PROPERTIES 5.25 TABLE 5.3
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PHYSICAL PROPERTIES 5.57 5.3 BOILIN
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TABLE 5.12 Ternary Azeotropic Mixtu
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TABLE 5.12 Ternary Azeotropic Mixtu
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PHYSICAL PROPERTIES 5.83 5.4 FREEZI
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PHYSICAL PROPERTIES 5.87 5.5 DENSIT
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PHYSICAL PROPERTIES 5.89 dt Dt P
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PHYSICAL PROPERTIES 5.135 5.6.1 Ref
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PHYSICAL PROPERTIES 5.137 where the
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PHYSICAL PROPERTIES 5.139 5.7 COMBU
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Temperature, C Substance 40 20 0 20
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PHYSICAL PROPERTIES 5.171 This equa
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SECTION 6 THERMODYNAMIC PROPERTIES
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THERMODYNAMICPROPERTIES 6.3 6.1.1.2
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THERMODYNAMICPROPERTIES 6.5 A gener
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THERMODYNAMICPROPERTIES 6.7 TABLE 6
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THERMODYNAMICPROPERTIES 6.9 TABLE 6
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THERMODYNAMICPROPERTIES 6.11 TABLE
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THERMODYNAMIC PROPERTIES 6.21 TABLE
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THERMODYNAMIC PROPERTIES 6.101 TABL
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THERMODYNAMIC PROPERTIES 6.143 The
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SECTION 7 SPECTROSCOPY 7.1 X-RAY ME
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SPECTROSCOPY 7.3 TABLE 7.1 Waveleng
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SPECTROSCOPY 7.9 TABLE 7.3 Critical
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SPECTROSCOPY 7.11 TABLE 7.4 X-Ray E
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SPECTROSCOPY 7.13 Emission line K 1
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SPECTROSCOPY 7.15 TABLE 7.7 Analyzi
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SPECTROSCOPY 7.17 TABLE 7.8 Mass Ab
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SPECTROSCOPY 7.19 TABLE 7.9 Electro
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SPECTROSCOPY 7.21 TABLE 7.11 Absorp
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SPECTROSCOPY 7.23 TABLE 7.13 Solven
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SPECTROSCOPY 7.25 7.3 FLUORESCENCE
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SPECTROSCOPY 7.27 TABLE 7.16 Fluore
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SPECTROSCOPY 7.29 TABLE 7.18 Detect
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SPECTROSCOPY 7.35 TABLE 7.19 Sensit
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SPECTROSCOPY 7.37 TABLE 7.19 Sensit
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SPECTROSCOPY 7.39 In terms of m ,
Page 744 and 745: SPECTROSCOPY 7.41 The ionization co
Page 746 and 747: SPECTROSCOPY 7.43 TABLE 7.20 Absorp
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Page 774 and 775: SPECTROSCOPY 7.71 7.6 RAMAN SPECTRO
Page 776 and 777: SPECTROSCOPY 7.73 TABLE 7.30 Raman
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Page 796 and 797: SPECTROSCOPY 7.93 TABLE 7.42 Proton
Page 798 and 799: SPECTROSCOPY 7.95 TABLE 7.44 Estima
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ELECTROLYTES, EMF, AND CHEMICAL EQU
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TABLE 8.7 Proton Transfer Reactions
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TABLE 8.7 Proton Transfer Reactions
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TABLE 8.9 Selected Equilibrium Cons
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8.75 3-tert-Butylbenzoic acid (0) 4
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4-Hydroxyproline (1) 1.900 1C 1.850
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N-Propionylglycine (1) 3.728 3.723
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TABLE 8.14 National Bureau of Stand
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1 part 0.1% neutral red in alc. * V
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3,3-Dimethoxybenzidine dihydrochlor
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TABLE 8.35 Equivalent Conductivitie
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KCl 127.3 124.4 122.4 115.8 112.0 1
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NaIO 3 75.2 72.6 70.9 64.4 60.5 1
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Page 1012 and 1013:
9.2 SECTION 9 9.1 LINEAR FREE ENERG
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9.4 SECTION 9 TABLE 9.1 Hammett and
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9.6 SECTION 9 TABLE 9.1 Hammett and
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9.8 SECTION 9 TABLE 9.3 pK a and Rh
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10.2 SECTION 10 10.4.6 Polyacrylate
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10.4 SECTION 10 10.2 ADDITIVES TO P
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10.6 SECTION 10 injection molding.
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10.8 SECTION 10 10.3 FORMULAS AND K
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10.10 SECTION 10 Key properties of
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10.12 SECTION 10 10.3.8 Fluorocarbo
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10.14 SECTION 10 10.3.11 Phenolics
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10.16 SECTION 10 The resin has the
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10.18 SECTION 10 10.3.19 Polyuretha
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10.20 SECTION 10 10.3.22 Sulfones B
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TABLE 10.2 Properties of Commercial
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10.58 SECTION 10 10.4 FORMULAS AND
Page 1078 and 1079:
10.60 SECTION 10 10.4.8 Polychlorop
Page 1080 and 1081:
10.62 SECTION 10 Styrene-butadiene
Page 1082 and 1083:
10.5 CHEMICAL RESISTANCE TABLE 10.4
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10.6 GAS PERMEABILITY TABLE 10.5 Ga
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TABLE 10.5 Gas Permeability Constan
Page 1088 and 1089:
TABLE 10.7 Constants ofFats and Oil
Page 1090 and 1091:
TABLE 10.8 Constants ofWaxes Wax Me
Page 1092:
SECTION 11 PRACTICAL LABORATORY INF
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11.4 SECTION 11 TABLE 11.2 Molecula
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11.6 SECTION 11 A saturated aqueous
Page 1099 and 1100:
11.8 SECTION 11 TABLE 11.6 Relative
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11.10 SECTION 11 11.3 BOILING POINT
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11.12 SECTION 11 TABLE 11.8 Organic
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11.14 SECTION 11 TABLE 11.9 Molecul
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11.4 SEPARATION METHODS TABLE 11.11
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11.18 SECTION 11 TABLE 11.12 Solven
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11.20 SECTION 11 TABLE 11.12 Solven
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TABLE 11.13 McReynolds’ Constants
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TABLE 11.13 McReynolds’ Constants
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11.26 SECTION 11 11.4.1 McReynolds
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11.28 SECTION 11 11.4.2.2 Partition
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11.30 SECTION 11 FIGURE 11.2 Band a
Page 1123 and 1124:
11.32 SECTION 11 11.4.3 Ion-Exchang
Page 1125 and 1126:
11.34 SECTION 11 TABLE 11.16 Guide
Page 1127 and 1128:
11.36 SECTION 11 TABLE 11.16 Guide
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11.38 SECTION 11 TABLE 11.18 Relati
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11.40 SECTION 11 distribution coeff
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11.42 SECTION 11 TABLE 11.19 Gravim
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11.68 SECTION 11 TABLE 11.20 Elemen
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11.70 SECTION 11 TABLE 11.22 Common
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11.72 SECTION 11 TABLE 11.25 Tolera
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11.74 SECTION 11 TABLE 11.26 Heatin
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11.76 SECTION 11 TABLE 11.28 Titrim
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11.84 SECTION 11 appears becomes le
Page 1177 and 1178:
11.86 SECTION 11 TABLE 11.29 Equati
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11.88 SECTION 11 TABLE 11.29 Equati
Page 1181 and 1182:
11.90 SECTION 11 The more stable th
Page 1183 and 1184:
11.92 SECTION 11 11.6.6.2.5 Buffer
Page 1185 and 1186:
11.94 SECTION 11 TABLE 11.30 Standa
Page 1187 and 1188:
TABLE 11.32 Properties and Applicat
Page 1189 and 1190:
11.98 SECTION 11 TABLE 11.36 Maskin
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11.100 SECTION 11 TABLE 11.37 Anion
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11.102 SECTION 11 TABLE 11.39 Amino
Page 1195 and 1196:
11.104 SECTION 11 TABLE 11.44 Facto
Page 1197 and 1198:
11.106 SECTION 11 11.7 LABORATORY S
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11.108 SECTION 11 TABLE 11.48 Stand
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11.110 SECTION 11 Alizarin yellow G
Page 1203 and 1204:
11.112 SECTION 11 Bromchlorophenol
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11.114 SECTION 11 p-Ethoxychrysoidi
Page 1207 and 1208:
11.116 SECTION 11 Mercurous nitrate
Page 1209 and 1210:
11.118 SECTION 11 Potassium carbona
Page 1211 and 1212:
11.120 SECTION 11 until the ammoniu
Page 1213 and 1214:
11.122 SECTION 11 TABLE 11.49 TLV C
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Page 1221 and 1222:
11.130 SECTION 11 TABLE 11.50 Chemi
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Page 1227 and 1228:
Page 1229 and 1230:
11.138 SECTION 11 of water which is
Page 1231 and 1232:
TABLE 11.55 Thermoelectric Values i
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TABLE 11.56 Type B Thermocouples: P
Page 1235 and 1236:
TABLE 11.58 Type J Thermocouples: I
Page 1237 and 1238:
TABLE 11.60 Type N Thermocouples: N
Page 1239 and 1240:
TABLE 11.62 Type S Thermocouples: P
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11.150 SECTION 11 11.11 CORRECTION
Page 1243 and 1244:
Index Terms Links 2 Acid-base indic
Page 1245 and 1246:
Index Terms Links 4 Alkynes, nomenc
Page 1247 and 1248:
Index Terms Links 6 Aurintricarboxy
Page 1249 and 1250:
Index Terms Links 8 Boron-11 chemic
Page 1251 and 1252:
Index Terms Links 10 Cellulose acet
Page 1253 and 1254:
Index Terms Links 12 Collective ino
Page 1255 and 1256:
Index Terms Links 14 Degree Fahrenh
Page 1257 and 1258:
Index Terms Links 16 Electrical res
Page 1259 and 1260:
Index Terms Links 18 Equivalent wei
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Index Terms Links 20 Fluorocarbon p
Page 1263 and 1264:
Index Terms Links 22 Halogenated hy
Page 1265 and 1266:
Index Terms Links 24 Impact strengt
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Index Terms Links 26 Kα 1 lines, m
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Index Terms Links 28 Melmine phenol
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Index Terms Links 30 Neon-neon bond
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Index Terms Links 32 One-tailed tes
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Index Terms Links 34 Physical chemi
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Index Terms Links 36 Polyolefin the
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Index Terms Links 38 Pyridine: bina
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Index Terms Links 40 Rho values: fo
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Index Terms Links 42 Single-bond ra
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Index Terms Links 44 Stereoisomers
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Index Terms Links 46 Tension, aqueo
Page 1289 and 1290:
Index Terms Links 48 Triethylenetet
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Index Terms Links 50 Water (Cont.)
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