preface to fifteenth edition

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THERMODYNAMIC PROPERTIES 6.149 TABLE 6.5 Critical Properties (Continued) Substance T c , C P c , atm P c ,MPa V c ,cm 3 ·mol 1 c ,g·cm 3 Ethyl benzoate 424 32 3.24 451 0.111 Ethylbutanoate 293 30.2 3.06 421 0.28 2-Ethyl-1-butanol 145.7 Ethyl crotonate 326 Ethylcyclohexane 336 29.9 3.03 450 0.249 Ethylcyclopentane 296.4 33.5 3.39 375 0.262 3-Ethyl-2,2-dimethylhexane 338.6 22.8 2.31 526 0.271 4-Ethyl-2,2-dimethylhexane 321.5 21.9 2.22 539 0.264 3-Ethyl-2,3-dimethylhexane 353.7 23.9 2.42 516 0.276 4-Ethyl-2,3-dimethylhexane 344.2 23.1 2.34 524 0.271 3-Ethyl-2,4-dimethylhexane 343.0 23.1 2.34 522 0.273 4-Ethyl-2,4-dimethylhexane 347.8 24.4 2.47 524 0.271 3-Ethyl-2,5-dimethylhexane 330.4 22.1 2.24 537 0.265 3-Ethyl-3,4-dimethylhexane 351.4 23.9 2.42 511 0.278 Ethylene 9.3 49.7 5.036 129 0.218 Ethylene glycol dimethyl ether 263 38.2 3.87 271 0.333 Ethylene glycol ethyl ether 334.2 31.25 3.166 443 0.298 acetate Ethylene glycol monobutyl 360.8 424 0.279 ether Ethylene oxide 196 71.0 7.275 140 0.314 Ethyl formate 235.4 46.8 4.74 229 0.323 3-Ethylhexane 292.4 25.74 2.608 455 0.251 2-Ethyl-1-hexanol 367.5 27.2 2.76 494 0.264 Ethyl isopentanoate 315 Ethyl isopropyl ether 217.2 2-Ethyl-1-methylbenzene 378 30.0 3.04 460 0.26 3-Ethyl-1-methylbenzene 364 28.0 2.84 490 0.24 4-Ethyl-1-methylbenzene 367 29.0 2.94 470 0.26 Ethyl 3-methylbutanoate 314.9 1-Ethyl-1-methylcyclopentane 319 29.5 2.99 Ethyl methyl ether 164.8 43.4 4.40 221 0.272 3-Ethyl-2-methylheptane 337.8 22.0 2.23 544 0.262 4-Ethyl-2-methylheptane 328.7 21.6 2.19 545 0.261 5-Ethyl-2-methylheptane 333.6 21.6 2.19 555 0.256 3-Ethyl-3-methylheptane 347.0 22.8 2.31 532 0.267 4-Ethyl-3-methylheptane 341.2 22.5 2.28 530 0.269 5-Ethyl-3-methylheptane 333.5 22.0 2.23 541 0.263 3-Ethyl-4-methylheptane 342.4 22.5 2.28 533 0.267 4-Ethyl-4-methylheptane 342.4 22.8 2.31 525 0.271 Ethyl methyl ketone 262.4 41.0 4.154 267 0.270 3-Ethyl-2-methylpentane 294.0 26.65 2.700 443 0.258 3-Ethyl-3-methylpentane 303.5 27.71 2.808 455 0.351 Ethyl 2-methylpropanoate 280 30 3.04 410 0.28 Ethyl methyl sulfide 260 42 4.26 2-Ethylnaphthalene 502 31.0 3.14 521 0.300 Ethyl nonanoate 401 3-Ethyloctane 340 21.6 2.19 561 0.241 4-Ethyloctane 337 21.5 2.18 552 0.258 Ethyl octanoate 386 3-Ethylpentane 267.6 28.53 2.891 416 0.241 1,2-Ethylphenol 429.9 1,3-Ethylphenol 443.3
6.150 SECTION 6 TABLE 6.5 Critical Properties (Continued) Substance T c , C P c , atm P c ,MPa V c ,cm 3 ·mol 1 c ,g·cm 3 1,4-Ethylphenol 443.3 Ethyl propanoate 272.9 33.18 3.362 345 0.296 Ethyl propyl ether 227.1 32.1 3.25 244 0.361 m-Ethyltoluene 364.0 28.1 2.837 490 0.245 o-Ethyltoluene 378.0 30.1 3.04 460 0.261 p-Ethyltoluene 367 29.0 2.94 479 0.256 3-Ethyl-2,2,3-trimethylpentane 372.9 25.4 2.57 503 0.283 3-Ethyl-2,2,4-trimethylpentane 342.2 23.4 2.37 518 0.275 3-Ethyl-2,3,4-trimethylpentane 369.2 25.1 2.54 506 0.281 Ethyl vinyl ether 202 40.17 4.07 260 0.277 Fluorine 129.0 51.47 5.215 66.2 0.574 Fluorobenzene 286.94 44.91 4.551 357 0.269 Fluoroethane 102.2 49.6 5.03 169 0.284 Fluoromethane 44.7 58.0 5.88 124 0.274 4-Fluorotoluene 316.4 Formaldehyde 135 65 6.6 105 0.286 Formicacid 315 2-Furaldehyde 397 58.1 5.89 Furan 217.1 54.3 5.50 218 0.312 Germanium tetrachloride 276.9 38 3.85 330 0.650 Glycerol 453 66 6.69 255 0.361 Hafnium tetrabromide 473 415 1.20 Hafnium tetrachloride 450 57.0 5.86 304 1.05 Hafnium tetraiodide 643 528 1.30 Helium (equilibrium) 267.96 2.261 0.2289 0.06930 Helium-3 269.85 1.13 0.1182 72.5 0.0414 Helium-4 267.96 2.24 0.227 57.3 0.0698 Heptadecane 460 13.0 1.32 1006 0.140 1-Heptadecanol 736 14.0 1.42 960 0.267 Heptane 267.1 27.0 2.74 428 0.232 1-Heptanol 359.5 30.18 3.058 435 0.267 2-Heptanol 335.2 29.81 3.021 432 0.269 3-Heptanol 332.3 2-Heptanone 338.4 33.91 3.436 421 0.271 1-Heptene 264.2 28.83 2.921 402 0.246 Heptylcyclopentane 406 19.2 1.945 Hexadecafluoroheptane 201.7 16.0 1.62 664 0.584 Hexadecane 444 14 1.42 930 0.243 1-Hexadecene 444 13.2 1.34 933 0.241 Hexadecylcyclopentane 518 9.6 0.97 1,5-Hexadiene 234 34 3.44 328 0.250 Hexafluoroacetone 84.1 29.0 2.94 329 0.505 Hexafluorobenzene 243.6 32.30 3.273 335 0.505 Hexafluoroethane 19.7 224 0.617 Hexamethylbenzene 494 600 0.271 Hexane 234.5 29.85 3.025 368 0.233 Hexanenitrile 360.7 32.57 3.30 Hexanoicacid 389 31.6 3.20 1-Hexanol 337.2 33.72 3.417 381 0.268 2-Hexanol 312.8 32.67 3.310
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LANGE'S HANDBOOK OF CHEMISTRY John
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Grateful acknowledgment is hereby m
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PREFACE TO FIFTEENTH EDITION This n
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PREFACE TO FIFTEENTH EDITION ix inv
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xii PREFACE TO FOURTEENTH EDITION l
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PREFACE TO FIRST EDITION This book
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For the detailed contents of any se
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1.2 SECTION 1 is derived from the G
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1.4 SECTION 1 rather than methylide
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1.6 SECTION 1 Styrene Toluene Xylen
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1.8 SECTION 1 TABLE 1.2 Fused Polyc
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1.10 SECTION 1 1.1.1.6 Bridged Hydr
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1.12 SECTION 1 TABLE 1.4 Suffixes f
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1.14 SECTION 1 TABLE 1.5 Trivial Na
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1.16 SECTION 1 TABLE 1.6 Trivial Na
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1.18 SECTION 1 Selection of the pri
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1.20 SECTION 1 attached to one anot
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1.22 SECTION 1 When side chains of
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1.24 SECTION 1 heterocyclic structu
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1.26 SECTION 1 Bivalent radicals of
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1.28 SECTION 1 Complex linear polya
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1.30 SECTION 1 TABLE 1.11 Names of
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1.32 SECTION 1 hydroxyamino- to the
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1.34 SECTION 1 may be named (1) by
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1.36 SECTION 1 Examples are methyl
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1.38 SECTION 1 tuted acid, respecti
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1.40 SECTION 1 FIGURE 1.2 Newman pr
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1.42 SECTION 1 from the ring are kn
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1.44 SECTION 1 FIGURE 1.11 Two isom
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1.46 SECTION 1 Chiral Center. The c
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1.48 SECTION 1 FIGURE 1.15 Isomers
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1.50 SECTION 1 entries to bring tog
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1.52 SECTION 1 TABLE 1.13 Names and
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1.60 SECTION 1 TABLE 1.14 Empirical
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2.2 SECTION 2 2.3.6 Student’s Dis
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2.4 SECTION 2 TABLE 2.1 Fundamental
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2.6 SECTION 2 TABLE 2.1 Fundamental
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2.8 SECTION 2 TABLE 2.2 Physical an
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2.10 SECTION 2 TABLE 2.2 Physical a
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2.24 SECTION 2 TABLE 2.3 Mathematic
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2.26 SECTION 2 TABLE 2.6 Abbreviati
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2.36 SECTION 2 TABLE 2.7 Conversion
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2.54 SECTION 2 TABLE 2.8 Temperatur
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2.66 SECTION 2 2.1.1 Conversion of
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2.68 SECTION 2 Oleometer. A hydrome
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2.70 SECTION 2 Example 3. 25 1.2500
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2.72 SECTION 2 TABLE 2.9 Barometer
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2.74 SECTION 2 TABLE 2.9 Barometer
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2.76 SECTION 2 TABLE 2.10 Barometri
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2.78 SECTION 2 TABLE 2.12 Reduction
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2.80 SECTION 2 TABLE 2.12 Reduction
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2.82 SECTION 2 TABLE 2.13 Viscosity
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2.84 SECTION 2 TABLE 2.14 Conversio
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2.86 SECTION 2 TABLE 2.15 Hydromete
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2.88 SECTION 2 TABLE 2.17 Correctio
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2.90 SECTION 2 TABLE 2.18 Pressure
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2.96 SECTION 2 TABLE 2.20 Values of
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2.98 SECTION 2 TABLE 2.21 Transmitt
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2.100 SECTION 2 TABLE 2.21 Transmit
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2.102 SECTION 2 2.2 MATHEMATICAL TA
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2.104 SECTION 2 TABLE 2.23 Derivati
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2.106 SECTION 2 TABLE 2.24 Integral
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2.108 SECTION 2 TABLE 2.24 Integral
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2.110 SECTION 2 Regular Polygon of
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2.112 SECTION 2 A h[0.4(y y ) 1.
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2.114 SECTION 2 2.2.3.1 Signs of th
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2.116 SECTION 2 x2 x3 x4 x5 ln(1 x
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2.118 SECTION 2 2.3.2 Errors in Qua
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2.120 SECTION 2 The breadth or spre
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2.122 SECTION 2 TABLE 2.26b Areas U
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2.124 SECTION 2 The distribution of
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2.126 SECTION 2 Should there be mor
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2.128 SECTION 2 Example 10 Six samp
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2.130 SECTION 2 2.3.9 The F Statist
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TABLE 2.29 F Distribution (Continue
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2.134 SECTION 2 mathematical treatm
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2.136 SECTION 2 The confidence limi
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2.138 SECTION 2 situation where rel
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3.2 SECTION 3 The alphabetical orde
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3.4 SECTION 3 When it is required t
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3.6 SECTION 3 PO phosphoryl SeO sel
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3.8 SECTION 3 3.1.5 Acids 3.1.5.1 A
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3.10 SECTION 3 3.1.6.6 Multiplicati
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3.12 SECTION 3 3.2 PHYSICAL PROPERT
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TABLE 3.2 Physical Constants of Ino
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3.62 SECTION 3 TABLE 3.3 Synonyms a
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SECTION 4 PROPERTIES OF ATOMS, RADI
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4.3 Fermium Fm 100 [Rn] 5f 12 7s 2
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Silver (argentum) Ag 47 [Kr] 4d 10
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PROPERTIES OF ATOMS,RADICALS,AND BO
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PROPERTIES OF ATOMS, RADICALS, AND
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SECTION 5 PHYSICAL PROPERTIES 5.1 S
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PHYSICAL PROPERTIES 5.3 5.1 SOLUBIL
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TABLE 5.1 Solubility of Gases in Wa
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TABLE 5.1 Solubility of Gases in Wa
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TABLE 5.2 Solubilities of Inorganic
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formateBa(CHO 2 ) 2 26.2 28.0 29.9
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(III) sulfateCe 2 (SO 4 ) 3 ·9H 2
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iodidePbI 2 0.044 0.056 0.069 0.090
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Nickel sulfateNiSO 4 ·6H 2 O (pale
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Praseodymium bromatePr(BrO 3 ) 3 55
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formate NaCHO 2 43.9 62.5 81.2 102
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Uranyl nitrate UO 2 (NO 3 ) 2 98 10
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PHYSICAL PROPERTIES 5.25 TABLE 5.3
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PHYSICAL PROPERTIES 5.57 5.3 BOILIN
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TABLE 5.12 Ternary Azeotropic Mixtu
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TABLE 5.12 Ternary Azeotropic Mixtu
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PHYSICAL PROPERTIES 5.83 5.4 FREEZI
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PHYSICAL PROPERTIES 5.87 5.5 DENSIT
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PHYSICAL PROPERTIES 5.89 dt Dt P
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PHYSICAL PROPERTIES 5.135 5.6.1 Ref
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PHYSICAL PROPERTIES 5.137 where the
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PHYSICAL PROPERTIES 5.139 5.7 COMBU
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Temperature, C Substance 40 20 0 20
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PHYSICAL PROPERTIES 5.171 This equa
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SECTION 6 THERMODYNAMIC PROPERTIES
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THERMODYNAMICPROPERTIES 6.3 6.1.1.2
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THERMODYNAMICPROPERTIES 6.5 A gener
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THERMODYNAMICPROPERTIES 6.7 TABLE 6
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THERMODYNAMICPROPERTIES 6.9 TABLE 6
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THERMODYNAMICPROPERTIES 6.11 TABLE
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THERMODYNAMIC PROPERTIES 6.21 TABLE
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Page 644 and 645: THERMODYNAMIC PROPERTIES 6.99 TABLE
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Page 706 and 707: SPECTROSCOPY 7.3 TABLE 7.1 Waveleng
Page 712 and 713: SPECTROSCOPY 7.9 TABLE 7.3 Critical
Page 714 and 715: SPECTROSCOPY 7.11 TABLE 7.4 X-Ray E
Page 716 and 717: SPECTROSCOPY 7.13 Emission line K 1
Page 718 and 719: SPECTROSCOPY 7.15 TABLE 7.7 Analyzi
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Page 722 and 723: SPECTROSCOPY 7.19 TABLE 7.9 Electro
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Page 728 and 729: SPECTROSCOPY 7.25 7.3 FLUORESCENCE
Page 730 and 731: SPECTROSCOPY 7.27 TABLE 7.16 Fluore
Page 732 and 733: SPECTROSCOPY 7.29 TABLE 7.18 Detect
Page 738 and 739: SPECTROSCOPY 7.35 TABLE 7.19 Sensit
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Page 742 and 743: SPECTROSCOPY 7.39 In terms of m ,
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SPECTROSCOPY 7.41 The ionization co
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SPECTROSCOPY 7.43 TABLE 7.20 Absorp
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SPECTROSCOPY 7.67 TABLE 7.28 Infrar
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7.69
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SPECTROSCOPY 7.71 7.6 RAMAN SPECTRO
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SPECTROSCOPY 7.73 TABLE 7.30 Raman
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SPECTROSCOPY 7.89 7.7 NUCLEAR MAGNE
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SPECTROSCOPY 7.91 TABLE 7.41 Nuclea
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SPECTROSCOPY 7.93 TABLE 7.42 Proton
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SPECTROSCOPY 7.95 TABLE 7.44 Estima
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SPECTROSCOPY 7.97 TABLE 7.46 Proton
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SPECTROSCOPY 7.99 TABLE 7.48 Solven
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SPECTROSCOPY 7.101 TABLE 7.49 Carbo
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SPECTROSCOPY 7.103 TABLE 7.51 Effec
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SPECTROSCOPY 7.107 TABLE 7.56 One-B
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SPECTROSCOPY 7.113 TABLE 7.63 Nitro
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SPECTROSCOPY 7.115 TABLE 7.64 Nitro
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SPECTROSCOPY 7.117 TABLE 7.69 Fluor
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SPECTROSCOPY 7.119 TABLE 7.72 Silic
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SPECTROSCOPY 7.121 TABLE 7.73 Phosp
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SPECTROSCOPY 7.123 TABLE 7.74 Phosp
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SPECTROSCOPY 7.125 when z 3 and y
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SPECTROSCOPY 7.127 Masses 19 and 31
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SPECTROSCOPY 7.129 TABLE 7.76 Conde
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SECTION 8 ELECTROLYTES, ELECTROMOTI
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ELECTROLYTES, EMF, AND CHEMICAL EQU
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TABLE 8.7 Proton Transfer Reactions
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TABLE 8.7 Proton Transfer Reactions
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TABLE 8.9 Selected Equilibrium Cons
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8.75 3-tert-Butylbenzoic acid (0) 4
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4-Hydroxyproline (1) 1.900 1C 1.850
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N-Propionylglycine (1) 3.728 3.723
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TABLE 8.14 National Bureau of Stand
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1 part 0.1% neutral red in alc. * V
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3,3-Dimethoxybenzidine dihydrochlor
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TABLE 8.35 Equivalent Conductivitie
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KCl 127.3 124.4 122.4 115.8 112.0 1
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NaIO 3 75.2 72.6 70.9 64.4 60.5 1
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9.2 SECTION 9 9.1 LINEAR FREE ENERG
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9.4 SECTION 9 TABLE 9.1 Hammett and
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9.6 SECTION 9 TABLE 9.1 Hammett and
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9.8 SECTION 9 TABLE 9.3 pK a and Rh
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10.2 SECTION 10 10.4.6 Polyacrylate
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10.4 SECTION 10 10.2 ADDITIVES TO P
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10.6 SECTION 10 injection molding.
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10.8 SECTION 10 10.3 FORMULAS AND K
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10.10 SECTION 10 Key properties of
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10.12 SECTION 10 10.3.8 Fluorocarbo
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10.14 SECTION 10 10.3.11 Phenolics
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10.16 SECTION 10 The resin has the
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10.18 SECTION 10 10.3.19 Polyuretha
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10.20 SECTION 10 10.3.22 Sulfones B
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TABLE 10.2 Properties of Commercial
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10.58 SECTION 10 10.4 FORMULAS AND
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10.60 SECTION 10 10.4.8 Polychlorop
Page 1080 and 1081:
10.62 SECTION 10 Styrene-butadiene
Page 1082 and 1083:
10.5 CHEMICAL RESISTANCE TABLE 10.4
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10.6 GAS PERMEABILITY TABLE 10.5 Ga
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TABLE 10.5 Gas Permeability Constan
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TABLE 10.7 Constants ofFats and Oil
Page 1090 and 1091:
TABLE 10.8 Constants ofWaxes Wax Me
Page 1092:
SECTION 11 PRACTICAL LABORATORY INF
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11.4 SECTION 11 TABLE 11.2 Molecula
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11.6 SECTION 11 A saturated aqueous
Page 1099 and 1100:
11.8 SECTION 11 TABLE 11.6 Relative
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11.10 SECTION 11 11.3 BOILING POINT
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11.12 SECTION 11 TABLE 11.8 Organic
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11.14 SECTION 11 TABLE 11.9 Molecul
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11.4 SEPARATION METHODS TABLE 11.11
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11.18 SECTION 11 TABLE 11.12 Solven
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11.20 SECTION 11 TABLE 11.12 Solven
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TABLE 11.13 McReynolds’ Constants
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TABLE 11.13 McReynolds’ Constants
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11.26 SECTION 11 11.4.1 McReynolds
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11.28 SECTION 11 11.4.2.2 Partition
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11.30 SECTION 11 FIGURE 11.2 Band a
Page 1123 and 1124:
11.32 SECTION 11 11.4.3 Ion-Exchang
Page 1125 and 1126:
11.34 SECTION 11 TABLE 11.16 Guide
Page 1127 and 1128:
11.36 SECTION 11 TABLE 11.16 Guide
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11.38 SECTION 11 TABLE 11.18 Relati
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11.40 SECTION 11 distribution coeff
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11.42 SECTION 11 TABLE 11.19 Gravim
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11.68 SECTION 11 TABLE 11.20 Elemen
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11.70 SECTION 11 TABLE 11.22 Common
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11.72 SECTION 11 TABLE 11.25 Tolera
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11.74 SECTION 11 TABLE 11.26 Heatin
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11.76 SECTION 11 TABLE 11.28 Titrim
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11.84 SECTION 11 appears becomes le
Page 1177 and 1178:
11.86 SECTION 11 TABLE 11.29 Equati
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11.88 SECTION 11 TABLE 11.29 Equati
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11.90 SECTION 11 The more stable th
Page 1183 and 1184:
11.92 SECTION 11 11.6.6.2.5 Buffer
Page 1185 and 1186:
11.94 SECTION 11 TABLE 11.30 Standa
Page 1187 and 1188:
TABLE 11.32 Properties and Applicat
Page 1189 and 1190:
11.98 SECTION 11 TABLE 11.36 Maskin
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11.100 SECTION 11 TABLE 11.37 Anion
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11.102 SECTION 11 TABLE 11.39 Amino
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11.104 SECTION 11 TABLE 11.44 Facto
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11.106 SECTION 11 11.7 LABORATORY S
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11.108 SECTION 11 TABLE 11.48 Stand
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11.110 SECTION 11 Alizarin yellow G
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11.112 SECTION 11 Bromchlorophenol
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11.114 SECTION 11 p-Ethoxychrysoidi
Page 1207 and 1208:
11.116 SECTION 11 Mercurous nitrate
Page 1209 and 1210:
11.118 SECTION 11 Potassium carbona
Page 1211 and 1212:
11.120 SECTION 11 until the ammoniu
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11.122 SECTION 11 TABLE 11.49 TLV C
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Page 1221 and 1222:
11.130 SECTION 11 TABLE 11.50 Chemi
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Page 1227 and 1228:
Page 1229 and 1230:
11.138 SECTION 11 of water which is
Page 1231 and 1232:
TABLE 11.55 Thermoelectric Values i
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TABLE 11.56 Type B Thermocouples: P
Page 1235 and 1236:
TABLE 11.58 Type J Thermocouples: I
Page 1237 and 1238:
TABLE 11.60 Type N Thermocouples: N
Page 1239 and 1240:
TABLE 11.62 Type S Thermocouples: P
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11.150 SECTION 11 11.11 CORRECTION
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Index Terms Links 2 Acid-base indic
Page 1245 and 1246:
Index Terms Links 4 Alkynes, nomenc
Page 1247 and 1248:
Index Terms Links 6 Aurintricarboxy
Page 1249 and 1250:
Index Terms Links 8 Boron-11 chemic
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Index Terms Links 10 Cellulose acet
Page 1253 and 1254:
Index Terms Links 12 Collective ino
Page 1255 and 1256:
Index Terms Links 14 Degree Fahrenh
Page 1257 and 1258:
Index Terms Links 16 Electrical res
Page 1259 and 1260:
Index Terms Links 18 Equivalent wei
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Index Terms Links 20 Fluorocarbon p
Page 1263 and 1264:
Index Terms Links 22 Halogenated hy
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Index Terms Links 24 Impact strengt
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Index Terms Links 26 Kα 1 lines, m
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Index Terms Links 28 Melmine phenol
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Index Terms Links 30 Neon-neon bond
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Index Terms Links 32 One-tailed tes
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Index Terms Links 34 Physical chemi
Page 1277 and 1278:
Index Terms Links 36 Polyolefin the
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Index Terms Links 38 Pyridine: bina
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Index Terms Links 40 Rho values: fo
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Index Terms Links 42 Single-bond ra
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Index Terms Links 44 Stereoisomers
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Index Terms Links 46 Tension, aqueo
Page 1289 and 1290:
Index Terms Links 48 Triethylenetet
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Index Terms Links 50 Water (Cont.)
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