preface to fifteenth edition

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THERMODYNAMIC PROPERTIES 6.153 TABLE 6.5 Critical Properties (Continued) Substance T c , C P c , atm P c ,MPa V c ,cm 3 ·mol 1 c ,g·cm 3 2-Methylpentane 224.6 29.91 3.031 367 0.235 3-Methylpentane 231.4 30.85 3.126 367 0.235 2-Methyl-2,4-pentanediol 405 33.9 3.43 Methyl pentanoate 294 2-Methyl-2-pentanol 286.4 2-Methyl-3-pentanol 302.9 34.1 3.46 3-Methyl-3-pentanol 302.5 34.7 3.52 4-Methyl-1-pentanol 330.4 4-Methyl-2-pentanol 301.3 42.4 4.30 380 0.269 3-Methyl-2-pentanone 298.8 4-Methyl-2-pentanone 298 32.3 3.27 371 0.270 2-Methyl-2-pentene 245 32.4 3.28 351 0.240 cis-3-Methyl-2-pentene 245 32.4 3.28 351 0.240 trans-3-Methyl-2-pentene 248 32.3 3.27 350 0.240 cis-4-Methyl-2-pentene 217 30 3.04 360 0.234 trans-4-Methyl-2-pentene 220 30 3.04 360 0.234 2-Methylpropanal 240 41 4.15 274 0.263 2-Methyl-1-propanamine 246 40.2 4.07 278 0.263 N-Methylpropanamide 412 2-Methylpropane 134.70 35.83 3.630 263 0.221 2-Methyl-1-propanethiol 286.4 2-Methyl-2-propanethiol 257.0 Methyl propanoate 257.5 39.5 4.00 282 0.312 2-Methylpropanoicacid 332 36.5 3.7 292 0.302 2-Methyl-1-propanol 274.6 42.39 4.295 273 0.272 2-Methyl-2-propanol 233.1 39.20 3.972 275 0.270 2-Methylpropene 144.73 39.48 4.000 239 0.235 2-Methylpropyl acetate 288 31.2 3.16 414 0.281 Methyl propyl ether 203.2 Methyl propyl sulfide 301.0 2-Methylpyridine 347.9 45.4 4.60 292 0.319 3-Methylpyridine 371.9 44.2 4.48 288 0.323 4-Methylpyridine 373 46.4 4.70 292 0.319 1-Methyl-2-pyrrolidinone 448.7 311 0.319 1-Methylstyrene 381 33.6 3.40 397 0.298 2-Methyltetrahydrofuran 264 37.1 3.76 267 0.322 2-Methylthiophene 333.1 47.9 4.85 275 0.356 3-Methylthiophene 337.7 48.9 4.95 275 0.356 Methyl vinyl ether 163 47 4.76 205 0.283 Morpholine 345 54 54.7 253 0.344 Naphthalene 475.3 39.98 4.051 407 0.31 Neon 228.71 27.2 2.77 41.7 0.4835 Niobium pentabromide 737 469 1.05 Niobium pentachloride 534 400 0.68 Niobium pentafluoride 464 62 6.28 155 1.21 Nitricoxide 92.9 64.6 6.55 58 0.52 Nitrobenzene 459 Nitroethane 284 37 3.75 Nitrogen-14 146.94 33.5 3.39 89.5 0.313 Nitrogen-15 146.8 33.5 3.39 90.4 0.332 Nitrogen chloride difluoride 64.3 50.8 5.15 Nitrogen dioxide (equilibrium) 158.2 100 10.1 170 0.557 Nitrogen trideuteride (ND 3 ) 132.4
6.154 SECTION 6 TABLE 6.5 Critical Properties (Continued) Substance T c , C P c , atm P c ,MPa V c ,cm 3 ·mol 1 c ,g·cm 3 Nitrogen trifluoride 39.3 44.7 4.53 Nitromethane 315 57.9 5.87 173 0.352 1-Nitropropane 402.0 2-Nitropropane 344.8 Nitrous oxide 36.434 71.596 7.2545 97.4 0.4525 Nitrosyl chloride 167 90 9.12 139 0.471 Nitryl fluoride 76.3 Nonadecane 483 11.0 1.12 1130 0.238 Nonane 321.5 22.6 2.29 555 0.231 Nonanoicacid 438 23.7 2.40 1-Nonanol 404 546 0.264 1-Nonene 319 23.1 2.34 580 0.218 Nonylbenzene 468 18.7 1.89 790 0.259 Nonylcyclopentane 437.4 16.3 1.65 Octadecafluorooctane 229 16.4 1.66 Octadecane 472.3 12.73 1.29 1070 0.238 1-Octadecanol 474 14 1.42 1-Octadecene 466 11.2 1.13 Octafluorocyclobutane 115.31 27.48 2.784 325 0.616 Octafluoronaphthalene 399.9 Octafluoropropane 72.7 26.5 2.69 299 0.628 Octamethylcyclotetrasiloxane 313 13.2 1.33 970 0.306 Octane 295.6 24.6 2.49 492 0.232 Octanenitrile 401.3 28.1 2.85 Octanoic acid 422 26.1 2.64 1-Octanol 379.4 27.41 2.777 490 0.266 2-Octanol 356.5 27.18 2.754 494 0.278 1-Octene 293.6 26.40 2.675 464 0.242 cis-2-Octene 307 27.3 2.77 Octylcyclopentane 421 17.7 1.79 Osmium tetroxide 132 170 17.2 Oxygen 118.56 49.77 5.043 73.4 0.436 Oxygen difluoride 58.0 48.9 4.95 97.7 0.553 Ozone 12.10 53.8 5.45 88.9 0.540 Pentachloroethane 373.0 Pentadecane 433.9 15 1.52 880 0.241 1-Pentadecene 431 14.4 1.46 Pentadecylcyclopentane 507 10.1 1.02 1,2-Pentadiene 230 40.2 4.07 276 0.248 cis-1,3-Pentadiene 223 39.4 3.99 275 0.248 1,4-Pentadiene 205 37.4 3.79 276 0.248 Pentafluorobenzene 258.9 34.7 3.52 2,3,4,5,6-Pentafluoro<strong>to</strong>luene 275.5 2,2,3,3,4-Pentamethylpentane 370.7 25.5 2.58 508 0.280 2,2,3,4,4-Pentamethylpentane 354.2 23.7 2.40 521 0.273 Pentanal 281 35 3.55 333 0.259 Pentane 196.6 33.26 3.370 311 0.237 Pentanenitrile 337.2 35.3 3.58 Pentanethiol 324.6 Pentanoicacid 370 35.3 3.58 340 0.300 1-Pentanol 315.0 38.38 3.889 326 0.270 2-Pentanol 287.3 36.27 3.675
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LANGE'S HANDBOOK OF CHEMISTRY John
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Grateful acknowledgment is hereby m
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PREFACE TO FIFTEENTH EDITION This n
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PREFACE TO FIFTEENTH EDITION ix inv
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xii PREFACE TO FOURTEENTH EDITION l
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PREFACE TO FIRST EDITION This book
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For the detailed contents of any se
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1.2 SECTION 1 is derived from the G
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1.4 SECTION 1 rather than methylide
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1.6 SECTION 1 Styrene Toluene Xylen
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1.8 SECTION 1 TABLE 1.2 Fused Polyc
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1.10 SECTION 1 1.1.1.6 Bridged Hydr
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1.12 SECTION 1 TABLE 1.4 Suffixes f
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1.14 SECTION 1 TABLE 1.5 Trivial Na
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1.16 SECTION 1 TABLE 1.6 Trivial Na
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1.18 SECTION 1 Selection of the pri
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1.20 SECTION 1 attached to one anot
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1.22 SECTION 1 When side chains of
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1.24 SECTION 1 heterocyclic structu
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1.26 SECTION 1 Bivalent radicals of
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1.28 SECTION 1 Complex linear polya
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1.30 SECTION 1 TABLE 1.11 Names of
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1.32 SECTION 1 hydroxyamino- to the
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1.34 SECTION 1 may be named (1) by
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1.36 SECTION 1 Examples are methyl
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1.38 SECTION 1 tuted acid, respecti
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1.40 SECTION 1 FIGURE 1.2 Newman pr
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1.42 SECTION 1 from the ring are kn
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1.44 SECTION 1 FIGURE 1.11 Two isom
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1.46 SECTION 1 Chiral Center. The c
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1.48 SECTION 1 FIGURE 1.15 Isomers
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1.50 SECTION 1 entries to bring tog
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1.52 SECTION 1 TABLE 1.13 Names and
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1.60 SECTION 1 TABLE 1.14 Empirical
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2.2 SECTION 2 2.3.6 Student’s Dis
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2.4 SECTION 2 TABLE 2.1 Fundamental
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2.6 SECTION 2 TABLE 2.1 Fundamental
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2.8 SECTION 2 TABLE 2.2 Physical an
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2.10 SECTION 2 TABLE 2.2 Physical a
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2.24 SECTION 2 TABLE 2.3 Mathematic
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2.26 SECTION 2 TABLE 2.6 Abbreviati
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2.36 SECTION 2 TABLE 2.7 Conversion
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2.54 SECTION 2 TABLE 2.8 Temperatur
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2.66 SECTION 2 2.1.1 Conversion of
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2.68 SECTION 2 Oleometer. A hydrome
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2.70 SECTION 2 Example 3. 25 1.2500
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2.72 SECTION 2 TABLE 2.9 Barometer
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2.74 SECTION 2 TABLE 2.9 Barometer
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2.76 SECTION 2 TABLE 2.10 Barometri
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2.78 SECTION 2 TABLE 2.12 Reduction
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2.80 SECTION 2 TABLE 2.12 Reduction
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2.82 SECTION 2 TABLE 2.13 Viscosity
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2.84 SECTION 2 TABLE 2.14 Conversio
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2.86 SECTION 2 TABLE 2.15 Hydromete
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2.88 SECTION 2 TABLE 2.17 Correctio
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2.90 SECTION 2 TABLE 2.18 Pressure
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2.96 SECTION 2 TABLE 2.20 Values of
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2.98 SECTION 2 TABLE 2.21 Transmitt
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2.100 SECTION 2 TABLE 2.21 Transmit
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2.102 SECTION 2 2.2 MATHEMATICAL TA
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2.104 SECTION 2 TABLE 2.23 Derivati
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2.106 SECTION 2 TABLE 2.24 Integral
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2.108 SECTION 2 TABLE 2.24 Integral
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2.110 SECTION 2 Regular Polygon of
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2.112 SECTION 2 A h[0.4(y y ) 1.
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2.114 SECTION 2 2.2.3.1 Signs of th
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2.116 SECTION 2 x2 x3 x4 x5 ln(1 x
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2.118 SECTION 2 2.3.2 Errors in Qua
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2.120 SECTION 2 The breadth or spre
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2.122 SECTION 2 TABLE 2.26b Areas U
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2.124 SECTION 2 The distribution of
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2.126 SECTION 2 Should there be mor
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2.128 SECTION 2 Example 10 Six samp
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2.130 SECTION 2 2.3.9 The F Statist
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TABLE 2.29 F Distribution (Continue
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2.134 SECTION 2 mathematical treatm
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2.136 SECTION 2 The confidence limi
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2.138 SECTION 2 situation where rel
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3.2 SECTION 3 The alphabetical orde
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3.4 SECTION 3 When it is required t
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3.6 SECTION 3 PO phosphoryl SeO sel
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3.8 SECTION 3 3.1.5 Acids 3.1.5.1 A
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3.10 SECTION 3 3.1.6.6 Multiplicati
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3.12 SECTION 3 3.2 PHYSICAL PROPERT
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TABLE 3.2 Physical Constants of Ino
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3.62 SECTION 3 TABLE 3.3 Synonyms a
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SECTION 4 PROPERTIES OF ATOMS, RADI
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4.3 Fermium Fm 100 [Rn] 5f 12 7s 2
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Silver (argentum) Ag 47 [Kr] 4d 10
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PROPERTIES OF ATOMS,RADICALS,AND BO
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PROPERTIES OF ATOMS, RADICALS, AND
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SECTION 5 PHYSICAL PROPERTIES 5.1 S
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PHYSICAL PROPERTIES 5.3 5.1 SOLUBIL
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TABLE 5.1 Solubility of Gases in Wa
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TABLE 5.1 Solubility of Gases in Wa
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TABLE 5.2 Solubilities of Inorganic
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formateBa(CHO 2 ) 2 26.2 28.0 29.9
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(III) sulfateCe 2 (SO 4 ) 3 ·9H 2
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iodidePbI 2 0.044 0.056 0.069 0.090
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Nickel sulfateNiSO 4 ·6H 2 O (pale
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Praseodymium bromatePr(BrO 3 ) 3 55
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formate NaCHO 2 43.9 62.5 81.2 102
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Uranyl nitrate UO 2 (NO 3 ) 2 98 10
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PHYSICAL PROPERTIES 5.25 TABLE 5.3
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PHYSICAL PROPERTIES 5.57 5.3 BOILIN
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TABLE 5.12 Ternary Azeotropic Mixtu
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TABLE 5.12 Ternary Azeotropic Mixtu
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PHYSICAL PROPERTIES 5.83 5.4 FREEZI
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PHYSICAL PROPERTIES 5.87 5.5 DENSIT
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PHYSICAL PROPERTIES 5.89 dt Dt P
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PHYSICAL PROPERTIES 5.135 5.6.1 Ref
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PHYSICAL PROPERTIES 5.137 where the
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PHYSICAL PROPERTIES 5.139 5.7 COMBU
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Temperature, C Substance 40 20 0 20
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PHYSICAL PROPERTIES 5.171 This equa
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SECTION 6 THERMODYNAMIC PROPERTIES
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THERMODYNAMICPROPERTIES 6.3 6.1.1.2
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THERMODYNAMICPROPERTIES 6.5 A gener
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THERMODYNAMICPROPERTIES 6.7 TABLE 6
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THERMODYNAMICPROPERTIES 6.9 TABLE 6
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THERMODYNAMICPROPERTIES 6.11 TABLE
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THERMODYNAMIC PROPERTIES 6.21 TABLE
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THERMODYNAMIC PROPERTIES 6.101 TABL
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Page 706 and 707: SPECTROSCOPY 7.3 TABLE 7.1 Waveleng
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Page 714 and 715: SPECTROSCOPY 7.11 TABLE 7.4 X-Ray E
Page 716 and 717: SPECTROSCOPY 7.13 Emission line K 1
Page 718 and 719: SPECTROSCOPY 7.15 TABLE 7.7 Analyzi
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Page 722 and 723: SPECTROSCOPY 7.19 TABLE 7.9 Electro
Page 724 and 725: SPECTROSCOPY 7.21 TABLE 7.11 Absorp
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Page 728 and 729: SPECTROSCOPY 7.25 7.3 FLUORESCENCE
Page 730 and 731: SPECTROSCOPY 7.27 TABLE 7.16 Fluore
Page 732 and 733: SPECTROSCOPY 7.29 TABLE 7.18 Detect
Page 738 and 739: SPECTROSCOPY 7.35 TABLE 7.19 Sensit
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Page 742 and 743: SPECTROSCOPY 7.39 In terms of m ,
Page 744 and 745: SPECTROSCOPY 7.41 The ionization co
Page 746 and 747: SPECTROSCOPY 7.43 TABLE 7.20 Absorp
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SPECTROSCOPY 7.45 TABLE 7.20 Absorp
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SPECTROSCOPY 7.67 TABLE 7.28 Infrar
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7.69
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SPECTROSCOPY 7.71 7.6 RAMAN SPECTRO
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SPECTROSCOPY 7.73 TABLE 7.30 Raman
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SPECTROSCOPY 7.89 7.7 NUCLEAR MAGNE
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SPECTROSCOPY 7.91 TABLE 7.41 Nuclea
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SPECTROSCOPY 7.93 TABLE 7.42 Proton
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SPECTROSCOPY 7.95 TABLE 7.44 Estima
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SPECTROSCOPY 7.97 TABLE 7.46 Proton
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SPECTROSCOPY 7.99 TABLE 7.48 Solven
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SPECTROSCOPY 7.101 TABLE 7.49 Carbo
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SPECTROSCOPY 7.103 TABLE 7.51 Effec
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SPECTROSCOPY 7.107 TABLE 7.56 One-B
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SPECTROSCOPY 7.113 TABLE 7.63 Nitro
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SPECTROSCOPY 7.115 TABLE 7.64 Nitro
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SPECTROSCOPY 7.117 TABLE 7.69 Fluor
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SPECTROSCOPY 7.119 TABLE 7.72 Silic
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SPECTROSCOPY 7.121 TABLE 7.73 Phosp
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SPECTROSCOPY 7.123 TABLE 7.74 Phosp
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SPECTROSCOPY 7.125 when z 3 and y
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SPECTROSCOPY 7.127 Masses 19 and 31
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SPECTROSCOPY 7.129 TABLE 7.76 Conde
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SECTION 8 ELECTROLYTES, ELECTROMOTI
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ELECTROLYTES, EMF, AND CHEMICAL EQU
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TABLE 8.7 Proton Transfer Reactions
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TABLE 8.7 Proton Transfer Reactions
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TABLE 8.9 Selected Equilibrium Cons
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8.75 3-tert-Butylbenzoic acid (0) 4
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4-Hydroxyproline (1) 1.900 1C 1.850
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N-Propionylglycine (1) 3.728 3.723
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TABLE 8.14 National Bureau of Stand
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1 part 0.1% neutral red in alc. * V
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3,3-Dimethoxybenzidine dihydrochlor
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TABLE 8.35 Equivalent Conductivitie
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KCl 127.3 124.4 122.4 115.8 112.0 1
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NaIO 3 75.2 72.6 70.9 64.4 60.5 1
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9.2 SECTION 9 9.1 LINEAR FREE ENERG
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9.4 SECTION 9 TABLE 9.1 Hammett and
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9.6 SECTION 9 TABLE 9.1 Hammett and
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9.8 SECTION 9 TABLE 9.3 pK a and Rh
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10.2 SECTION 10 10.4.6 Polyacrylate
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10.4 SECTION 10 10.2 ADDITIVES TO P
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10.6 SECTION 10 injection molding.
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10.8 SECTION 10 10.3 FORMULAS AND K
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10.10 SECTION 10 Key properties of
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10.12 SECTION 10 10.3.8 Fluorocarbo
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10.14 SECTION 10 10.3.11 Phenolics
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10.16 SECTION 10 The resin has the
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10.18 SECTION 10 10.3.19 Polyuretha
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10.20 SECTION 10 10.3.22 Sulfones B
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TABLE 10.2 Properties of Commercial
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10.58 SECTION 10 10.4 FORMULAS AND
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10.60 SECTION 10 10.4.8 Polychlorop
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10.62 SECTION 10 Styrene-butadiene
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10.5 CHEMICAL RESISTANCE TABLE 10.4
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10.6 GAS PERMEABILITY TABLE 10.5 Ga
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TABLE 10.5 Gas Permeability Constan
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TABLE 10.7 Constants ofFats and Oil
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TABLE 10.8 Constants ofWaxes Wax Me
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SECTION 11 PRACTICAL LABORATORY INF
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11.4 SECTION 11 TABLE 11.2 Molecula
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11.6 SECTION 11 A saturated aqueous
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11.8 SECTION 11 TABLE 11.6 Relative
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11.10 SECTION 11 11.3 BOILING POINT
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11.12 SECTION 11 TABLE 11.8 Organic
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11.14 SECTION 11 TABLE 11.9 Molecul
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11.4 SEPARATION METHODS TABLE 11.11
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11.18 SECTION 11 TABLE 11.12 Solven
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11.20 SECTION 11 TABLE 11.12 Solven
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TABLE 11.13 McReynolds’ Constants
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TABLE 11.13 McReynolds’ Constants
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11.26 SECTION 11 11.4.1 McReynolds
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11.28 SECTION 11 11.4.2.2 Partition
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11.30 SECTION 11 FIGURE 11.2 Band a
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11.32 SECTION 11 11.4.3 Ion-Exchang
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11.34 SECTION 11 TABLE 11.16 Guide
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11.36 SECTION 11 TABLE 11.16 Guide
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11.38 SECTION 11 TABLE 11.18 Relati
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11.40 SECTION 11 distribution coeff
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11.42 SECTION 11 TABLE 11.19 Gravim
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11.68 SECTION 11 TABLE 11.20 Elemen
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11.70 SECTION 11 TABLE 11.22 Common
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11.72 SECTION 11 TABLE 11.25 Tolera
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11.74 SECTION 11 TABLE 11.26 Heatin
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11.76 SECTION 11 TABLE 11.28 Titrim
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11.84 SECTION 11 appears becomes le
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11.86 SECTION 11 TABLE 11.29 Equati
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11.88 SECTION 11 TABLE 11.29 Equati
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11.90 SECTION 11 The more stable th
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11.92 SECTION 11 11.6.6.2.5 Buffer
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11.94 SECTION 11 TABLE 11.30 Standa
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TABLE 11.32 Properties and Applicat
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11.98 SECTION 11 TABLE 11.36 Maskin
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11.100 SECTION 11 TABLE 11.37 Anion
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11.102 SECTION 11 TABLE 11.39 Amino
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11.104 SECTION 11 TABLE 11.44 Facto
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11.106 SECTION 11 11.7 LABORATORY S
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11.108 SECTION 11 TABLE 11.48 Stand
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11.110 SECTION 11 Alizarin yellow G
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11.112 SECTION 11 Bromchlorophenol
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11.114 SECTION 11 p-Ethoxychrysoidi
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11.116 SECTION 11 Mercurous nitrate
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11.118 SECTION 11 Potassium carbona
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11.120 SECTION 11 until the ammoniu
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11.122 SECTION 11 TABLE 11.49 TLV C
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11.130 SECTION 11 TABLE 11.50 Chemi
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11.138 SECTION 11 of water which is
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TABLE 11.55 Thermoelectric Values i
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TABLE 11.56 Type B Thermocouples: P
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TABLE 11.58 Type J Thermocouples: I
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TABLE 11.60 Type N Thermocouples: N
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TABLE 11.62 Type S Thermocouples: P
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11.150 SECTION 11 11.11 CORRECTION
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Index Terms Links 2 Acid-base indic
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Index Terms Links 4 Alkynes, nomenc
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Index Terms Links 6 Aurintricarboxy
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Index Terms Links 8 Boron-11 chemic
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Index Terms Links 10 Cellulose acet
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Index Terms Links 12 Collective ino
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Index Terms Links 14 Degree Fahrenh
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Index Terms Links 16 Electrical res
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Index Terms Links 18 Equivalent wei
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Index Terms Links 20 Fluorocarbon p
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Index Terms Links 22 Halogenated hy
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Index Terms Links 24 Impact strengt
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Index Terms Links 26 Kα 1 lines, m
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Index Terms Links 28 Melmine phenol
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Index Terms Links 30 Neon-neon bond
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Index Terms Links 32 One-tailed tes
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Index Terms Links 34 Physical chemi
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Index Terms Links 36 Polyolefin the
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Index Terms Links 38 Pyridine: bina
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Index Terms Links 40 Rho values: fo
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Index Terms Links 42 Single-bond ra
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Index Terms Links 44 Stereoisomers
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Index Terms Links 46 Tension, aqueo
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Index Terms Links 48 Triethylenetet
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Index Terms Links 50 Water (Cont.)
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